Search results for "Stack"
showing 10 items of 392 documents
Mononuclear Mn(III) and dinuclear Mn(III,III) Schiff base complexes: Influence of π–π stacking on magnetic properties
2012
Abstract Synthesis of a mononuclear Mn(III) (1) and a dinuclear Mn(III, III) (2) complex of a tetradentate N2O2 donor Schiff base ligand with ancillary carboxylate ligands are reported. Complex 1 crystallizes in the monoclinic space group C2/c, complex 2 in the triclinic space group P-1. In both complexes the central Mn(III) ions are hexacoordinated having a distorted octahedral MnN2O4 coordination environment. Intermolecular hydrogen bonding and strong π–π stacking in both 1 and 2 leads to dimerization of 1 and formation of a syn–anti one-dimensional chain for 2. Magnetic properties of 1 and 2 are reported. Both complexes show very weak intermolecular antiferromagnetic interaction. Most in…
Proposal of an Architecture to Retrieve Information from Multiple Devices Using Matchmaking Algorithms
2007
Semantic Web services (SWS) propose to extend the traditional Web services technologies on the way to consolidate ontologies and semantics. This makes possible the selection, the integration and the dynamic invocation of services. In this way, services are able to dynamically adapt themselves to changes without human intervention. The main purpose of this paper is to present an algorithm for matching SWS. The algorithm uses the description of the services capabilities to match the semantic values. The traditional matching has been improving using ontologies witch constitutes a step further in the matching algorithms. To implement the algorithm an agent FIPA compliant architecture has been d…
A hybrid approach to semantic web services matchmaking
2008
AbstractDeploying the semantics embedded in web services is a mandatory step in the automation of discovery, invocation and composition activities. The semantic annotation is the “add-on” to cope with the actual interoperability limitations and to assure a valid support to the interpretation of services capabilities. Nevertheless many issues have to be reached to support semantics in the web services and to guarantee accurate functionality descriptions. Early efforts address automatic matchmaking tasks, in order to find eligible advertised services which appropriately meet the consumer’s demand. In the most of approaches, this activity is often entrusted to software agents, able to drive re…
Similarity estimation module for OWSCIS
2008
Semantic interoperability based on ontologies is nowadays becoming a great challenge. We propose an architecture for semantic-based cooperation called OWSCIS (Ontology and Web Service based Cooperation of Information Sources). It allows to map various information sources using ontologies and to answer users' queries over the cooperation. In this paper we focus on the similarity estimation service of the OWSCIS Architecture which allows to discover mappings between different ontologies. It relies on various mappings methods which are combined and refined to semi-automatically generate mappings between a local and a reference ontologies.
Breaking layer 2: A new architecture for programmable wireless interfaces
2012
This paper introduces a new architecture for programmable wireless interfaces, aiming at responding to the emerging request of wireless access flexibility and adaptability. Instead of implementing a specific MAC protocol stack, the proposed architecture supports a set of programmable services, devised to customize the wireless access operations according to specific network and application scenarios. The services are composed by means of simpler functions, which in turns work on system primitives (i.e. elementary non-programmable functionalities, natively provided by the system) dealing with the physical transmission and reception of the frames. Our approach significantly differs from softw…
Fuzzy-neural Web switch supporting differentiated service
2006
New designs of the Web switches must incorporate a client-and-server-aware adaptive dispatching algorithm to be able to optimize multiple static and dynamic services providing quality of service and service differentiation. This paper presents such an algorithm called FNRD (Fuzzy-Neural Request Distribution) which operates at layer-7 of the OSI protocol stack. This algorithm assigns each incoming request to the server with the least expected response time estimated using the fuzzy approach. FNRD has ability for learning and adaptation by means of a neural network feedback loop. We demonstrate through the simulations that our dispatching policy is more effective than state-of-the-art layer-7…
Approximate solutions for two-level optimization problems
1988
This paper is devoted to general results for approximating two-level optimization problems in which the set of solutions to the lower level problem is not a singleton.
Looking Beyond Genres: Identifying Meaningful Semantic Layers from Tags in Online Music Collections
2011
A scheme for identifying the semantic layers of music-related tags is presented. Arguments are provided why the applications of the tags cannot be effectively pursued without a reasonable understanding of their semantic qualities. The identification scheme consists of a set of filters. The first is related with social consensus, user-count ratio, and n-gram properties of tags. The next relies on look-up functions across multiple databases to determine the probable semantic layer of each tag. Examples of the semantic layers with prevalence rates are given based on application of the scheme to a subset of the Million Song Dataset. Finally, a validation of the results was carried out with an i…
Semantic traffic applications based on DatexII
2009
In this work we demonstrate a particular use of ontologies based on the European specifications DATEXII. These specifications are designed and developed as a traffic and travel data exchange mechanism by a European task force to set up and standardise the interface between traffic control and information centres. It is the reference for applications that are developed and implemented in Europe.This language describes concepts and structures of data related to traffic, but the description is just syntactic, not semantic. Therefore the objective to be reached in this part of the research has been to develop a semantic description in order to carry out some applications like syndication and a …
Nickel(II) 3,4;9,10-perylenediimide bis-phosphonate pentahydrate: A metal-organic ferromagnetic dye
2012
The new metal organic compound nickel(II) 3,4;9,10-perylenediimide bis-phosphonate pentahydrate, i.e. Ni-2[(PDI-BP)-(H2O)(2)]center dot 3H(2)O (1), has been synthesized and its structural and magnetic properties have been studied. Reaction of 3,4;9,10-perylenediimide bisphosphonate (PDI-BP, hereafter) ligand and nickel chloride in water resulted in the precipitation of a red and poorly crystalline solid (1). As the solid shows a poor crystalline organization of aggregates, the energy dispersive X-ray diffraction analysis (EDXD) technique has been used to obtain short-range order structural information of the single nanoaggregates by radial distribution function analysis. The overall structu…