Search results for "Stability"

showing 10 items of 3085 documents

Breather dynamics in a stochastic sine-Gordon equation: evidence of noise-enhanced stability

2023

The dynamics of sine-Gordon breathers is studied in the presence of dissipative and stochastic perturbations. Taking a stationary breather with a random phase value as the initial state, the performed simulations demonstrate that a spatially-homogeneous noisy source can make the oscillatory excitation more stable, i.e., it enables the latter to last significantly longer than it would in a noise-free scenario. Both the frequency domain and the localization of energy are examined to document the effectiveness of the noise-enhanced stability phenomenon, which emerges as a nonmonotonic behavior of an average characteristic time for the breather as a function of the noise intensity. The influenc…

Perturbed sine-Gordon modelSettore FIS/02 - Fisica Teorica Modelli E Metodi MatematiciStatistical Mechanics (cond-mat.stat-mech)Condensed Matter - Mesoscale and Nanoscale PhysicsGeneral MathematicsApplied MathematicsFOS: Physical sciencesGeneral Physics and AstronomyStatistical and Nonlinear PhysicsPattern Formation and Solitons (nlin.PS)Noise-enhanced stabilityNonlinear Sciences - Pattern Formation and SolitonsBreathersMesoscale and Nanoscale Physics (cond-mat.mes-hall)Breathers; Noise-enhanced stability; Perturbed sine-Gordon model; Soliton dynamicsSoliton dynamicsCondensed Matter - Statistical Mechanics
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Nitroblue-tetrazolium test for the functional evaluation of phagocytic cells: a critical analysis of the methodology.

1981

The reduction of NBT to formazan has been suggested as an indicator of the reduction potential of biological systems. An increase in the amount of reduced formazan reflects the activation of the hexose monophosphate shunt of phagocytes cultivated in vitro, as a result of cellular stimulation by chemical or biological factors, or during phagocytosis. This phenomenon has been widely used for the determination of activated phagocytes by different methods. However, the technical limitations of these methods have not been evaluated carefully. In the investigations presented here three solvents for formazan, pyridine, dioxane and dimethyl-formamide, have been tested for their suitability as extra…

PhagocyteChemical PhenomenaPyridinesPhagocytosisImmunologyTetrazolium SaltsIn Vitro TechniquesToxicologyDioxaneschemistry.chemical_compoundDrug StabilitymedicineHumansPharmacology (medical)DissolutionPharmacologyPhagocytesChromatographyFormazansNitroblue TetrazoliumExtraction (chemistry)DimethylformamideIn vitroSolventChemistrymedicine.anatomical_structurechemistryBiochemistrySolventsDimethylformamideFormazanOxidation-ReductionAgents and actions
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Influence of poloxamers on the dissolution performance and stability of controlled-release formulations containing Precirol® ATO 5

2005

Abstract Lipid excipients are usually used for the development of sustained-release formulations. When used in relatively high quantities, Precirol ® ATO 5 imparts sustained-release properties to solid oral dosage forms, by forming a lipid matrix. To control or adjust the drug release kinetics from such lipid matrix however, one must often resort to complementary ingredients or techniques. This study investigates the influence of poloxamers (Lutrol ® ) included in lipid matrices composed of glyceryl palmitostearate (Precirol ® ATO 5) on their dissolution performance and their stability. The addition of these hydrophilic polymers in the lipid matrix increased the amount of theophylline relea…

Pharmaceutical ScienceExcipientPoloxamerMolding (process)In Vitro TechniquesDosage formDiglyceridesExcipientsDrug StabilityTheophyllinemedicineTechnology PharmaceuticalTheophyllineDissolutionChromatographyCalorimetry Differential ScanningViscosityChemistryWaterPoloxamerControlled releaseKineticsMicroscopy ElectronModels ChemicalSolubilityDelayed-Action PreparationsSwellingmedicine.symptomRheologyPorositymedicine.drugInternational Journal of Pharmaceutics
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In-use physicochemical and microbiological stability of biological parenteral products

