Search results for "Syngas"
showing 4 items of 14 documents
CO2: from waste to resource for methanol-based processes
2009
This paper reports on research aiming at developing sustainable processes for the production of methanol (CH3OH) and dimethyl carbonate (DMC, (CH3)2CO3) using carbon dioxide (CO2) as a raw material. Using carbon dioxide as a raw material has several advantages; it is non-toxic, in abundant supply, and promises innovative routes to the production of commodity chemicals. Methanol and dimethyl carbonate are important products and feedstocks of the chemical industry. Methanol is produced commercially from synthesis gas, but it is also possible to use carbon dioxide as a feedstock. Conventional production of dimethyl carbonate involves the use of toxic phosgene or carbon monoxide, while the met…
Experimental study of the pyrolysis of waste bitumen for oil production
2020
Abstract This work focuses on bitumen slow pyrolysis. Mass and energy yields of oil, solid and gas were obtained from pyrolysis experiments using a semi-batch reactor in a nitrogen atmosphere, under three non-isothermal conditions (maximum temperature: 450 °C, 500 °C and 550 °C). The effect of temperature on the product yields was discussed. The gas compositions were analysed using gas chromatography (GC) and the heating value of oil and solid residue was also measured. Using a thermo-gravimetric analyser, kinetic parameters were evaluated through Ozawa-Flynn-Wall (OFW) method. Results showed that oil yield is maximum at 500 °C (50%). Moreover, gas yield increased with increasing pyrolysis …
Small Scale Gasification Application and Perspectives in Circular Economy
2018
Abstract Gasification is the process converting solid fuels as coal and organic plant matter, or biomass into combustible gas, called syngas. Gasification is a thermal conversion process using carbonaceous fuel, and it differs substantially from other thermal processes such as incineration or pyrolysis. The process can be used with virtually any carbonaceous fuel. It is an endothermic thermal conversion process, with partial oxidation being the dominant feature. Gasification converts various feedstock including waste to a syngas. Instead of producing only heat and electricity, synthesis gas produced by gasification may be transformed into commercial products with higher value as transport f…
Supercritical water gasification of waste oils as a source of syngas
2021
A huge amount of waste oil is produced worldwide. Also substantial amount of virgin oils is available that are interesting candidates for upgrading into syngas. Supercritical water gasification (SCWG) can be considered as an aqueous phase reforming process to produce syngas from oils. In this work, a variety of waste and virgin oils were gasified in a continuous down-flow autoclave reactor at supercritical conditions. Experiments were carried out at 430 °C and 660 °C, 25 MPa, with a residence time in the range 103-170 s, in order to investigate gasification and carbon efficiency, hydrogen yield and composition of the produced gas. All the analysed feedstocks were suspended in water at vario…