Search results for "TEP"

showing 10 items of 712 documents

Spin Crossover and Long-Lived Excited States in a Reduced Molecular Ruby.

2020

Abstract The chromium(III) complex [CrIII(ddpd)2]3+ (molecular ruby; ddpd=N,N′‐dimethyl‐N,N′‐dipyridine‐2‐yl‐pyridine‐2,6‐diamine) is reduced to the genuine chromium(II) complex [CrII(ddpd)2]2+ with d4 electron configuration. This reduced molecular ruby represents one of the very few chromium(II) complexes showing spin crossover (SCO). The reversible SCO is gradual with T 1/2 around room temperature. The low‐spin and high‐spin chromium(II) isomers exhibit distinct spectroscopic and structural properties (UV/Vis/NIR, IR, EPR spectroscopies, single‐crystal XRD). Excitation of [CrII(ddpd)2]2+ with UV light at 20 and 290 K generates electronically excited states with microsecond lifetimes. This…

step-scan IR spectroscopychemistry.chemical_element010402 general chemistryPhotochemistry01 natural sciencesCatalysislaw.inventionChromiumSpin crossoverlawSpin CrossoverElectron paramagnetic resonanceexcited states010405 organic chemistryChemistryCommunicationOrganic ChemistryGeneral ChemistryCommunications0104 chemical sciencesMicrosecondExcited stateElectron configurationchromiummagnetic propertiesExcitationChemistry (Weinheim an der Bergstrasse, Germany)
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Images de la steppe russe et l'opinion publique française au XXe siècle

1999

steppe russe[SHS.DROIT]Humanities and Social Sciences/Law[SHS.DROIT] Humanities and Social Sciences/Lawopinion publique française[ SHS.DROIT ] Humanities and Social Sciences/Law
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IMEX schemes for pricing options under jump–diffusion models

2014

We propose families of IMEX time discretization schemes for the partial integro-differential equation derived for the pricing of options under a jump-diffusion process. The schemes include the families of IMEX-midpoint, IMEX-CNAB and IMEX-BDF2 schemes. Each family is defined by a convex combination parameter [email protected]?[0,1], which divides the zeroth-order term due to the jumps between the implicit and explicit parts in the time discretization. These IMEX schemes lead to tridiagonal systems, which can be solved extremely efficiently. The schemes are studied through Fourier stability analysis and numerical experiments. It is found that, under suitable assumptions and time step restric…

ta113Numerical AnalysisMathematical optimizationTridiagonal matrixDiscretizationApplied MathematicsJump diffusionStability (probability)Term (time)Computational MathematicsValuation of optionsConvex combinationLinear multistep methodMathematicsApplied Numerical Mathematics
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Developing a metatheoretical framework for second language development : a cultural-historical theory and dynamic systems theory perspective

2017

The main aim of this article-based dissertation is to construct and articulate a dialectical metatheoretical architecture for the study of second language development termed Purposive-Historical Systems Theory (PHiST) invoking, inter alia, the axiomatic imperatives of dynamic systems theory (DST), Vygotskian cultural-historical theory (CHT), and Pepperian root metaphor theory (RMT). Specifically, it primarily purports, first, to demonstrate the tenability of a dialectical synthesis of DST and CHT; second, to philosophize on the fundamental contours of PHiST; third, to apply a novel metatheoretical perspective, as a quintessential example, to reconceptualizing the seminal construct of the Zo…

toinen kielicausalitysecond language developmentoppiminenpurposive-historical systems theorydialecticsosiokulttuuriset tekijätpurpositivityorganicismkulttuurihistoriaVygotski Lev Semjonovitšmetatheorycultural-historical theorydynamic systems theoryemergenceontologykielen oppiminenPepper Stephen Ctimecognitive SLAcontextualismoppimisteoriatroot metaphor theoryepistemologysystems thinkingself-organizationsocial SLAzone of proximal developmentkognitiivinen kehitysspeeching event
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Using Corpus Linguistics as a research and training tool for Public Service Interpreting (PSI) in the legal sector

