Search results for "Temperature"
showing 10 items of 3798 documents
Liquid−Liquid Equilibria for the System 1-Methyl Propyl Ethanoate (1) + Acetic Acid (2) + Water (3) at (283.15 and 323.15) K
2009
Liquid−liquid equilibrium (LLE) data for the system 1-methyl propyl ethanoate + acetic acid + water were measured at temperatures of (283.15 and 323.15) K. The temperature influence on the LLE data is very small in the temperature range studied. The NRTL and UNIQUAC models were used to correlate the data for both ternary systems. The interaction parameters obtained from both models successfully correlated the equilibrium compositions.
Sample Preparation Improvement in Polycyclic Aromatic Hydrocarbons Determination in Olive Oils by Gel Permeation Chromatography and Liquid Chromatogr…
2005
Abstract The determination of 15 polycyclic aromatic hydrocarbons (PAHs) in olive oil samples has been improved in order to obtain a fast methodology with a low limit of detection through the combination of liquid–liquid extraction with acetonitrile and preparative gel permeation chromatography (GPC) prior to the injection of purified extracts into a C18 column. Acetonitrile–water was used as the mobile phase with a gradient from 50 to 95%, w/w, acetonitrile in 30 min. The oven temperature was maintained at 15°C, and fluorometric detection was made at a fixed excitation wavelength of 264 nm and variable, optimal emission wavelength for each analyte ranging from 352 nm for 11-H-benzo(b)fluor…
Estimation of Arsenic Bioaccessibility in Edible Seaweed by an in Vitro Digestion Method
2003
The aim of this study was to examine the bioaccessibility (maximum soluble concentration in gastrointestinal medium) of total (AsT) and inorganic (AsI) arsenic contents and the effect on them of cooking edible seaweed, a food of great interest because of its high As content. An in vitro gastrointestinal digestion (pepsin, pH 2, and pancreatin−bile extract, pH 7) was applied to obtain the mineral soluble fraction of three seaweeds (Hizikia fusiforme, Porphyra sp., and Enteromorpha sp.). AsT was determined by dry-ashing flow injection hydride generation atomic absorption spectrometry. AsI was determined by acid digestion, solvent extraction, and flow injection hydride generation atomic absorp…
High-spin polarization of Heusler alloys
2006
Fermi surface of a half-metal compound with cubic Fm–3m symmetry: Heusler alloy or double perovskite.The inset shows the spin resolved density of state for a CCFA Heusler compound. ( This illustration appears on the cover of the print edition. ) This cluster issue of Journal of Physics D: Applied Physics is devoted to magnetic Heusler alloys. This class of materials is currently considered to contain the most attractive half-metallic ferromagnets due to their high Curie temperatures and their structural relation to conventional semiconductors. The first compound to be identified as a half-metallic ferromagnet, by de Groot et al back in 1983, was the half-Heusler alloy NiMnSb. After a period…
Off-stoichiometry in Co2FeSi thin films sputtered from stoichiometric targets revealed by nuclear magnetic resonance
2009
Co2FeSi is predicted to be a half-metallic ferromagnet with an extraordinary high magnetic moment and Curie temperature. However, a low tunnel magneto-resistance ratio, a lower spin polarization and a lower magnetic moment were experimentally observed in thin film samples. Consequently, thin Co2FeSi films of different groups were studied using spin-echo nuclear magnetic resonance (NMR). NMR probes the local hyperfine fields of the active atoms, which strongly depend on the local environment. NMR is thus able to reveal the next neighbouring shells of the Co-59 nuclei in the Co2FeSi thin films. As expected, our NMR study shows the main resonance line corresponding to Co-59 nuclei in the L2(1)…
Thermoelectric properties of CoTiSb based compounds
2009
Several CoTiSb based compounds were synthesized and investigated on their thermoelectric properties. The aim was to improve the thermoelectric properties of CoTiSb by the systematic substitution of atoms or the introduction of additional Co into the vacant sublattice. The solid solutions Co1+xTiSb, Co1?yCuyTiSb and CoTiSb1?zBiz were synthesized. X-ray diffraction was used to investigate the crystal structure. The resistivity, the Seebeck coefficient and the thermal conductivity were determined for all compounds in the temperature range from 2 to 400?K. The highest figure of merit for each solid solution is presented. We were able to improve the figure of merit by a factor of approximately s…
Double Thermoresponsive Block Copolymers Featuring a Biotin End Group
2010
A poly(oligo(ethylene glycol) monomethyl ether methacrylate)-block-poly(N-isopropyl methacrylamide) (POEGMA-b-PNIPMAM) block copolymer with a biotin end group on the PNIPMAM block as a biotarget was synthesized as a model system for temperature-controlled polymer immobilization. The synthesis was based on RAFT polymerization followed by postpolymerization modification of an activated ester precursor block and an exchange of the dithioester end group within one step. NMR, differential scanning calorimetry (DSC), dynamic light scattering (DLS), and turbidimetry measurements were performed to investigate the stimulus-responsive properties. The double thermoresponsive POEGMA-b-PNIPMAM with biot…
Controlled synthesis of poly(acetone oxime acrylate) as a new reactive polymer: Stimuli-responsive reactive copolymers
2007
Abstract Acetone oxime acrylate has been synthesized as a new active ester monomer. Free radical polymerization yielded a reactive polymer soluble in various organic solvents, such as chloroform, dioxane, DMSO, acetone, methanol, dichloromethane, DMF, and ethanol. Controlled radical polymerization of acetone oxime acrylate was successfully conducted using the RAFT, NMP and Iniferter method. Partly polymer analogous reaction with N-isopropylamine resulted in the reactive copolymer poly(N-isopropylacrylamide-co-acetone oxime acrylate), which featured a lower critical solution temperature (LCST) of 61 °C in water. Further, the reactivity of the copolymer was exemplary proven by complete reacti…
Calculation of the chemical potential and the activity coefficient of two layers of CO2 adsorbed on a graphite surface.
2014
We study the adsorption of carbon dioxide at a graphite surface using the new Small System Method, and find that for the temperature range between 300 K and 550 K most relevant for CO2 separation; adsorption takes place in two distinct thermodynamic layers defined according to Gibbs. We calculate the chemical potential and the activity coefficient of both layers directly from the simulations. Based on thermodynamic relations, the entropy and enthalpy of the CO2 adsorbed layers are also obtained. Their values indicate that there is a trade-off between entropy and enthalpy when a molecule chooses for one of the two layers. The first layer is a densely packed monolayer of relatively constant e…
Spatial sharpening of land surface temperature for daily energy balance applications
2008
ABSTRACT Daily high spatial resolution assessment of actual evapotranspiration is essential for water management and crop water requirement estimation under stress conditions. The application of energy balance models usually requires satellite observations of radiometric surface temperat ure with high geometrical and temporal resolutions. By now, however, high spatial resolution (~ 100 m) is available with low time fre quency (approximately every two weeks); at the opposite daily acquisition are characterised by poor spatial resolution. The analysis of vegetation index (VI) and land surface temperature (LST) spatial relationship, shows in substance a scale invariant behaviour [1] ; this con…