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Thermal stability and enhanced thermoelectric properties of the tetragonal tungsten bronzes Nb8-xW9+xO47 (0 <x <5)

2017

Thermoelectric materials are believed to play a fundamental role in the energy field over the next years thanks to their ability of directly converting heat into usable electric energy. To increase their integration in the commercial markets, improvements of the efficiencies are needed. At the same time, cheap and non-toxic materials are required along with easily upscalable production cycles. Compounds of the tetragonal tungsten bronze (TTB) series Nb8-xW9+xO47 fulfill all these requirements and are promising materials. Their adaptive structure ensures glass-like values of the thermal conductivity, and the substitution on the cation side allows a controlled manipulation of the electronic p…

Materials scienceEQUILIBRIATITANIUM-OXYGEN SYSTEMCRYSTALLOGRAPHIC SHEARchemistry.chemical_elementNanotechnology02 engineering and technologyTemperature cyclingThermal treatmentTungsten010402 general chemistry01 natural sciencesTHERMOPOWERPHYSICSTetragonal crystal systemThermal conductivityThermoelectric effectMETAL-OXIDESGeneral Materials ScienceThermal stabilityCRYSTAL-STRUCTURESRenewable Energy Sustainability and the EnvironmentMOLYBDENUMGeneral ChemistryPERFORMANCE021001 nanoscience & nanotechnologyThermoelectric materials0104 chemical sciencesChemical engineeringchemistry0210 nano-technologyPB
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