Search results for "Statistical Mechanic"
showing 10 items of 707 documents
Collective atomic effects in resonance fluorescence
1977
We suggest that the statistical properties of the scattered radiation in resonance-fluorescence experiments may be affected significantly by the existence of atomic correlations. The scattered light spectrum from two- and three-atom collective systems has been calculated and compared with the one-atom spectrum. The differences are quite significant for weak fields, but become less pronounced as the intensity of the driving field is increased. In addition, we have calculated the scattered intensity correlation function for collectively interacting systems, and found that its behavior is very different from that of the single-atom intensity correlation function, both for weak and strong incid…
Test of the semischematic model for a liquid of linear molecules
1998
We apply to a liquid of linear molecules the semischematic mode-coupling model, previously introduced to describe the center of mass (COM) slow dynamics of a network-forming molecular liquid. We compare the theoretical predictions and numerical results from a molecular dynamics simulation, both for the time and the wave-vector dependence of the COM density-density correlation function. We discuss the relationship between the presented analysis and the results from an approximate solution of the equations from molecular mode-coupling theory [R. Schilling and T. Scheidsteger, Phys. Rev. E 56 2932 (1997)].
Probing slow fluctuations in nonergodic systems: Interleaved sampling technique
2007
We present a new dynamic light scattering scheme to obtain ensemble-averaged correlation functions of slow fluctuations in non-ergodic systems in an efficient way. On a rotating sample, a large set of separate correlation functions is measured in parallel, for each independent orientational component of the sample’ density fluctuations. The ensemble-averaged correlation function spans a lag time range from 1 to 104 s. We describe our first implementation of this technique, discuss its statistical accuracy and show first results. Compared to plain ensemble averaging over a series of N measurements, the total measurement time is usualy reduced by a factor N without significant degradation of …
Ferromagnetism of the Hubbard Model at Strong Coupling in the Hartree-Fock Approximation
2005
As a contribution to the study of Hartree-Fock theory we prove rigorously that the Hartree-Fock approximation to the ground state of the d-dimensional Hubbard model leads to saturated ferromagnetism when the particle density (more precisely, the chemical potential mu) is small and the coupling constant U is large, but finite. This ferromagnetism contradicts the known fact that there is no magnetization at low density, for any U, and thus shows that HF theory is wrong in this case. As in the usual Hartree-Fock theory we restrict attention to Slater determinants that are eigenvectors of the z-component of the total spin, {S}_z = sum_x n_{x,\uparrow} - n_{x,\downarrow}, and we find that the ch…
Some aspects of the nonperturbative renormalization of the phi^4 model
2007
A nonperturbative renormalization of the phi^4 model is considered. First we integrate out only a single pair of conjugated modes with wave vectors +/- q. Then we are looking for the RG equation which would describe the transformation of the Hamiltonian under the integration over a shell Lambda - d Lambda < k < Lambda, where d Lambda -> 0. We show that the known Wegner--Houghton equation is consistent with the assumption of a simple superposition of the integration results for +/- q. The renormalized action can be expanded in powers of the phi^4 coupling constant u in the high temperature phase at u -> 0. We compare the expansion coefficients with those exactly calculated by the…
Theory of bound polarons in oxide compounds
2001
We present a multilateral theoretical study of bound polarons in oxide compounds MgO and \alpha-Al_2O_3 (corundum). A continuum theory at arbitrary electron-phonon coupling is used for calculation of the energies of thermal dissociation, photoionization (optically induced release of an electron (hole) from the ground self-consistent state), as well as optical absorption to the non-relaxed excited states. Unlike the case of free strong-coupling polarons, where the ratio \kappa of the photoionization energy to the thermal dissociation energy was shown to be always equal to 3, here this ratio depends on the Froehlich coupling constant \alpha and the screened Coulomb interaction strength \beta.…
Thermodynamic formalism for transport coefficients with an application to the shear modulus and shear viscosity.
2016
We discuss Onsager's thermodynamic formalism for transport coefficients and apply it to the calculation of the shear modulus and shear viscosity of a monodisperse system of repulsive particles. We focus on the concept of extensive "distance" and intensive "field" conjugated via a Fenchel-Legendre transform involving a thermodynamic(-like) potential, which allows to switch ensembles. Employing Brownian dynamics, we calculate both the shear modulus and the shear viscosity from strain fluctuations and show that they agree with direct calculations from strained and non-equilibrium simulations, respectively. We find a dependence of the fluctuations on the coupling strength to the strain reservoi…
Landau-Zener-Stueckelberg effect in a model of interacting tunneling systems
2003
The Landau-Zener-Stueckelberg (LZS) effect in a model system of interacting tunneling particles is studied numerically and analytically. Each of N tunneling particles interacts with each of the others with the same coupling J. This problem maps onto that of the LZS effect for a large spin S=N/2. The mean-field limit N=>\infty corresponds to the classical limit S=>\infty for the effective spin. It is shown that the ferromagnetic coupling J>0 tends to suppress the LZS transitions. For N=>\infty there is a critical value of J above which the staying probability P does not go to zero in the slow sweep limit, unlike the standard LZS effect. In the same limit for J>0 LZS transition…
STATISTICAL MECHANICS OF NONCLASSIC SOLITONIC STRUCTURES-BEARING DNA SYSTEM
2011
We theoretically investigate the thermodynamic properties of modified oscillator chain proposed by Peyrard and Bishop. This model obtained by adding the quartic anharmonicity term to the coupling in the Peyrard–Bishop model is useful to model the coexistence of various phases of the molecule during the denaturation phenomenon. Within the model, the negative anharmonicity is responsible for the sharpness of calculated melting curves. We perform the transfer integral calculations to demonstrate that the model leads to a good agreement with known experimental results for DNA.
Glassy dynamics in confinement: planar and bulk limits of the mode-coupling theory.
2014
We demonstrate how the matrix-valued mode-coupling theory of the glass transition and glassy dynamics in planar confinement converges to the corresponding theory for two-dimensional (2D) planar and the three-dimensional bulk liquid, provided the wall potential satisfies certain conditions. Since the mode-coupling theory relies on the static properties as input, the emergence of a homogeneous limit for the matrix-valued intermediate scattering functions is directly connected to the convergence of the corresponding static quantities to their conventional counterparts. We show that the 2D limit is more subtle than the bulk limit, in particular, the in-planar dynamics decouples from the motion …