2015

Pharmaceutical scientists in the biotechnology industry have traditionally focused on achieving acceptable shelf lives of drug products in their original, unopened product unit configuration (e.g., two years stored at 2–8 °C). However, it is now clear that stability considerations extend beyond

PharmacologyBiological ProductsBacteriabusiness.industryChemistry PharmaceuticalDrug CompoundingHealth PolicyProteinsBiotechnologyPharmaceutical SolutionsDrug StabilityHumansInfusions ParenteralBusinessBiochemical engineeringProduct (category theory)Drug ContaminationDrug PackagingBiotechnology industryAmerican Journal of Health-System Pharmacy
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A phosphonamidate containing aromatic N-terminal amino group as inhibitor of leucine aminopeptidase-design, synthesis and stability.

2006

Fully deprotected phosphonamidate dipeptides, predicted as effective inhibitors of cytosolic leucine aminopeptidase, showed unexpected instability in water solution at pH below 12. Their hydrolysis rate was strictly correlated with basicity of the N-terminal amino group. To improve this feature a phosphonamidate analogue containing less basic, aromatic 2-aminophenylphosphonate residue in P1 position of the inhibitor was designed. The target compound was synthesised starting from diethyl 2-nitrophosphonate in several step procedure. The decrease in basicity of the terminal amino moiety of the modified analogue in fact resulted in satisfactory improvement of hydrolytic stability of the P–N bo…

PharmacologyModels MolecularMagnetic Resonance SpectroscopyChemistryStereochemistryphosphonamidateLAP inhibitorsOrganic ChemistryGeneral MedicineAminopeptidaseChemical synthesisResidue (chemistry)HydrolysisLeucyl AminopeptidaseOrganophosphorus CompoundsDrug StabilityDrug DesignDrug Discoveryhydrolytic stabilityMoietyChemical stabilityProtease InhibitorsLeucineLeucyl aminopeptidaseEuropean journal of medicinal chemistry
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Physicochemical stability of human insulin 1 I.U./mL infusion solution in 50 mL polypropylene syringes

2021

Abstract Objectives The objective of this study was to investigate the physicochemical stability of human insulin 1 I.U./mL injection solutions (Insuman® Rapid) diluted with 0.9% NaCl solution in 50 mL disposable three-piece polypropylene syringes and stored refrigerated or at room temperature. Methods 1 I.U./mL test solutions were prepared with Insuman® Rapid and 0.9% sodium chloride infusion solution in 50 mL Original-Perfusor® syringes and BD® Perfusion syringes. Test solutions were stored for 90 days at 2–8 °C/dark or 48 h at 20–25 °C/diffuse room light in order to determine chemical stability. Additional test solutions were stored 28 days at 2–8 °C/dark followed by 24 h at 20–25 °C/dif…

PharmacologyPolypropyleneChromatographyInternational unitphysicochemical stabilityInfusion solutionPharmacyRM1-950polypropylene syringechemistry.chemical_compoundchemistryHuman insulinhuman insulinPharmacology (medical)intravenous injectionTherapeutics. PharmacologyHD9665-9675Pharmaceutical industryPharmaceutical Technology in Hospital Pharmacy
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The azulene scaffold from a medicinal chemist's perspective: Physicochemical and in vitro parameters relevant for drug discovery.

