Search results for "TP1080-1185"
showing 2 items of 2 documents
Long-term ISO 23936-2 sweet oil ageing of HNBR
2021
Abstract A hydrogenated nitrile butadiene rubber (HNBR) compound is subjected to ageing in a simulated oil and gas environment in accordance with ISO 23936-2 standard at two elevated temperatures (130 °C and 150 °C) for a period of up to 9 months. Shore D hardness, thermal expansion, dynamic mechanical analysis (DMA), Fourier transform infrared (FTIR) spectroscopy, compression and compression set (CS) measurements are made before and after the chemical exposure. The hardness, modulus at short times, degree of relaxation and CS increases while the coefficient of thermal expansion in HNBR tends to decrease with ageing time and temperature. Temperature is shown to impose a greater effect on th…
Gas Transport in Interacting Planar Brushes
2021
Recent experiments on melts of spherical nanoparticles (NPs) densely grafted with polymer chains show enhanced gas transport relative to the neat polymer (without NPs). As a means of understanding this unexpected behavior, we consider here the simpler case of two interacting planar brushes, under conditions representing a polymer melt far below its critical point (i.e., where the "free volume" or holes act akin to a poor solvent). Computer simulations illustrate, in agreement with mean-field ideas, that the density profile far away from the walls is flat but with a value that is marginally larger than the corresponding polymer melt under identical state conditions. We find that tracer parti…