Search results for "THERMODYNAMICS"

Thermodynamics and continuum fracture mechanics for nonlocal-elastic plastic materials

2002

Nonlocal elasticity is used as an improved elasticity model which engenders no crack-tip stress singularities and thus makes applicable the classical stress-based failure criteria. Considering nonlocal-elastic plastic materials exposed to softening by particle decohesion in a process surface and to subsequent surface separation by fracture, fracture mechanics is addressed within the framework of irreversible internal-variable thermodynamics in the hypothesis of small strains and arbitrary (but sufficiently regular) fracture surface (crack surface plus process surface). The state equations and the energy dissipation densities are derived for the bulk material and for the process surface, for…

Recombinant NeutraLite Avidin: a non-glycosylated, acidic mutant of chicken avidin that exhibits high affinity for biotin and low non-specific bindin…

2000

AbstractA recombinant non-glycosylated and acidic form of avidin was designed and expressed in soluble form in baculovirus-infected insect cells. The mutations were based on the same principles that guided the design of the chemically and enzymatically modified avidin derivative, known as NeutraLite Avidin. In this novel recombinant avidin derivative, five out of the eight arginine residues were replaced with neutral amino acids, and two of the lysine residues were replaced by glutamic acid. In addition, the carbohydrate-bearing asparagine-17 residue was altered to an isoleucine, according to the known sequences of avidin-related genes. The resultant mutant protein, termed recombinant Neutr…

On the thermodynamics of listric faults

2004

We investigate a novel fully coupled thermal-mechanical numerical model of the crust in order to trace the physics of interaction of its brittle and ductile layers. In a unified approach these layers develop in a natural transition as a function of the state variables pressure, deviatoric stress, temperature and strain-rate. We find that the main storage of elastic energy lies in the domain where brittle and ductile strain-rates overlap so that shear zones are attracted to this zone of maximum energy dissipation. This dissipation appears as a local heat source (shear heating). The brittle-ductile transition zone evolves through extreme weakening by thermo-mechanical feedback. The physics of…

On the phase diagram of[N(CH3)4]2ZnCl4under uniaxial stress

1992

Abstract Optical measurement and microscopic observations have been performed of single crystals of (TMA)2ZnCl4 with the aim to establish its phase diagram in the coordinates temperature-uniaxial stress σ. Stress-induced shifts of transition temperatures have been evaluated. For stresses exceeding 4.5 MPa two new monoclinic phases are reported, tentatively labeled as VIII and IX, both with the monoclinic axis b.

1980

A phenomenological theory of the Phase Distribution Chromatography (PDC)-separation effect is outlined and a theoretical equation for the measured PDC-calibration curves is given. Assuming a reversible-thermodynamical equilibrium in the polystyrene-PDC-column, only a relatively small part of the measured PDC-calibration curves could be explained: namely those running below their tangents. In order to explain the whole sigmoidal shape of the experimental curves, a theory of steady state in the system sol/gel was developed assuming deformation of the polymer coil near the gel front due to the stress related to the velocity gradient. The resulting dynamical flow-equilibrium differs highly from…

Negative Interfacial Tension in Phase-Separated Active Brownian Particles.

2015

We study numerically a model for active suspensions of self-propelled repulsive particles, for which a stable phase separation into a dilute and a dense phase is observed. We exploit the fact that for nonsquare boxes a stable "slab" configuration is reached, in which interfaces align with the shorter box edge. Evaluating a recent proposal for an intensive active swimming pressure, we demonstrate that the excess stress within the interface separating both phases is negative. The occurrence of a negative tension together with stable phase separation is a genuine nonequilibrium effect that is rationalized in terms of a positive stiffness, the estimate of which agrees excellently with the numer…

New model describing the total dispersion of dry powder agglomerates

2010

Micron and submicron particles tend to form agglomerates due to adhesive and cohesive forces. The disintegration of these dry powder agglomerates often represents a major task in powder technology. One model describing the mechanical stability of granulates is given by the planar fracture model of Rumpf. In the present work, a new model is introduced intended for applications where a complete disintegration of dry powder agglomerates is required (e.g. for pharmaceutical aerosol generation). Therefore, the breakup of every single connection inside an agglomerate is considered and the dispersion strength σdisp of model agglomerates is calculated and discussed. In order to balance the stabilit…

A review of the general theory of thermoelastic stress analysis

2003

Thermoelastic stress analysis (TSA) is now a well-known experimental technique providing information on the surface stress field in structures. Many studies have assessed the potential of the technique for a number of applications and some useful and detailed reviews of these investigations are available, focusing mainly on the experimental aspects related to the measurement of the thermoelastic signal. In this work, instead, a complete and detailed insight into the origins of the various forms of the equations describing the thermoelastic effect is given with reference to the concepts of the thermodynamic theory of a continuum. A discussion on the theory leading to the thermoelastic effec…

Fractional Viscoelasticity Under Combined Stress and Temperature Variations

2020

Nowadays polymeric materials or composites with polymeric matrices are widely used in a very wide range of applications such as aerospace, automotive, biomedical and also civil engineering. From a mechanical point of view, polymers are characterized by high viscoelastic properties and high sensitiveness of mechanical parameters from temperature. Analytical predictions in real-life conditions of mechanical behaviour of such a kind of materials is not trivial for the intrinsic hereditariness that imply the knowledge of all the history of the material at hand in order to predict the response to applied external loads. If temperature variations are also present in the materials, a reliable eval…

Nonlocal Elastic-Damage Interface Mechanical Model

2007

The paper presents a nonlocal extension of the elastic-damage interface mechanical model, which is able to describe the effects of the spatially extended microstructure on the decohesion (or fracture) process along a surface. The key feature of the proposed model is an integral constitutive relation between tractions and displacement jumps at the interface. The presence of an integral kernel brings in the model an internal length measure, which characterizes the transition from the microscale, dominated by heterogeneities and discontinuous media, to the mesoscale, characterized as an enhanced homogenized continuum with nonlocal features. The motivations and the fields of applications of the…