Search results for "Starch"

showing 10 items of 182 documents

Natural Anti-oxidants for Bio-polymeric Materials

2017

In this work, three different bio-polymers, i.e. a commercial starch-based polymer (Mater-Bi®) a bio-polyester (PLA), and a bio-polyether (PEO) were additivated with quercetin, a natural flavonoid antioxidants, in order to formulate biobased films for eco-sustainable packaging and outdoor applications. The photo-oxidation behavior of unstabilized and quercetin stabilized films has been evaluated and compared with that of films additivated with a commercial synthetic light stabilizer. Obtained results show that quercetin molecules are able to slow down the photodegradation rate of all investigated bio-polymeric films, opening new avenues in the formulation of fully renewable polymer-based sy…

chemistry.chemical_classificationMaterials scienceStarchFlavonoidNanotechnologyPolymerMicrobiologychemistry.chemical_compoundchemistryChemical engineeringOpen access publishingnatural anti-oxidant bio-polymersPhotodegradationQuercetinStabilizer (chemistry)
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Biopolymer interactions affect the functional properties of edible films based on agar, cassava starch and arabinoxylan blends

2009

Abstract Edible films based on the binary combination of agar (AG), cassava starch (CAS) and arabinoxylan (AX) were studied with regard to their microstructure, moisture barrier and mechanical properties. Though the films appear macroscopically homogeneous, electron microscopy observations reveal a phase separation and dispersion, respectively, in AG–CAS and AG–AX blend film structures, whereas the structure of CAS–AX blend films seems homogeneous. In case high moisture (84% and 99% RH), neither the combination of AG and CAS nor the addition of AX into CAS can improve film moisture barrier properties, except at a lower RH (57%). Conversely, water vapor permeability (WVP) of AG based film is…

chemistry.chemical_classificationMaterials scienceStarchPolymerengineering.materialMicrostructurechemistry.chemical_compoundChemical engineeringchemistryUltimate tensile strengthArabinoxylanengineeringOrganic chemistryBiopolymerWettingElongationFood ScienceJournal of Food Engineering
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(Co-)solvent selection for single-wall carbon nanotubes: best solvents, acids, superacids and guest-host inclusion complexes.

2011

Analysis of 1-octanol-water, cyclohexane-water and chloroform (CHCl(3))-water partition coefficients P(o-ch-cf) allows calculation of molecular lipophilicity patterns, which show that for a given atom log P(o-ch-cf) is sensitive to the presence of functional groups. Program CDHI does not properly differentiate between non-equivalent atoms. The most abundant single-wall carbon nanotube (SWNT), (10,10), presents a relatively small aqueous solubility and large elementary polarizability, P(o-ch-cf) and kinetic stability. The SWNT solubility is studied in various solvents, finding a class of non-hydrogen-bonding Lewis bases with good solubility. Solvents group into three classes. The SWNTs in so…

chemistry.chemical_classificationModels MolecularCyclodextrinChemistryNanotubes CarbonAmylopectinCationic polymerizationStarchSolventPartition coefficientColloidGlucoseSolubilityLipophilicityLewis BasesSolventsPhysical chemistryOrganic chemistryNanotechnologyThermodynamicsGeneral Materials ScienceLewis acids and basesSolubilityAcidsNanoscale
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Characterizing physicochemical, nutritional and quality attributes of wholegrain Oryza sativa L. subjected to high intensity ultrasound-stimulated pr…

2020

Abstract When ultrasonic stimulation is applied to plant seeds it may promote the development of new adaptive characteristics during germination, thus providing an alternative to regulate nutritional and physicochemical attributes of germinated seeds. However, there is rather limited information concerning high-intensity ultrasound (HIU) effects on the germination process of crop seeds as foodstuff. This investigation aimed at examining the effects of a novel processing pattern, which coupled HIU stimulation (28 kHz, 17.83 W cm−2) to a pre-germination stage, on the physicochemical, nutritional and quality changes of wholegrain brown rice (WBR; Oryza sativa L.). Results suggested that HIU st…

chemistry.chemical_classificationOryza sativaStarch010401 analytical chemistryfood and beverageschemistry.chemical_elementStimulation04 agricultural and veterinary sciencesCalcium040401 food science01 natural sciences0104 chemical sciencesReducing sugarchemistry.chemical_compound0404 agricultural biotechnologychemistryGerminationBrown riceProlineFood scienceFood ScienceBiotechnologyFood Control
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Quercetin as natural stabilizing agent for bio-polymer

2014

The introduction of antioxidants in polymers is the main way to prevent or delay the degradation process. In particular natural antioxidants receive attention in the food industry also because of their presumed safety. In this work bio-polymers, i.e. a commercial starch-based polymer (Mater-Bi®) and a bio-polyester (PLA), and a bio-polyether (PEO) were additivated with quercetin, a natural flavonoid antioxidants, in order to formulate bio-based films for ecosustainable packaging and outdoor applications. The photo-oxidation behavior of unstabilized and quercetin stabilized films was analyzed and compared with the behavior of films additivated with a commercial synthetic light stabilizer. Th…

chemistry.chemical_classificationPolyesterchemistry.chemical_compoundMaterials sciencechemistryStarchFlavonoidOrganic chemistryNatural antioxidant Quercetin Bio-polymer Photoxidation StabilizationPolymerDegradation processQuercetinStabilizer (chemistry)
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Differential function of the phosphoglucomutase isozymes PGM1 and PGM2

