Search results for "TRIF"

showing 10 items of 1419 documents

Molecular Mechanism of ATP Hydrolysis in an ABC Transporter

2018

Hydrolysis of nucleoside triphosphate (NTP) plays a key role for the function of many biomolecular systems. However, the chemistry of the catalytic reaction in terms of an atomic-level understanding of the structural, dynamic, and free energy changes associated with it often remains unknown. Here, we report the molecular mechanism of adenosine triphosphate (ATP) hydrolysis in the ATP-binding cassette (ABC) transporter BtuCD-F. Free energy profiles obtained from hybrid quantum mechanical/molecular mechanical (QM/MM) molecular dynamics (MD) simulations show that the hydrolysis reaction proceeds in a stepwise manner. First, nucleophilic attack of an activated lytic water molecule at the ATP γ-…

0301 basic medicinehydrolyysiStereochemistryGeneral Chemical EngineeringATP-binding cassette transporterbiomolekyylitCatalysis03 medical and health scienceschemistry.chemical_compoundHydrolysisNucleophileATP hydrolysisMoleculeQD1-999ta116ta1182General ChemistryadenosiinitrifosfaattiChemistry030104 developmental biologychemistryATP hydrolysisNucleoside triphosphateproteiinitABC transportermolecular mechanismAdenosine triphosphateResearch ArticleACS Central Science
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Effect of oocyte vitrification on embryo quality: time-lapse analysis and morphokinetic evaluation.

2017

To analyze whether oocyte vitrification may affect subsequent embryo development from a morphokinetic standpoint by means of time-lapse imaging.Observational cohort study.University-affiliated private IVF center.Ovum donation cycles conducted with the use of vitrified (n = 631 cycles; n = 3,794 embryos) or fresh oocytes (n = 1,359 cycles; n = 9,935 embryos) over 2 years.None.Embryo development was analyzed in a time-lapse imaging incubator. The studied variables included time to 2 cells (t2), 3 cells (t3), 4 cells (t4), 5 cells (t5), morula (tM), and cavitated, early, and hatching blastocyst (tB, tEB, tHB) as well as 2nd cell cycle duration (cc2 = t3 - t2). All of the embryos were classifie…

0301 basic medicinemedicine.medical_specialtyEmbryonic DevelopmentBiologyTime-Lapse ImagingAndrologyCohort Studies03 medical and health sciences0302 clinical medicineImage Interpretation Computer-AssistedmedicineHumansVitrificationBlastocystEmbryo ImplantationCells CulturedCryopreservation030219 obstetrics & reproductive medicineEmbryogenesisObstetrics and GynecologyEmbryoOocyteBlastulaEmbryo MammalianOvum donationSurgery030104 developmental biologymedicine.anatomical_structureReproductive Medicineembryonic structuresOocytesFemaleEmbryo qualityFertility and sterility
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Analysis of the morphological dynamics of blastocysts after vitrification/warming: defining new predictive variables of implantation

2017

Objective To describe the morphological dynamics of vitrified/warmed blastocysts and to identify quantitative morphological variables related to implantation. Subsequently, by using the most predictive parameters, to develop a hierarchical model by subdividing vitrified/warmed blastocysts into categories with different implantation potentials. Design Observational, retrospective, cohort study. Setting University-affiliated private IVF center. Patient(s) The study included 429 vitrified/warmed blastocysts with known implantation data, which were evaluated by time-lapse imaging. Blastocysts were routinely placed in EmbryoScope (Vitrolife) immediately after warming until transfer. Intervention…

0301 basic medicinemedicine.medical_specialtyHot TemperaturePregnancy RateEmbryonic DevelopmentBiologyLogistic regressionTime-Lapse ImagingAndrology03 medical and health sciences0302 clinical medicinePregnancymedicineHumansInner cell massVitrificationEmbryo ImplantationBlastocystBlastocyst implantationreproductive and urinary physiologyRetrospective Studies030219 obstetrics & reproductive medicineInfant NewbornOutcome measuresObstetrics and GynecologyPrognosisVitrificationConfidence intervalSurgeryBlastocyst030104 developmental biologymedicine.anatomical_structureReproductive MedicineInfertilityembryonic structuresFemalePredictive variablesFertility and Sterility
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EV-TRACK: transparent reporting and centralizing knowledge in extracellular vesicle research

2017

We argue that the field of extracellular vesicle (EV) biology needs more transparent reporting to facilitate interpretation and replication of experiments. To achieve this, we describe EV-TRACK, a crowdsourcing knowledgebase (http://evtrack.org) that centralizes EV biology and methodology with the goal of stimulating authors, reviewers, editors and funders to put experimental guidelines into practice.

