Search results for "Sulphur"
showing 10 items of 43 documents
Diatoms from thermal-sulphur waters of “Fiume Caldo” (North-western Sicily).
2007
The present study describes the taxonomic composition, richness and seasonal dynamics of the diatom community from thermal-sulphur waters of "Fiume Caldo" (Northwestern Sicily). The diatom flora of these waters consists of 64 taxa, showing similarities with thermal diatom communities from different geographical areas. Among the recorded taxa, Diadesmis confervacea Kütz. is a new record for Sicily. Seasonal changes in assemblage composition and richness have been recorded; the highest diversity values were observed during winter and spring, while during summer the diatom community consisted of a limited number of organisms whereas blue-green algae were quantitatively dominant. Inside the stu…
Over-evaluation of total flavonoids in grape skin extracts containing sulphur dioxide
2015
Abstract Sulphur dioxide (SO 2 ) proved to increase absorbance at 280 nm of grape skin and seed extracts containing it, diluted with ethanol–HCl to assess total flavonoids and anthocyanins in the same analysis. Additional absorbance at 280 nm was also observed in acetone:H 2 O extracts, if the acetone had not completely evaporated before the extracts were diluted with a solvent. Flavonoids were correctly quantified in the extracts when SO 2 or acetone were removed by solid-phase extraction with a C 18 RP as sorbent and methanol as eluting solvent.
Synthesis of a labile sulfur-centred ligand, [S(H)C(PPh2S)2]−: structural diversity in lithium(i), zinc(ii) and nickel(ii) complexes
2016
A high-yield synthesis of [Li{S(H)C(PPh2S)2}]2 [Li2·(3)2] was developed and this reagent was used in metathesis with ZnCl2 and NiCl2 to produce homoleptic complexes 4 and 5b in 85 and 93% yields, respectively. The solid-state structure of the octahedral complex [Zn{S(H)C(PPh2S)2}2] (4) reveals notable inequivalence between the Zn-S(C) and Zn-S(P) contacts (2.274(1) Å vs. 2.842(1) and 2.884(1) Å, respectively). Two structural isomers of the homoleptic complex [Ni{S(H)C(PPh2S)2}2] were isolated after prolonged crystallization processes. The octahedral green Ni(ii) isomer 5a exhibits the two monoprotonated ligands bonded in a tridentate (S,S',S'') mode to the Ni(ii) centre with three distinctl…
Triggering the generation of an iron(IV)-oxo compound and its reactivity toward sulfides by RuII photocatalysis
2014
The preparation of [FeIV(O)(MePy2tacn)]2+ (2, MePy2tacn = N-methyl-N,N-bis(2-picolyl)-1,4,7-triazacyclononane) by reaction of [FeII(MePy2tacn)(solvent)]2+ (1) and PhIO in CH3CN and its full characterization are described. This compound can also be prepared photochemically from its iron(II) precursor by irradiation at 447 nm in the presence of catalytic amounts of [Ru II(bpy)3]2+ as photosensitizer and a sacrificial electron acceptor (Na2S2O8). Remarkably, the rate of the reaction of the photochemically prepared compound 2 toward sulfides increases 150-fold under irradiation, and 2 is partially regenerated after the sulfide has been consumed; hence, the process can be repeated several times.…
Sulphur behaviour in Etnean magmatic system (Italy
2015
Sulfur is an essential volatile component of basaltic magmas and it is mostly dissolved as S6+ and/or S2- depending on the redox conditions. Mt. Etna continuously discharges enormous quantity of SO2 (~3563 t/d [1]). However these high flows are not fully understood in terms of S origin (magmatic or crustal) and of its behavior during magmatic evolution (fractional crystallization, magma mixing, vapor/melt fractionation [2]). Our research combines the study of sulfur in natural olivine hosted melt inclusions with an experimental study on S solubility in hydrous alkali basalts at magmatic conditions. We report new data of S in melt inclusions, belonging to six of the most characteristic Etnea…
Morphology and evolution of sulphuric acid caves in South Italy
2016
Sulphuric acid speleogenesis (SAS) related to the upwelling of acid water enriched in H2S and CO2 represents an unusual way of cave development. Since meteoric infiltration waters are not necessarily involved in speleogenesis, caves can form without the typical associated karst expressions (i.e. dolines) at the surface. The main mechanism of sulphuric acid dissolution is the oxidation of H2S (Jones et al., 2015) which can be amplified by bacterial mediation (Engel et al., 2004). In these conditions, carbonate dissolution associated with gypsum replacement, is generally believed to be faster than the normal epigenic one (De Waele et al., 2016). In Italy several SAS caves have been identified…
Analysis of highly excited 'hot' bands in the SO2 molecule: ν2 + 3ν3 - ν2 and 2ν1 + ν2 + ν3 - ν2
2010
International audience; We set up a variational procedure of assignments of transitions and we applied it to the analysis very weak 'hot' bands, v(2) + 3v(3) - v(2) and 2v(1) + v(2) + v(3) - v(2), of the SO2 molecule. As the first step of the study, the 'cold' bands, 3v(3) and 2v(1) + v(3), are re-analysed and transitions belonging to those bands are assigned up to the values of quantum numbers J(max.) = 60, K-a(max.) = 19, and J(max.) = 69, K-a(max.) = 20 for the bands 3v(3) and 2v(1) + v(3), respectively. After 'cleaning' the experimental spectrum from transitions belonging to the 3v(3) and 2v(1) + v(3) bands, a variational procedure was used that allowed us to assign 230 and 115 transiti…
Transcriptional response of Medicago truncatula sulphate transporters to arbuscular mycorrhizal symbiosis with and without sulphur stress
2013
Sulphur is an essential macronutrient for plant growth, development and response to various abiotic and biotic stresses due to its key role in the biosynthesis of many S-containing compounds. Sulphate represents a very small portion of soil S pull and it is the only form that plant roots can uptake and mobilize through H(+)-dependent co-transport processes implying sulphate transporters. Unlike the other organically bound forms of S, sulphate is normally leached from soils due to its solubility in water, thus reducing its availability to plants. Although our knowledge of plant sulphate transporters has been growing significantly in the past decades, little is still known about the effect of…
Melt inclusions constrain S behaviour and redox conditions in Etnean magmas
2016
Mount Etna is a complex magmatic system characterized by a continuous variability both in terms of eruptive style and composition of erupted products. Currently, its volcanic activity is marked by high gas fluxes (of above all SO2), both during eruptive and non-eruptive periods. In this study, we have studied the volatile contents and Fe speciation of olivine-hosted melt inclusions from 6 eruptions of the last 15 ky, mainly to investigate the behaviour of S during ascent and differentiation of Etnean magmas. Samples selected come from the FS eruption which is the oldest and most primitive (picritic composition, Fo91), the Mt Spagnolo and from more recent eruptions: 2002/3, 2006, 2008, and 2…
Prefazione
2018
prefazione monografia sulla produzione della zolfo nella Sicilia romana