1979

A total of 13 metabolites thought to be possibly inhibitory were tested for their influence on PGM isozyme activities, each at several different concentrations. The analysis of statistical significance was based on enzyme activities obtained by densitometric measurements of starch gels. Five of the substances were found to inhibit PGM activity, three of which definitely and a further one probably led to a significantly stronger inhibition of the isozymes of the PGM2 locus than of PGM1 isozymes. They are (1) fructose-1,6-diphosphate, (2) adenosine triphosphate, (3) citrate, and (4) possibly 2,3-diphosphoglycerate. Thus, PGM1 isozymes proved to function better in hard or perhaps marginal meta…

chemistry.chemical_classificationStarchChromosome MappingLocus (genetics)BiologyDiphosphoglyceric AcidsMolecular biologyIsozymeIsoenzymeschemistry.chemical_compoundAdenosine TriphosphateEnzymeGenesPhosphoglucomutasechemistryBiochemistryPGM1FructosediphosphatesGeneticsHumansPhosphoglucomutaseCitratesAdenosine triphosphateGeneGenetics (clinical)Human Genetics
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Relaxations Below Glass Transition Temperature in Bread and Its Components

1999

ABSTRACT Dry glassy bread, cooked gluten, and gelatinized wheat starch-sucrose mixtures were prepared. Dielectric properties were studied as a function of temperature at different frequencies ranging from 100 to 1,000 kHz. Both bread and starch samples exhibited a tan δ peak at -53°C at 10 kHz, which is associated with a secondary relaxation characterized by an activation energy of 50 kJ/mol. The gluten sample did not show any relaxation in the temperature range studied. The magnitude of the relaxation peak was sensitive to the sucrose concentration of the starch sample. The higher the sucrose content, the greater the amplitude of the peak. Such an effect is attributed to a greater β-relaxa…

chemistry.chemical_classificationSucroseChemistryStarchOrganic ChemistryAnalytical chemistryfood and beveragesMineralogyDielectricActivation energyAtmospheric temperature rangeGlutenchemistry.chemical_compoundRelaxation (physics)Glass transitionFood ScienceCereal Chemistry Journal
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Processing and Mechanical Properties of Natural Fiber Reinforced Thermoplastic Starch Biocomposites

2007

Natural fiber reinforced starch polymers are processed by compression molding. Potato, sweet potato, and corn starch are used as matrices. Three types of natural fibers, namely sisal, jute, and cabuya, are used in concentrations varying from 2.5 to 12.5% w/w in the composites. Different plasticizers are used for the starch polymers, such as water and glycerol. Mechanical properties are assessed by tensile and impact tests. In both cases, improved mechanical properties are obtained at increasing fiber contents. Tensile strength appears to be markedly improved with the addition of 10% by weight of sisal fibers, while the best results for impact strength are obtained for cabuya fibers.

chemistry.chemical_classificationThermoplasticMaterials scienceStarchfood and beveragesCompression moldingIzod impact strength test02 engineering and technology021001 nanoscience & nanotechnologyCondensed Matter Physicschemistry.chemical_compound020401 chemical engineeringchemistryUltimate tensile strengthCeramics and CompositesFiber0204 chemical engineeringComposite material0210 nano-technologycomputerSISALNatural fibercomputer.programming_languageJournal of Thermoplastic Composite Materials
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Influence of xanthan gum and locust bean gum upon flow and thixotropic behaviour of food emulsions containing modified starch

2007

Abstract Low oil content mayonnaises are food emulsions which exhibit shear thinning and thixotropic behaviour. They include generally modified starch in their formulation. In this work we study the effect of substituting part of this starch with other natural gums, such as xanthan gum or locust bean gum, upon the consistency and stability of the emulsions in relation to stirring. The gels prior to final emulsification have also been analyzed. Steady flow curves of all systems are well described by the Carreau model. The emulsions containing the greatest percentage of gums presented significantly higher viscosity than the reference emulsion and the emulsions containing the synergistic mixtu…

chemistry.chemical_classificationThixotropyShear thinningStarchPolysaccharideModified starchchemistry.chemical_compoundchemistryEmulsionmedicineLocust bean gumFood scienceXanthan gumFood Sciencemedicine.drugJournal of Food Engineering
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Effect of Ti(IY) on some indicators of physiological activity inCapsicum annuum, L.

1994

SummaryPaprika pepper (Capsicum annuum, L., cv. Negral) plants grown in a greenhouse were supplied Ti(IV) ascorbate through the roots or through leaves. Biomass production, peroxidase (donor: H2O, oxidoreductase; EC 1.11.1.7) activity, and malic acid, starch and chlorophyll concentrations were determined in different plant organs. It was observed that Ti increased the concentration of some of the metabolites studied and promoted both peroxidase activity and biomass production. The profitable effect of the Ti treatments could occur because they enhance the availability of other nutrients. This effect could be due to the low redox potential of the Ti+3/Ti+4 system that catalyzes the activity …

chemistry.chemical_classificationbiologyStarchfood and beveragesPlant ScienceRedoxchemistry.chemical_compoundHorticultureNutrientchemistryOxidoreductaseChlorophyllPepperBotanybiology.proteinMalic acidPeroxidaseJournal of Horticultural Science
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