Search results for "THERMODYNAMICS"
showing 10 items of 2774 documents
ANALISIS KADAR BIOETANOL HASIL FERMENTASI DARI NIRA NIPAH (Nypa fruticans wurmb) ASAL PAPUA
2019
This study aims to analyze the ethanol content in fermented palm juice.This research includes the preparation of raw materials, fermentation, distillation and distillation products analyzed by gas chromatography method. Fermentation is carried out for 2, 5, 7 days, the highest level of bioethanol produced is then selected for distillation. Levels the highest fermentation process is on the 5th day with a level of 18%. Got results the final distillation is 117 mL with a level of 94% of the initial volume of 4.2 L fermentation based on measurements using an alcoholmeter while the analysis by gas chromatography yielded 93.9% levels. The density of bioethanol is 0.8232 gr / mL. The results of th…
Quantitative description of temperature induced self-aggregation thermograms determined by differential scanning calorimetry
2012
A novel thermodynamic approach for the description of differential scanning calorimetry (DSC) experiments on self-aggregating systems is derived and presented. The method is based on a mass action model where temperature dependence of aggregation numbers is considered. The validity of the model was confirmed by describing the aggregation behavior of poly(ethylene oxide)-poly(propylene oxide) block copolymers, which are well-known to exhibit a strong temperature dependence. The quantitative description of the thermograms could be performed without any discrepancy between calorimetric and van 't Hoff enthalpies, and moreover, the aggregation numbers obtained from the best fit of the DSC exper…
Assessing the Robustness of Thermoeconomic Diagnosis of Fouled Evaporators: Sensitivity Analysis of the Exergetic Performance of Direct Expansion Coi…
2016
Thermoeconomic diagnosis of refrigeration systems is a pioneering approach to the diagnosis of malfunctions, which has been recently proven to achieve good performances for the detection of specific faults. Being an exergy-based diagnostic technique, its performance is influenced by the trends of exergy functions in the “design” and “abnormal” conditions. In this paper the sensitivity of performance of thermoeconomic diagnosis in detecting a fouled direct expansion coil and quantifying the additional consumption it induces is investigated; this fault is critical due to the simultaneous air cooling and dehumidification occurring in the coil, that induce variations in both the chemical and th…
Application of advanced thermodynamics, thermoeconomics and exergy costing to a Multiple Effect Distillation plant: In-depth analysis of cost formati…
2015
Abstract The high thermal energy consumption per m3 fresh water is one of the main barriers to the spread of thermally driven desalination processes and has limited their use to applications in countries with high reserves of fossil fuels or to specific technological solutions like dual purpose cogeneration plants and solar desalination systems. Being energy conversion efficiency a major issue to improve the performance of thermally driven desalination plants, thermoeconomic analysis has been attracting the efforts of researchers for the identification of margins for process improvement. In this paper a rigorous exergy and thermoeconomic analysis is presented for an 8 effect forward feed Mu…
Performance maps for an air-cooled air conditioning system as a preliminary instrument for the diagnosis of evaporator fouling
2019
Abstract During the past few decades, there has been increased interest in the development of automated approaches for detecting and diagnosing faults in air conditioning systems. Among them, thermoeconomic diagnosis is a technique which involves the use of exergy analysis. As a first step towards improving its performance, this work is focused on the thermodynamic and exergy analysis of a direct expansion air conditioning system used in small commercial building applications. The analysis was carried out by means of experimental activities on a 17.5 kW rooftop unit installed at the Herrick Laboratories, Purdue University, Indiana (USA). The system under investigation was equipped with a va…
Performance Analysis of a RED-MED Salinity Gradient Heat Engine
2018
A performance analysis of a salinity gradient heat engine (SGP-HE) is presented for the conversion of low temperature heat into power via a closed-loop Reverse Electrodialysis (RED) coupled with Multi-Effect Distillation (MED). Mathematical models for the RED and MED systems have been purposely developed in order to investigate the performance of both processes and have been then coupled to analyze the efficiency of the overall integrated system. The influence of the main operating conditions (i.e., solutions concentration and velocity) has been quantified, looking at the power density and conversion efficiency of the RED unit, MED Specific Thermal Consumption (STC) and at the overall syste…
Exergy analysis of reverse electrodialysis
2018
Abstract Reverse electrodialysis in closed loop configurations is a promising membrane technology in the energy conversion and storage fields. One of the main advantages of closed-loop reverse electrodialysis is the possibility of using a wide range of operating concentrations, flow rates and different salts for generating the salinity gradient. In this work, an original exergy analysis of the reverse electrodialysis process was carried out in order to investigate reverse electrodialysis performance in terms of energetic and exergetic efficiency parameters in a wide range of operating conditions. A mono-dimensional model of the reverse electrodialysis process was developed, in which all sou…
Determination of transport and kinetic properties in self-propagating high-temperature synthesis
2007
International audience; Exothermic reactions in solid powders are analyzed using the usual macroscopic modeling based on the heat transfer equation coupled to an Arrhenius type of dynamics. This problem have important applications in the synthesis of intermetallics and ceramic materials which occur when a high temperature reaction wave propagates throughout the system. Understanding the mechanism of such processes are thus crucial in mastering real laboratory experiments. We first analyze the model, both theoretically and numerically, for a set of representative parameters. We then use traditional data analyses procedures to estimate from the temperature profiles the same set of representat…
Development of a combined solver to model transport and chemical reactions in catalytic wall-flow filters
2017
Abstract In this work, we develop a non-isothermal model for diesel particulate filters including exothermic and competing chemical reactions. We begin with an isothermal, single-reaction model and we gradually increase its complexity. By comparing various models, we aim at establishing the minimum degree of complexity required to effectively model the system under investigation. Based on the numerical simulations, we conclude that isothermal models are adequate only if the temperature of the catalyst is, at all times, completely below or completely above a critical temperature. However, if the goal is to predict the critical temperature, only non-isothermal models should be used. The resul…
Effect of Boundary Conditions on the Hydrogen Absorption in a Metal Hydride Reactor
2018
In this paper, a numerical study of the heat and mass transfer in a metal hydride reactor is presented. The reaction within the metal hydride reactor is exothermic. That makes the hydriding process less effective. Thus, a cooling system is needed to reduce the temperature in order to increase the amount of the absorbed hydrogen. The geometry of the studied reactor is cylindrical with (H=3cm) of height and (R=5cm) of radius. A heat exchanger is considered in the lateral and base walls. The transfer is considered two-dimensional and transient. The governing equations of the transfer phenomenon are based on the conservation principle of mass, momentum and energy. Using the finite volume method…