Search results for "Susceptibility"
showing 10 items of 912 documents
Diatropicity of tetraazanaphthalenes
2006
Tetraazanaphthalenes are diatropic molecules, whose magnetic response to a magnetic field perpendicular to the molecular plane closely resembles that of naphthalene. The out-of-plane component of the magnetic susceptibility tensor and its strong anisotropy can be used as quantifiers of magnetic aromaticity. Maps showing streamlines and modulus of the current density field provide clear evidence for diatropicity of these systems. They also explain the strong anisotropy of carbon and nitrogen magnetic shielding, which is determined by the big out-of-plane component of the nuclear shielding tensor. The electronic ring currents observed in the map deshield the nuclei of ring hydrogens by enforc…
Spin crossover in a catenane supramolecular system.
1995
The compound [Fe(tvp)(2)(NCS)(2)] . CH(3)OH, where tvp is 1,2-di-(4-pyridyl)-ethylene, has been synthesized and characterized by x-ray single-crystal diffraction. It consists of two perpendicular, two-dimensional networks organized in parallel stacks of sheets made up of edge-shared [Fe(II)](4) rhombuses. The fully interlocked networks define large square channels in the [001] direction. Variable-temperature magnetic susceptibility measurements and Mossbauer studies reveal that this compound shows low-spin to high-spin crossover behavior in the temperature range from 100 to 250 kelvin. The combined structural and magnetic characterization of this kind of compound is fundamental for the inte…
A Bis(diazadiene) Adduct of MoCl 2 : Mononuclear, Octahedral, Undistorted and Diamagnetic
2004
The complex [MoCl2(iPr2dad)2] (iPr2dad = iPrN=CH−CH=N−iPr) is obtained in one step by reduction of [MoCl3(THF)3] in the presence of iPr2dad. The X-ray structure reveals a relatively undistorted octahedral coordination geometry with a relative cis configuration and points to a more appropriate description of the ligands as enediamides. The NMR investigation is in agreement with the same cis structure in solution and underlines the diamagnetism of the compound, at odds with previously reported very similar complexes. A bulk magnetic susceptibility measurement further confirms the compound’s diamagnetism. No equilibrium with a dinuclear, metal-metal bonded species is apparent from the solution…
Influence of morphology in the magnetic properties of layered double hydroxides
2018
We report the controlled synthesis of magnetic CoAl and NiFe layered double hydroxides (LDHs) endowed with well-defined morphology (hexagonal and flower-like shapes) by means of modified homogeneous precipitation. These layered magnets display high crystallinity and micrometric size, thus offering a perfect scenario for the elucidation of the role exerted by distortion of the layers in their magnetic behaviour. The magnetic properties have been investigated by means of DC and AC magnetic susceptibility measurements and isothermal magnetization, demonstrating that the distortion of the nanosheets induces a magnetically more disordered behaviour, with marked spin-glass nature, independently o…
Exploring the effect of absence selection on landslide susceptibility models: A case study in Sicily, Italy
2016
Abstract A statistical approach was employed to model the spatial distribution of rainfall-triggered landslides in two areas in Sicily (Italy) that occurred during the winter of 2004–2005. The investigated areas are located within the Belice River basin and extend for 38.5 and 10.3 km 2 , respectively. A landslide inventory was established for both areas using two Google Earth images taken on October 25th 2004 and on March 18th 2005, to map slope failures activated or reactivated during this interval. Geographic Information Systems (GIS) were used to prepare 5 m grids of the dependent variables (absence/presence of landslide) and independent variables (lithology and 13 DEM-derivatives). Mul…
Mapping Susceptibility to Debris Flows Triggered by Tropical Storms: A Case Study of the San Vicente Volcano Area (El Salvador, CA)
2021
In this study, an inventory of storm-triggered debris flows performed in the area of the San Vicente volcano (El Salvador, CA) was used to calibrate predictive models and prepare a landslide susceptibility map. The storm event struck the area in November 2009 as the result of the simultaneous action of low-pressure system 96E and Hurricane Ida. Multivariate Adaptive Regression Splines (MARS) was employed to model the relationships between a set of environmental variables and the locations of the debris flows. Validation of the models was performed by splitting 100 random samples of event and non-event 10 m pixels into training and test subsets. The validation results revealed an excellent (…
Prediction of debris-avalanches and -flows triggered by a tropical storm by using a stochastic approach: An application to the events occurred in Moc…
2019
Abstract Landslides are among the most dangerous natural processes. Debris avalanches and debris flows in particular have often caused casualties and severe damage to infrastructures in a wide range of environments. The assessment of susceptibility to these phenomena may help policy makers in mitigating the associated risk and thus it has attracted special attention in the last decades. In this experiment, we assessed susceptibility to debris-avalanche and -flow landslides by using a stochastic approach. Two different modeling techniques were employed: i) Multivariate Adaptive Regression Splines (MARS) and ii) Logistic Regression (LR). Both MARS and LR allow for calculating the probability …
Evaluation of debris flow susceptibility in El Salvador (CA): a comparison between Multivariate Adaptive Regression Splines (MARS) and Binary Logisti…
2018
In the studies of landslide susceptibility assessment, which have been developed in recent years, statistical methods have increasingly been applied. Among all, the BLR (Binary Logistic Regression) certainly finds a more extensive application while MARS (Multivariate Adaptive Regression Splines), despite the good performance and the innovation of the strategies of analysis, only recently began to be employed as a statistical tool for predicting landslide occurrence. The purpose of this research was to evaluate the predictive performance and identify possible drawbacks of the two statistical techniques mentioned above, focusing in particular on the prediction of debris flows. To this aim, an…
Assessment of susceptibility to earth-flow landslide using logistic regression and multivariate adaptive regression splines: A case of the Belice Riv…
2015
Abstract In this paper, terrain susceptibility to earth-flow occurrence was evaluated by using geographic information systems (GIS) and two statistical methods: Logistic regression (LR) and multivariate adaptive regression splines (MARS). LR has been already demonstrated to provide reliable predictions of earth-flow occurrence, whereas MARS, as far as we know, has never been used to generate earth-flow susceptibility models. The experiment was carried out in a basin of western Sicily (Italy), which extends for 51 km 2 and is severely affected by earth-flows. In total, we mapped 1376 earth-flows, covering an area of 4.59 km 2 . To explore the effect of pre-failure topography on earth-flow sp…