Search results for "THERMAL"
showing 10 items of 3576 documents
Retrieval of evapotranspiration over the Alpilles/ReSeDA experimental site using airborne POLDER sensor and a thermal camera
2005
Abstract Knowledge of land surface evapotranspiration is of prime interest for environmental applications, such as optimizing irrigation water use, especially in arid and semiarid rangelands where water shortage is a critical problem. Numerous methods aiming at estimating evapotranspiration have been proposed in the literature. In the current paper, we assess the potential of the evaporative fraction based on the S-SEBI (Simplified Surface Energy Balance Index) concept for estimating instantaneous evapotranspiration, and extend this potential to the retrieval of daily evapotranspiration (ETd). To this end, a feasible and operational method is developed, which allows mapping instantaneous an…
Combustion wave structure during the MoSi2 synthesis by Mechanically-Activated Self-propagating High-temperature Synthesis (MASHS): In situ time-reso…
2006
Abstract In situ synchrotron time-resolved X-ray diffraction experiments coupled with an infrared imaging camera have been used to reveal the combustion wave structure during the production of MoSi2 by Mechanically Activated Self-propagating High-temperature Synthesis (MASHS). The fast combustion front exhibits a form described as an ‘equilibrium structure’ where the chemical reaction is the sole major driving force. In the MASHS process, oxide-free interfaces between Mo and Si nanocrystallites enhance the reaction Mo+2Si→MoSi2. Exhaustive time-resolved investigations show a possible solid-state process in the first second of the reaction within the combustion front. If preheating is added,…
Noise characterization of analog to digital converters for amplitude and phase noise measurements
2017
International audience; Improvements on electronic technology in recent years have allowed the application of digital techniques in phase noise metrology where low noise and high accuracy are required, yielding flexibility in systems implementation and setup. This results in measurement systems with extended capabilities, additional functionalities and ease of use. In most digital schemes the Analog to Digital Converters (ADCs) set the ultimate performance of the system, therefore the proper selection of this component is a critical issue. Currently, the information available in literature describes in depth the ADC features only at frequency offsets far from the carrier. However, the perfo…
Elaboration et caractérisation mécanique et physico-chimique des revêtements déposés sur des substrats en laiton par les techniques de projection the…
2019
Brass alloys are used in many applications, especially in the sanitary industrial application. In this field, the brass is coated with an electroplated chromium layer. However, the electroplating technique is achieved by means of solutions in which the chromium is in the six oxidation state. At this degree of oxidation, chromium is toxic and has the reputation of being carcinogenic. In this context, the main objective of this work is to develop functional coatings on brass substrates using new techniques namely thermal and pneumatic spraying techniques. The mechanical and physical-chemical properties are studied in order to evaluate the performances of these coatings and the potency of thei…
Comportement en fatigue thermomécanique à haute température d’un système barrière thermique texturé par laser
2020
In service life of Thermal Barrier Coating (TBC) systems for blade applications can be limited by the top-coat (TC) spallation under thermo-mechanical fatigue (TMF) loadings. To improve its TMF life, laser texturing at the bond-coat/top coat interface in the CMSX-4 Plus / γ-γ’ BC/ EB-PVD TC system has been investigated.Thanks to the study of the laser-matter interaction, it seems that the different Ni-based single crystal superalloys have similar laser ablation behaviors and they present almost no sub-surface damage after ablation. Nevertheless, the formation of melted matter near created cavities, possibly recrystallized, is often observed.Different patterns (holes, lines, grids) have been…
An algorithm for the assessment of subjective adaptive thermal comfort conditions based on multi-agent systems
2011
Thermal comfort conditions in the built environment are strictly related not only to the thermal and geometric building features and to air-conditioning systems, but also to the building destination, to its using profile and to the biological-metabolic-psychological characteristics of users. As a consequence, there is a strong claim for new models, both subjective and adaptive to the environment, in a particular holistic vision of the problem, with regards to the novel tern user-plant-building system. In such a frame, through the paper the characterization of an algorithm aimed at subjective adaptive thermal comfort evaluations, enriching the one proposed by Fanger with an adaptive approach…
The complementary structural studies of the double metal cyanide type catalysts for the ring opening polymerization of the oxiranes
2016
Przeprowadzono badania strukturalne katalizatorów dimetalocyjankowych (DMC) z dwoma rodzajami ligandów organicznych. Zaproponowano wyjaśnienie etapów przebiegu krzywych otrzymanych metodą analizy termograwimetrycznej i różnicowej kalorymetrii skaningowej (TG/DSC) badanych katalizatorów. Wykazano obecność kilku stopni związania ligandów w kompleksach DMC. Na podstawie wyników badań z wykorzystaniem absorpcji rentgenowskiej (XAS) stwierdzono, że centrum aktywne katalizatora stanowi atom cynku. W bezpośrednim sąsiedztwie atomów Zn wykryto obecność atomów Cl, natomiast w najbliższych sferach koordynacyjnych atomu Zn nie wykryto atomów tlenu.
A contribution to the study of staling of white bread: effect of water and hydrocolloid
1996
Abstract Staling of white bread at ambient temperature was studied using differential scanning calorimetry and dynamic mechanical thermal analysis. During storage, sample hydration varied slightly, from 0 to 0.4% per day, depending on packaging conditions. An increase in rigidity was observed, which was attributed both to starch retrogradation and to changes in the organization of the amorphous part of crumb. The glass transition temperature of crumb was not significantly modified by these structural changes. Hydrocolloids did not affect the overall shape of the viscoelastic behavior of crumb in the temperature range from −40°C to 80°C, and had a limited influence on the kinetics of starch …
Chiral hemicucurbit[8]uril as an anion receptor: selectivity to size, shape and charge distribution
2017
A novel eight-membered macrocycle of the hemicucurbit[n]uril family, chiral (all-R)-cyclohexanohemicucurbit[8]uril (cycHC[8]) binds anions in a purely protic solvent with remarkable selectivity. The cycHC[8] portals open and close to fully encapsulate anions in a 1 : 1 ratio, resembling a molecular Pac-Man™. Comprehensive gas, solution and solid phase studies prove that the binding is governed by the size, shape and charge distribution of the bound anion. Gas phase studies show an order of SbF6− ≈ PF6− > ReO4− > ClO4− > SCN− > BF4− > HSO4− > CF3SO3− for anion complexation strength. An extensive crystallographic study reveals the preferred orientations of the anions within the octahedral cav…
Oligoamide Foldamers as Helical Chloride Receptors-the Influence of Electron-Withdrawing Substituents on Anion-Binding Interactions.
2019
The anion-binding properties of three closely related oligoamide foldamers were studied using NMR spectroscopy, isothermal titration calorimetry and mass spectrometry, as well as DFT calculations. The 1 H NMR spectra of the foldamers in [D6 ]acetone solution revealed partial preorganization by intramolecular hydrogen bonding, which creates a suitable cavity for anion binding. The limited size of the cavity, however, enabled efficient binding by the inner amide protons only for the chloride anion resulting in the formation of a thermodynamically stable 1:1 complex. All 1:1 chloride complexes displayed a significant favourable contribution of the entropy term. Most likely, this is due to the …