Search results for "TRIP"
showing 10 items of 2134 documents
Modelling of phase boundaries for large industrial FZ silicon crystal growth with the needle-eye technique
2003
In order to facilitate the numerical calculations of the phase boundaries in large industrial floating zone silicon crystal growth with the needle-eye technique, the chain of improved mathematical models is developed. The phase boundaries are solved in a partly transient way and the modelling improvements cover the open melting front, the inner triple point and the free melt surface. The view factors model is applied for the radiative heat transfer. The electromagnetic field is calculated with account of a multiple-slit inductor.
Rigorous investigation of RF breakdown effects in high power microstrip passive circuits
2009
This work presents a new rigorous investigation of corona effects in microstrip components. To carry out the investigation, a new software tool has been developed. The new tool first calculates the electromagnetic fields in complex microstrip structures using a Volume Integral Equation (VIE) formulation. Novel numerical techniques have been incorporated in the VIE to increase the accuracy during the computation of the electromagnetic fields. This includes novel techniques introduced to treat the singularities of the Green's functions. Once the electromagnetic fields are computed accurately, corona effects in the relevant structures are investigated. For this, a numerical solution of the fre…
Photoinduced interfacial electron injection in RuN3–TiO2 thin films: Resolving picosecond timescale injection from the triplet state of the protonate…
2008
Using femtosecond transient absorption spectroscopy we have studied light-induced electron injection from the sensitizer RuN3 and its partly deprotonated tetrabutylamonium salt to nano-structured TiO2 film. Previous studies have suggested significant differences in electron injection dynamics for these dyes and some results have indicated that aggregation of the sensitizer may lead to slow injection. By measuring transient absorption spectra and kinetics of RuN3 and RuN3-TBA in solution and attached to TiO2 film we show that the electron injection dynamics are very similar for the two forms of the dye and that aggregation has only moderate effects on the electron transfer dynamics. (c) 2008…
Electron Transfer from the Singlet and Triplet Excited States of Ru(dcbpy)2(NCS)2into Nanocrystalline TiO2Thin Films
2002
Time-resolved absorption spectroscopy was used to study the femtosecond and picosecond time scale electron injection from the excited singlet and triplet states of Ru(dcbpY)(2)(NCS)(2) (RuN3) into titanium dioxide (TiO2) nanocrystalline particle film in acetonitrile. The fastest resolved time constant of similar to30 fs was shown to reflect a sum of two parallel ultrafast processes, nonergodic electron transfer (ET) from the initially excited singlet state of RuN3 to the conduction band of TiO2 and intersystem crossing (ISC). The branching ratio of 1.5 between the two competing processes gives rate constants of 1/50 fs(-1) for ET and 1/75 fs(-1) for ISC. Following the ultrafast processes, a…
Ab initio calculations of zero-field splitting parameters in linear polyacenes
2003
Abstract The results of ab initio calculations of zero-field splitting (ZFS) parameters are presented for the linear polyacenes from benzene to pentacene. We show how the electron spin–spin (SS) parameters can be efficiently obtained from restricted high-spin open-shell wave functions (ROHF), and present calculations of these, comparing with the results of a recent multi-configurational self-consistent field approach. The SS parameters are obtained from electron SS coupling strengths evaluated as expectation values over the wave functions and from state-to-state spin–orbit (SO) interactions. The results for the two lowest triplet states of naphthalene demonstrate that excellent values can b…
Spin State and Ligand Dissociation in [CpCoL2] Complexes (L = PH3, H2C=CH2): A Computational Study
1999
International audience; The relative energies of [CpCoL] compounds (L = PH3, H2C=CH2) were calculated at the DFT/B3LYP level of theory. The triplet spin state was found to be favored over the singlet by between 33.0 and 21.0 kcal mol−1 for both fixed and optimized geometries. The basis set size was found to be important for the energy calculations, particularly when the energetics of ligand dissociation was examined. The role of the triplet spin state in facilitating the ligand dissociation process is discussed.
Analysis of fumonisins B1, B2 and B3 in corn-based baby food by pressurized liquid extraction and liquid chromatography/tandem mass spectrometry
2008
A sensitive and reliable method using pressurized liquid extraction (PLE) and liquid chromatography (LC)/electrospray ionization (ESI) tandem mass spectrometry with a triple quadrupole (QqQ) analyzer has been developed for the analysis of fumonisin B(1) (FB(1)), fumonisin B(2) (FB(2)) and fumonisin B(3) (FB(3)) in corn-based baby foods. Influence of several extraction parameters that affect PLE efficiency such as temperature, pressure, solvent extraction, number of cycles and dispersant/clean-up agents were studied. The selected PLE operating method was: 3g of sample was packed into 11 ml stainless-steel cell and fumonisins were extracted with methanol at 40 degrees C, 34 atm in one cycle o…
Effects of acute amitriptyline administration on memory, anxiety and activity in male and female mice
2002
The effects of acute administration of amitriptyline on memory consolidation in male and female CD1 mice were investigated. Three doses of this tricyclic antidepressant (7.5, 15 and 30 mg/kg) were administered immediately after inhibitory avoidance training. Forty-five minutes after injection, subjects explored the elevated plus-maze for five minutes. Subjects were tested for avoidance twenty-four hours later. Amitriptyline impaired inhibitory avoidance consolidation at doses 7.5, 15 and 30 mg/kg in males, and at doses 7.5 and 30 mg/kg in females. In the elevated plus-maze, amitriptyline had no effect on anxiety (percentage of open arm entries) and induced a dose-dependent impairment of act…
The periods of the generalized Jacobian of a complex elliptic curve
2015
Abstract We show that the toroidal Lie group G = ℂ2/Λ, where Λ is the lattice generated by (1, 0), (0, 1) and (τ̂, τ͂), with τ̂ ∉ ℝ, is isomorphic to the generalized Jacobian JL of the complex elliptic curve C with modulus τ̂, defined by any divisor class L ≡ (M) + (N) of C fulfilling M − N = [℘ (τ͂) : ℘´(τ͂) : 1] ∈ C. This follows from an apparently new relation between the Weierstrass sigma and elliptic functions.
Deviations in pedestrian itineraries in urban areas: a method to assess the role of environmental factors
2010
Walking has long been neglected in urban-mobility research, but it is now making its way into numerous studies using various approaches. Empirical data are often processed in well-known models of flow allocation to study the behaviour of pedestrians and to identify their preferences. However, these models assume that route choices are predetermined at the start of each trip and do not admit any possible intervening decision along these trips. We propose to overcome this limitation through a new method for the analysis of pedestrian behaviour. This method, which we call ‘deviation analysis’ consists of (1) identifying the intersections from which a pedestrian has chosen a route longer than …