0301 basic medicineminimum informationblood-plasmaphysiology [Extracellular Vesicles]Biomedical ResearchInternationalityComputer sciencephenotype[SDV]Life Sciences [q-bio]MedizinexosomesCrowdsourcingBioinformaticsBiochemistry03 medical and health sciencesExtracellular VesiclesultracentrifugationBiological propertycancerddc:610resolution flow-cytometryMolecular Biologysubpopulationsbusiness.industrybiological-propertiesCell BiologyExtracellular vesicleData scienceDatabases BibliographicReplication (computing)030104 developmental biologycellsbusinessBiotechnology
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A UHPLC-UV Method to Quantify Skin Deposition and Transdermal Permeation of Tizanidine Hydrochloride

2015

Tizanidine hydrochloride is an α2-adrenergic agonist used for the symptomatic relief of spasticity associated with multiple sclerosis or with spinal cord injury or disease. The objective of this study was to develop an isocratic, robust and sensitive ultra-high performance liquid chromatography method using UV detection for use in a project to develop a transdermal therapeutic system to deliver tizanidine across the skin. Isocratic separation was achieved using a C18 column and a mobile phase comprising a 80:20 mixture of 0.004% trifluoroacetic acid in water and MeCN (pH* 3.2) at a flow rate of 0.2 mL min(-1) Tizanidine eluted at 1.499 min and the total run time was 2 min. The method was sp…

030226 pharmacology & pharmacy01 natural sciencesClonidinePermeabilityAnalytical ChemistryMatrix (chemical analysis)03 medical and health scienceschemistry.chemical_compound0302 clinical medicineLimit of DetectionmedicineTrifluoroacetic acidAnimalsChromatography High Pressure LiquidSkinTransdermalLiquid ChromatographyDetection limitChromatographyChemistryElution010401 analytical chemistryReproducibility of ResultsGeneral MedicineSymptomatic relief0104 chemical sciencesTizanidineSpectrophotometry UltravioletTizanidine Hydrochloridemedicine.drugJournal of Chromatographic Science
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The effect of peracetic acid on microbial community, water quality, nitrification and rainbow trout (Oncorhynchus mykiss) performance in recirculatin…

2020

Abstract Microbial biofilters control water quality and enable the overall function of recirculation aquaculture systems (RAS). Changes in environmental conditions can affect the abundance and interactions of the diverse microbial populations of the biofilter, affecting nitrification of harmful ammonium and thus fish health. Here, we examined the effect of different application frequencies (0, 1, 2 and 4 times per week) of a common disinfectant, peracetic acid (PAA, applied 1.1 mg l−1 twice per day), on biofilter microbial communities, focusing especially on nitrifying microbial groups and using a high throughput sequencing of 16S rRNA gene and quantitative PCR (qPCR). In addition, we measu…

0303 health sciencesbusiness.industry04 agricultural and veterinary sciencesbiochemical phenomena metabolism and nutritionAquatic ScienceComammoxBiology03 medical and health scienceschemistry.chemical_compoundchemistryAquacultureMicrobial population biologyPeracetic acidBiofilter040102 fisheries0401 agriculture forestry and fisheriesAmmoniumNitrificationFood scienceWater qualitybusiness030304 developmental biologyAquaculture
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CCDC 2211279: Experimental Crystal Structure Determination

2023

Related Article: Anssi Peuronen, Anni Taponen, Elina Kalenius, Ari Lehtonen, Manu Lahtinen|2023|Angew.Chem.,Int.Ed.|62|e202215689|doi:10.1002/anie.202215689

11'1''-[(246-trimethylbenzene-135-triyl)tris(methylene)]tris(14-diazabicyclo[2.2.2]octan-1-ium) iodide bis(bis(trifluoromethanesulfonyl)azanide) acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1901898: Experimental Crystal Structure Determination

2023

Related Article: Antti J. Neuvonen, Dimitris Noutsias, Filip Topić, Kari Rissanen, Tamás Földes, Imre Pápai, Petri M. Pihko|2019|J.Org.Chem.|84|15009|doi:10.1021/acs.joc.9b01980

2-[({2-[2-({[35-bis(trifluoromethyl)phenyl]carbamoyl}amino)-4-(trifluoromethyl)phenoxy]-23-dihydro-1H-inden-1-yl}carbamothioyl)amino]-NN-dimethylcyclohexan-1-aminium diphenyl phosphate toluene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1901895: Experimental Crystal Structure Determination

2023

Related Article: Antti J. Neuvonen, Dimitris Noutsias, Filip Topić, Kari Rissanen, Tamás Földes, Imre Pápai, Petri M. Pihko|2019|J.Org.Chem.|84|15009|doi:10.1021/acs.joc.9b01980

2-[({2-[2-({[35-bis(trifluoromethyl)phenyl]carbamoyl}amino)-4-(trifluoromethyl)phenoxy]-23-dihydro-1H-inden-1-yl}carbamothioyl)amino]-NN-dimethylcyclohexan-1-aminium fluoride cyclopentane unknown solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 653860: Experimental Crystal Structure Determination

2008

Related Article: A.P.Piccionello, A.Pace, S.Buscemi, N.Vivona, M.Pani|2008|Tetrahedron|64|4004|doi:10.1016/j.tet.2008.02.047

2-amino-4-trifluoromethyl-5-benzoyl-1H-imidazoleSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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