2022

Azulene is a bicyclic scaffold rarely applied in medicinal chemistry. Here we report physicochemical and in vitro parameters relevant for drug discovery for a series of diversely substituted azulenes. We synthesized and characterized several scaffold hopping series of analogously substituted azulenes, indoles and naphthalenes. This enabled a comparison of azulene with the more common scaffolds indole and naphthalene. Our data indicates that undesirably low photostability of azulenes is restricted to certain substitution patterns. Generally, we conclude that azulene is an underused lipophilic bicycle and should be considered as a valuable complement to the collection of medicinal chemistry s…

Pharmacologyaromaattiset yhdisteetScaffold hoppingChemistry PharmaceuticalOrganic ChemistryGeneral MedicineAzuleneslääkesuunnitteluPhotostabilitylääkekemiaIndoleDrug Discoveryatsuleenibiologinen aktiivisuusNaphthaleneEuropean journal of medicinal chemistry
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European Databases on Stability and Compatibility of Injectable Medicinal Products in Europe

2020

AbstractIn hospitals, the majority of medication therapy is administered intravenously. Especially, in intensive care units, simultaneous of various injectable drugs is a common practice Drug incompatibilities have been reported to be associated with up to 60 % of all serious and life-threatening adverse drug events. Several databases are used by hospital pharmacists to answer the questions of (in)compatibility of co-administered injectable drugs. The objective of this article is to present the European databases on compatibility and stability of injectable drugs. According to a questionnaire which was sent to the National Hospital Pharmacy Associations of the 28 countries of European Commu…

Pharmacologybusiness.industryelectronic databasePharmacyRM1-950compatibility030226 pharmacology & pharmacyBiotechnologychemical stability03 medical and health sciences0302 clinical medicine030220 oncology & carcinogenesisCompatibility (mechanics)MedicinePharmacology (medical)Electronic databaseTherapeutics. PharmacologyHD9665-9675businessinjectable drugsPharmaceutical industryPharmaceutical Technology in Hospital Pharmacy
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Polymorphic and regular localized activity structures in a two-dimensional two-component reaction–diffusion lattice with complex threshold excitation

2010

Abstract Space–time dynamics of the system modeling collective behaviour of electrically coupled nonlinear units is investigated. The dynamics of a local cell is described by the FitzHugh–Nagumo system with complex threshold excitation. It is shown that such a system supports formation of two distinct kinds of stable two-dimensional spatially localized moving structures without any external stabilizing actions. These are regular and polymorphic structures. The regular structures preserve their shape and velocity under propagation while the shape and velocity as well as other integral characteristics of polymorphic structures show rather complex temporal behaviour. Both kinds of structures r…

Phase spaceLattice (order)Quasiperiodic functionReaction–diffusion systemBound statePattern formationStatistical and Nonlinear PhysicsGeometryStatistical physicsCondensed Matter PhysicsBifurcationMultistabilityMathematicsPhysica D: Nonlinear Phenomena
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Hydrolytic action of phospholipase A2 in monolayers in the phase transition region: direct observation of enzyme domain formation using fluorescence …

1990

Phospholipase A2, a ubiquitous lipolytic enzyme highly active in the hydrolysis of organized phospholipid substrates, has been characterized optically in its action against a variety of phospholipid monolayers using fluorescence microscopy. By labeling the enzyme with a fluorescent marker and introducing it into the subphase of a Langmuir film balance, the hydrolysis of lipid monolayers in their liquid-solid phase transition region could be directly observed with the assistance of an epifluorescence microscope. Visual observation of hydrolysis of different phospholipid monolayers in the phase transition region in real-time could differentiate various mechanisms of hydrolytic action against …

Phase transition12-DipalmitoylphosphatidylcholineStereochemistryBiophysicsPhospholipidBiochemistryPhospholipases Achemistry.chemical_compoundPhospholipase A2Phase (matter)MonolayerEnzyme StabilityFluorescence microscopeLipid bilayer phase behaviorParticle SizePhospholipidsFluorescent DyesElapid VenomsPhospholipase ABinding SitesbiologyHydrolysisPhosphatidylethanolaminesCell BiologyImage EnhancementPhospholipases A2chemistryMicroscopy FluorescencePhospholipasesBiophysicsbiology.proteinlipids (amino acids peptides and proteins)DimyristoylphosphatidylcholineBiochimica et biophysica acta
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