Search results for "Tally"
showing 10 items of 151 documents
Sharp estimate on the inner distance in planar domains
2020
We show that the inner distance inside a bounded planar domain is at most the one-dimensional Hausdorff measure of the boundary of the domain. We prove this sharp result by establishing an improved Painlev\'e length estimate for connected sets and by using the metric removability of totally disconnected sets, proven by Kalmykov, Kovalev, and Rajala. We also give a totally disconnected example showing that for general sets the Painlev\'e length bound $\kappa(E) \le\pi \mathcal{H}^1(E)$ is sharp.
Removable sets for intrinsic metric and for holomorphic functions
2019
We study the subsets of metric spaces that are negligible for the infimal length of connecting curves; such sets are called metrically removable. In particular, we show that every totally disconnected set with finite Hausdorff measure of codimension 1 is metrically removable, which answers a question raised by Hakobyan and Herron. The metrically removable sets are shown to be related to other classes of "thin" sets that appeared in the literature. They are also related to the removability problems for classes of holomorphic functions with restrictions on the derivative.
Reversible complexation of ethylene by a silylene under ambient conditions.
2014
Treatment of toluene solutions of the silylenes Si(SArMe6)2 (ArMe6 = C6H3-2,6(C6H2-2,4,6-Me3)2, 1) or Si(SArPri4)2 (ArPri4 = C6H3-2,6(C6H3-2,6-Pri2)2, 2) with excess ethylene gas affords the siliranes (ArMe6S)2tiebar above startSiCH2tiebar above endCH2 (3) or (ArPri4S)2tiebar above startSiCH2tiebar above endCH2 (4). Silirane 4 evolves ethylene spontaneously at room temperature in toluene solution. A Van’t Hoff analysis by variable-temperature 1H NMR spectroscopy showed that ΔGassn = −24.9(2.5) kJ mol–1 for 4. A computational study of the reaction mechanism using a model silylene Si(SPh)2 (Ph = C6H5) was in harmony with the Van’t Hoff analysis, yielding ΔGassn = −24 kJ mol–1 and an activatio…
Rapid Catalytic Water Disinfection from Earth Abundant Ca 2 Fe 2 O 5 Brownmillerite
2021
Water disinfection is a crucial challenge for humanity. Approaches that are effective, cheap, environmentally friendly, and do not promote gene exchange between bacteria are urgently required. Strongly oxidizing radicals are highly promising to achieve this as they lead to bacterial activation at high efficiencies. However, sources to consistently generate these radicals are limited to high energy UV/H2O2 treatments requiring a large energy input. Here the use of abundant, cheap, brownmillerite (Ca2Fe2O5) is demonstrated as an efficient radical generation material under dark conditions, showing a seven order of magnitude decrease in bacterial concentration over 10 min. This decrease is attr…
Glucose as an Eco‐Friendly Reductant in a One‐Pot Synthesis of 2,3‐Dihydroquinazolin‐4(1 H )‐ones
2020
Insulating Building Components Made from a Mixture of Waste and Vegetal Materials: Thermal Characterization of Nine New Products
2021
Nowadays, energy efficiency and sustainability are the fulcra of building policies. These policies promote the use of new technologies and materials that can reduce the primary energy involved and the environmental costs of construction, guarantying at the same time a high level of comfort for the building’s occupants. Synergy between previous construction techniques and the use of new materials should be pursued by employing materials with a low environmental impact and optimal thermal insulation properties. Within this framework, new materials derived from the agriculture sector, and waste or recycling products from the industrial/agricultural sectors have been studied. The aim of this pa…
Towards the implementation of circular economy in the water softening industry: A technical, economic and environmental analysis
2020
Abstract To reduce the environmental impact of the industrial sectors, circular strategies should be implemented to purify the effluents and recover raw materials. In this context, a novel integrated methodological approach is proposed to identify the most suitable strategy to improve the sustainability of the water softening industry via the treatment and recycling of the produced wastewater. Different concentration technologies and energy supply systems are compared to find economically feasible and environmentally friendly treatment systems. The investigated chains present the same pre-treatment step (nanofiltration and crystallization) and different concentration technologies: Multi-Eff…
The care crisis in Spain: an analysis of the family care situation in mental health from a professional psychosocial perspective
2019
ABSTRACTThe aim of this article is to investigate the importance of family care in mental health and identify the shortcomings of the Spanish model of health care for the mentally ill. The empirica...
Immobilised Humic Substances as Low-Cost Sorbents for Emerging Contaminants
2021
Environmental pollution with contaminants of emerging concern (CECs) is a worldwide problem that is receiving increasing attention. Although these substances have been released in the aquatic environment for a long time, wastewater treatment plants are still incapable of removing emerging contaminants completely. Consequently, trace metals, metalloids and pharmaceuticals, as well as surfactant leftovers, are often found in environmental samples. Environmentally friendly and cost-effective sorbents such as humic substances can be used for purification if their sorption properties are increased by immobilization. To our knowledge, immobilized humic substances have not been widely studied as s…
The effect of an eco-label on the booking decisions of air passengers
2022
Abstract In the last few years there has been an increasing attempt to find solutions on how to mitigate the environmental impacts of air travel. Behavioral change has hereby been identified as the measure with the most significant impact. One way to encourage behavioral change is the use of eco-labels. Eco-labels have, to date, received scant attention in the aviation industry, and their effect on air travel behavior is still largely unknown. This study explores the effect of an eco-label on the booking decisions of passengers. We conduct a stated choice experiment with 553 air passengers. Our findings show that providing passengers with an eco-label leads to behavioral change, as the labe…