2017

Public Service Translation has for long been the ‘forgotten voice’ in PSI studies but it is arguably a valuable linguistic support for legal institutions and for training interpreters in the legal sector. Given that interpreters in the legal system in Italy often tend to ‘double-up’ as legal translators (to make a living) the line between the two is often hazy. Hybrid modalities like sight translation of legal and administrative documents is also a ‘borderline’ feature of these intertwined professions. The main aim of this paper is to describe how parallel and monolingual corpora can be used to train public service interpreters in double roles (translators, interpreters), namely by using co…

trainingCorpus data; Public service; intepreters; legal;intepreterscorpus linguisticsCorpus dataPublic serviceSettore L-LIN/12 - Lingua e Traduzione - Lingua Inglesediscourse markerslegalPublic Service Interpreting
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Aeolian Remobilisation of the 2011-Cordón Caulle Tephra-Fallout Deposit: Example of an Important Process in the Life Cycle of Volcanic Ash

2020

Although volcanic eruptions represent short periods in the whole history of a volcano, the large amount of loose pyroclastic material produced, combined with aeolian processes, can lead to continuous, long-lasting reworking of volcanic products. Driven by wind, these processes significantly influence the geomorphology and prolong the impacts of eruptions on exposed communities and ecosystems. Since such phenomena are of interest to scientists from a range of disciplines (e.g., volcanology, atmospheric and soil sciences), a well-defined, common nomenclature is necessary to optimise the multidisciplinary characterisation of both processes and deposits. We, therefore, first describe ash wind-r…

transport and deposition processestephra falloutlcsh:Qlcsh:Sciencewind remobilisationlithometeor classificationvolcanic ash life cycleFrontiers in Earth Science
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Educational Impairment in Social Anxiety Disorder and Post-Traumatic Stress Disorder

2020

Tant la Fòbia social (FS) com el Trastorn d’estrès posttraumàtic (TEPT) s’han associat al baix rendiment acadèmic, però els estudis previs presentaven importants limitacions metodològiques. Per a realitzar recerca epidemiològica, és útil utilitzar els registres administratius i de salut poblacionals, com els disponibles a Suècia. Per tal de desenvolupar estudis amb garanties, és important que els codis diagnòstics que contenen aquests registres siguen vàlids i fiables. Aquesta tesi per compendi d’articles té com a primer objectiu validar el codi diagnòstic de l’FS (el codi diagnòstic del TEPT ja ha sigut prèviament validat) per a després explorar, per mitjà dels registres poblacionals suecs…

traumaTEPTsocial anxiety disorderpost-traumatic stress disorder:PSICOLOGÍA [UNESCO]PTSDepidemiologyUNESCO::PSICOLOGÍAeducational impairmentsocial phobiarendiment educatiu
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Kolmas sektori sosiaalisen asuntotuotannon kentällä : ylioppilaskylä sosiaalisen pääoman lähteenä

2012

Tutkimukseni tehtävänä on selvittää kolmannen sektorin roolia sosiaalisessa asuntotuotannossa. Tarkastelen, mitä mahdollisuuksia ja haasteita asunto- ja asumispalvelutuotantoon liittyy, kun tuottajana ei ole yksityinen tai julkinen toimija. Tutkin asiaa sekä kolmannen sektorin organisaation että organisaation asiakkaiden näkökulmista, joista viimeksi mainittu saa kuitenkin enemmän painoarvoa. Hypoteesina on, että kolmannen sektorin asuntotuotanto voi vahvistaa asukkaiden yhteisöllisyyden kokemusta edistämällä verkostoitumista. Yhteisöllisyydellä taas voi olla positiivisia vaikutuksia yksilöiden sosiaalisen pääoman määrään. Tutkimuksen aineisto on kaksiosainen: ensimmäinen osa koostuu Kortep…

verkostotylioppilaskyläJyväskyläsosiaalinen asuntotuotantoyhteisöllisyyskolmas sektoriKortepohjasosiaalinen pääoma
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Vesipallo : "roiskuvaa riemua"

1999

vesiliikuntavesipallouintihengenpelastusviitepelitvesipelitpalloiluoppimateriaali
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Pelinomaisilla harjoituksilla pesäpallon taitajaksi

1999

viitepelitpelikäsityspesäpallo
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