Search results for "TEP"
showing 10 items of 712 documents
Dissociation energies of silver clusters Agn+, n=14, 15, 16, 18
2003
A recently developed method to determine dissociation energies has been applied to positively charged silver clusters of size n=14, 15, 16 and 18. The method uses a combination of sequential and single step decays. It requires an uncalibrated thermometer which here is provided by the evaporation rate constants of the product clusters. For this purpose, earlier measurements [J. Chem. Phys. 57 (1998) 2786] are reanalyzed with the new method. The resulting dissociation energies are compared with the liquid drop values and the measured decay rate constants with expected rate constants from detailed balance theory.
Coadsorption of NRR and HER Intermediates Determines the Performance of Ru-N4 toward Electrocatalytic N2 Reduction
2021
Efficiency of the electrochemical N2 reduction reaction (NRR) to ammonia is seriously limited by the competing hydrogen evolution reaction (HER) but our current atomic-scale insight on the factors controlling HER/NRR competition are unknown. Herein we unveil the elementary mechanism, thermodynamics, and kinetics determining the HER/NRR selectivity on the state-of-the-art NRR electrocatalyst, Ru-N4 using constant potential density functional theory calculations (DFT). The calculations show that NRR and HER intermediates coadsorb on the catalyst where HER is greatly suppressed by the NRR intermediates. The first reaction step leading to either *NNH or *H determines the selectivity towards NRR…
A Lotka-type model for oscillations in surface reactions
1997
In this paper we introduce a reaction model on a lattice which leads to oscillations. The model consists of two monomolecular and one bimolecular reaction step and is related to the Lotka model. Despite the simple evolution rules, the model shows a complex behaviour (i.e. the appearance of oscillations). This offers us the opportunity to test different types of stochastic approximations and compare them with the results of a Monte Carlo simulation. The simulation is performed on a large lattice (L = 1024) in order to take long-range correlations into account. Comparing the results of this simulation with the stochastic approaches shows that only advanced numerical approximations are able to…
An automatic filtering algorithm for SURF-based registration of remote sensing images
2017
International audience; The registration of remote sensing images has been often a necessary step for further analyses of images taken at different times, different viewing geometry or with different sensors. For this task there exists many approaches. This paper focuses on the feature-based category of image registration methods. Particularly, we propose an improvement of the SURF algorithm on the point matching step. Indeed, in order to achieve a correct registration, a good matching of feature point is required. However The presence of outliers lead to a fail in the registration. Therefore, in this paper, we introduce an efficient method devoted to the detection and removal of such outli…
On a step method and a propagation of discontinuity
2019
In this paper we analyze how to compute discontinuous solutions for functional differential equations, looking at an approach which allows to study simultaneously continuous and discontinuous solutions. We focus our attention on the integral representation of solutions and we justify the applicability of such an approach. In particular, we improve the step method in such a way to solve a problem of vanishing discontinuity points. Our solutions are considered as regulated functions.
Early rehabilitation of cancer patients - a randomized controlled intervention study.
2013
Published version of an article in the journal: BMC Cancer. Also available from the publisher at: http://dx.doi.org/10.1186/1471-2407-13-9 Open access Background: Faced with a life-threatening illness, such as cancer, many patients develop stress symptoms, i.e. avoidance behaviour, intrusive thoughts and worry. Stress management interventions have proven to be effective; however, they are mostly performed in group settings and it is commonly breast cancer patients who are studied. We hereby present the design of a randomized controlled trial (RCT) evaluating the effectiveness and cost-effectiveness of an individual stress-management intervention with a stepped-care approach in several cance…
Tukivastemalli (Response to intervention model)
2021
Tukivastemalli on oppimisen ja koulunkäynnin tuen suunnittelua ja toteutusta selkeyttävä toimintatapa, jota voidaan hyödyntää minkä tahansa taidon tukemisessa kolmiportaisen tuen mallin kaikilla portailla. Tukivastemallissa tuen tavoitteiden määrittely ja kohdennettu tukitoimien suunnittelu perustuvat huolelliseen, yksilölliseen alkuarviointiin oppilaan tuen tarpeesta ja ymmärrykseen siitä, mistä oppilaan yksilöllisissä oppimisen pulmissa on kyse. Tuki kohdistetaan siihen kehitysvaiheeseen, jossa oppilas kehityksellisesti on ja niihin osataitoihin, joissa oppilaan kehitys edellyttää tukea. Oppimisen tuen suunnittelun yhteydessä suunnitellaan, miten ja kuinka usein oppimisen edistymistä ja t…
A kinematics analysis of three best 100 m performances ever.
2013
The purpose of this investigation was to compare and determine the relevance of the morphological characteristics and variability of running speed parameters (stride length and stride frequency) between Usain Bolt’s three best 100 m performances. Based on this, an attempt was made to define which factors determine the performance of Usain Bolt's sprint and, therefore, distinguish him from other sprinters. We analyzed the previous world record of 9.69 s set in the 2008 Beijing Olympics, the current record of 9.58 s set in the 2009 Berlin World Championships in Athletics and the O lympic record of 9.63 s set in 2012 London Olympics Games by Usain Bolt. The application of VirtualDub Programme …
Proton Transfer and Protein Conformation Dynamics in Photosensitive Proteins by Time-resolved Step-scan Fourier-transform Infrared Spectroscopy
2014
Monitoring the dynamics of protonation and protein backbone conformation changes during the function of a protein is an essential step towards understanding its mechanism. Protonation and conformational changes affect the vibration pattern of amino acid side chains and of the peptide bond, respectively, both of which can be probed by infrared (IR) difference spectroscopy. For proteins whose function can be repetitively and reproducibly triggered by light, it is possible to obtain infrared difference spectra with (sub)microsecond resolution over a broad spectral range using the step-scan Fourier transform infrared technique. With -10(2)-10(3) repetitions of the photoreaction, the minimum num…
PETROLOGICAL AND EXPERIMENTAL CONSTRAINTS OF THE PRE-ERUPTIVE CONDITIONS OF LA SOMMATA BASALT AND BROWN TUFFS TEPHRA (AEOLIAN ISLANDS)
2011
The principal focus of this thesis was the reconstruction of pre-eruptive conditions of two key eruptions at Vulcano island, the Brown Tuffs and the La Sommata, by combining the melt inclusion approach with phase equilibria derived by crystallization experiments. Brown Tuffs (the most energetic and widely distributed eruption of the Archipelago) were produced by several eruptions that occurred in a large age interval, 78-7.7 ka B.P. At Vulcano BT deposits crop out as proximal facies. La Sommata centre (age ca. 50 ka B.P.), is instead a basaltic scoria cone fed by one of the most primitive magmas of Aeolian Arc with ankaramitic affinity. Pyroxene-hosted melt inclusions on Lower and Intermedi…