Search results for "Supercritical"

showing 6 items of 236 documents

Melt phase ring opening polymrization of lactide and glycolide assisted by supercritical carbon dioxide

2010

supercritical carbon dioxide polyesters ring opening polymerizationSettore ING-IND/27 - Chimica Industriale E Tecnologica
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Supercritical carbon dioxide induces sterilization of PLLA scaffolds contaminated by E. coli.

2014

The common sterilization techniques are based on physical processes that involve, for example, the use of autoclaves or systems to radiation such as γ-rays that can cause a structural change of the polymer treated. Therefore, the use of supercritical carbon dioxide (scCO2) is an excellent alternative, as it does not induce any variation of biomaterials treated (Perrut M., 2012). It's a good candidate because is readily available at low cost, non-toxic and non-flammable, it has an easily accessible critical point (7.38 MPa and 304.2 K) and excellent transport properties and wettability (White A. et al., 2005). We report the development of a supercritical CO2 based process capable of steriliz…

supercritical carbon dioxide scaffold sterilization
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Modeling Heterogeneous copolymerization in scCO2

2008

supercritical carbon dioxidemass transferFree radical copolymerizationkinetic model
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CO(2)-water supercritical mixtures: Test of a potential model against neutron diffraction data

2007

Abstract A neutron diffraction experiment on supercritical mixtures of water and CO 2 at two concentrations is presented. Data are analyzed within the EPSR framework and the water–water and water–CO 2 radial distribution functions are compared with those calculated by a Molecular Dynamics simulation performed by using the TIPS2 and EPM-M potential models for water and CO 2 respectively. It is found that the Molecular Dynamics simulation reproduces the overall shape of the site–site radial distribution functions, although missing a few subtle changes brought along when the CO 2 concentration is increased.

supercritical fluidChemistryNeutron diffractionAnalytical chemistryThermodynamicsRadial distributionCondensed Matter PhysicsAtomic and Molecular Physics and OpticsSupercritical fluidElectronic Optical and Magnetic MaterialsMolecular dynamicsneutron diffractionMaterials ChemistryAstrophysics::Earth and Planetary AstrophysicsPhysical and Theoretical ChemistryPhysics::Atmospheric and Oceanic PhysicsSpectroscopy
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Supercritical Antisolvent Extraction of Bioactive Compounds from Mango by-Products

2013

supercritical fluids extraction bio-compoundSettore ING-IND/25 - Impianti Chimici
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Numerical Simulations of the Flow Field of a Submerged Hydraulic Jump over Triangular Macroroughnesses

2021

The submerged hydraulic jump is a sudden change from the supercritical to subcritical flow, specified by strong turbulence, air entrainment and energy loss. Despite recent studies, hydraulic jump characteristics in smooth and rough beds, the turbulence, the mean velocity and the flow patterns in the cavity region of a submerged hydraulic jump in the rough beds, especially in the case of triangular macroroughnesses, are not completely understood. The objective of this paper was to numerically investigate via the FLOW-3D model the effects of triangular macroroughnesses on the characteristics of submerged jump, including the longitudinal profile of streamlines, flow patterns in the cavity regi…

velocitylcsh:Hydraulic engineering010504 meteorology & atmospheric sciencesGeography Planning and Development0207 environmental engineering02 engineering and technologyAquatic Science01 natural sciencesBiochemistrySettore ICAR/01 - IdraulicaPhysics::Fluid Dynamicssymbols.namesakelcsh:Water supply for domestic and industrial purposeslcsh:TC1-978triangular macroroughnesseShear stressFroude numberStreamlines streaklines and pathlines020701 environmental engineeringHydraulic jump0105 earth and related environmental sciencesWater Science and Technologylcsh:TD201-500TKEbed shear stress coefficientFLOW-3D modelsubmerged hydraulic jumpTurbulenceMechanicsSupercritical flowTurbulence kinetic energyJumpsymbolsGeologytriangular macroroughnessesWater
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