Search results for "Tact"
showing 10 items of 1313 documents
Solidification of syndiotactic polystyrene by a continuous cooling transformation approach
2007
Syndiotactic polystyrene (sPS) was solidified from the melt under drastic conditions according to a continuous cooling transformation methodology developed by the authors, which covered a cooling rate range spanning from approximately 0.03 to 3000 °C/s. The samples produced, structurally homogeneous across both their thickness and surface, were analyzed by macroscopic methods, such as density, wide-angle X-ray diffraction (WAXD), and microhardness (MH) measurements. The density was strictly related to the phase content, as confirmed by WAXD deconvolution. The peculiar behavior encountered (the density first decreasing and then increasing with the cooling rate) was attributed to the singular…
An experimental methodology to study polymer crystallization under processing conditions. The influence of high cooling rates
2002
Abstract A new experimental route for investigating polymer crystallization under very high cooling rates (up to 2000°C/s) is described. A complete and exhaustive description of the apparatus employed for preparing thin quenched samples (100– 200 μm thick) is reported, the cooling mechanism and the temperature distribution across sample thickness is also analysed, showing that the final structure is determined only by the thermal history imposed by the fast quench apparatus. Details concerning the characterization techniques used to probe the final structure are reported, including density measurements and wide angle X-ray diffraction patterns. Experimental results concerning isotactic poly…
Isotactic polypropylene solidification under pressure and high cooling rates. A master curve approach
2000
Solidification in industrial processes very often involves flow fields, high thermal gradients and high pressures: the development of a model able to describe the polymer behavior becomes complex. Recently a new equipment has been developed and improved to study the crystallization of polymers when quenched under pressure. An experimental apparatus based on a modified, special injection moulding machine has been employed. Polymer samples can be cooled at a known cooling rate up to 100 °C/s and under a constant pressure up to 40 MPa. Density, Micro Hardness (MH), Wide angle X-ray diffraction (WAXD), and annealing measurements were then used to characterize the obtained sample morphology. Res…
Numerical analysis of masonry structures via interface models
2001
The present paper is devoted to the theoretical formulation and numerical implementation of an interface model suitable to simulate the behavior of mortar joints in masonry structures. The interface laws are formulated in the framework of elasto-plasticity for non-standard materials in order to simulate the softening response which occurs along the decohesion process in presence of shear and tension tractions. A variable material dilatancy parameter is introduced together with a further geometrical dilatancy related to the roughness of contact surfaces after joint fracture. An asperity model is adopted with the aim to describe the evolution of the contact surface shape during the loss of co…
An interface model for analysis of deformation behaviour of discontinuities
1996
An interface constitutive model is presented accounting for slip and sliding effects and also for dilatancy phenomena. The microslip effects are described by considering spherical asperity interaction with variation of contact area and generation of progressive or reverse slip zones. The incremental constitutive equations are derived with proper memory rules accounting for generation and annihilation of particular slip zones during the process of variable loading. It is further assumed that sliding of spherical contacts occurs along large asperities whose slope varies due to the wear process. The predicted shear and dilatancy curves are shown to provide close quantitative simulation of avai…
Co-occurrence of discourse markers in English : from juxtaposition to composition
2019
Abstract In this paper, we report on a qualitative analysis of co-occurring discourse markers, that is, sequences of adjacent discourse markers that belong to the same unit but may express different functions. We examine several formal and functional features of these co-occurring strings on the basis of corpus examples extracted from conversational data in English. In particular, we focus on scope, meaning-in-context (or functions), syntactic category and position. Our analysis reveals several degrees of integration: differences in scope allow us to differentiate juxtaposition and combination of markers. In the case of combination, difference in meaning integration allows us to distinguish…
BIEM-based variational principles for elastoplasticity with unilateral contact boundary conditions
1998
The structural step problem for elastic-plastic internal-variable materials is addressed in the presence of frictionless unilateral contact conditions. Basing on the BIEM (boundary integral equation method) and making use of deformation-theory plasticity (through the backward-difference method of computational plasticity), two variational principles are shown to characterize the solution to the step problem: one is a stationarity principle having as unknowns all the problem variables, the other is a saddle-point principle having as unknowns the increments of the boundary tractions and displacements, along with the plastic strain increments in the domain. The discretization by boundary and i…
The symmetric boundary element method for unilateral contact problems
2008
Abstract On the basis of the boundary integral equation method, in its symmetric formulation, the frictionless unilateral contact between two elastic bodies has been studied. A boundary discretization by boundary elements leads to an algebraic formulation in the form of a linear complementarity problem. In this paper the process of contact or detachment is obtained through a step by step analysis by using generalized (weighted) quantities as the check elements: the detachment or the contact phenomenon may happen when the weighted traction or the weighted displacement is greater than the weighted cohesion or weighted minimum reference gap, respectively. The applications are performed by usin…
Objective assessment of the effect of pupil size upon the power distribution of multifocal contact lenses
2017
AIM: To analytically assess the effect of pupil size upon the refractive power distributions of different designs of multifocal contact lenses. METHODS: Two multifocal contact lenses of center-near design and one multifocal contact lens of center-distance design were used in this study. Their power profiles were measured using the NIMO TR1504 device (LAMBDA-X, Belgium). Based on their power profiles, the power distribution was assessed as a function of pupil size. For the high addition lenses, the resulting refractive power as a function of viewing distance (far, intermediate, and near) and pupil size was also analyzed. RESULTS: The power distribution of the lenses was affected by pupil siz…
Plural Paths for Interweaving Diversity in Palermo
2008
The most recent ethnic movements and cultural contacts are modifying the city nature all over the world, and in these years even the most fringe European areas are witnessing an increase in cultural and social mixité. Currently we can assert that the city is not an unitary system any more, instead is composed of multiple (often non-homogeneous) groups which express new forms and demands of space use. In this context of fast changes, the various ethnic groups coming to European cities are not the only stakeholders of diversity. There are also cultural groups which have remained separate until now, each one rooted in a restricted part of the city, according to models that are obsolete nowaday…