Search results for "Tempering"

A Study on the Correlations between Machining Parameters and Specimen Quality in WEDM

1999

Wire electrical discharge machining (WEDM) is widely used in manufacturing, medical, aircraft applications and, virtually, all areas of conductive material machining. The process involves a series of very complex electrical, thermodynamical and electromagnetical phenomena that are still partially unknown. Due to the large amount of parameters involved in the process, a suitable set-up of the variables aimed to obtain the best performance is often very difficult. In the paper the results of a wide experimental analysis are presented: the tests were carried out on high-speed steel and tempered steel specimens utilising brass wires. The influence of the most important process parameters on the…

CLUSTER MONTE CARLO ALGORITHMS IN STATISTICAL MECHANICS

1992

The cluster Monte Carlo method, where variables are updated in groups, is very efficient at second order phase transitions. Much better results can be obtained with less computer time. This article reviews the method of Swendsen and Wang and some of its applications.

Monte Carlo Simulations of Polymer Systems

1988

The impact of Monte Carlo “computer experiments” in polymer physics is described, emphasizing three examples taken from the author’s research group. The first example is a test of the classical Flory—Huggins theory for polymer mixtures, including a discussion of cricital phenomena. Also “technical aspects” of such simulations (“grand-canonical” ensemble, finite—size scaling, etc.) are explained briefly. The second example refers to configurational statistics and dynamics of chains confined to cylindrical tubes; the third example deals with the adsorption of polymers at walls. These simulations check scaling concepts developed along the lines of de Gennes.

Crossover scaling in semidilute polymer solutions: a Monte Carlo test

1991

Molecular-Level Characterization of Heterogeneous Catalytic Systems by Algorithmic Time Dependent Monte Carlo

2009

Monte Carlo algorithms and codes, used to study heterogeneous catalytic systems in the frame of the computational section of the NANOCAT project, are presented along with some exemplifying applications and results. In particular, time dependent Monte Carlo methods supported by high level quantum chemical information employed in the field of heterogeneous catalysis are focused. Technical details of the present algorithmic Monte Carlo development as well as possible evolution aimed at a deeper interrelationship of quantum and stochastic methods are discussed, pointing to two different aspects: the thermal-effect involvement and the three-dimensional catalytic matrix simulation. As topical app…

Non-reversible Monte Carlo simulations of spin models

2011

Abstract Monte Carlo simulations are used to study simple systems where the underlying Markov chain satisfies the necessary condition of global balance but does not obey the more restrictive condition of detailed balance. Here, we show that non-reversible Markov chains can be set up that generate correct stationary distributions, but reduce or eliminate the diffusive motion in phase space typical of the usual Monte Carlo dynamics. Our approach is based on splitting the dynamics into a set of replicas with each replica representing a biased movement in reaction-coordinate space. This introduction of an additional bias in a given replica is compensated for by choosing an appropriate dynamics …

Simulation of Models for the Glass Transition: Is There Progress?

2002

The glass transition of supercooled fluids is a particular challenge for computer simulation, because the (longest) relaxation times increase by about 15 decades upon approaching the transition temperature T g. Brute-force molecular dynamics simulations, as presented here for molten SiO2 and coarse-grained bead-spring models of polymer chains, can yield very useful insight about the first few decades of this slowing down. Hence this allows to access the temperature range around T c of the so-called mode coupling theory, whereas the dynamics around the experimental glass transition is completely out of reach. While methods such as “parallel tempering” improve the situation somewhat, a method…

Mechanical properties and corrosion behaviour of low carbon martensitic stainless steel after machining

2014

The influence of different combinations of cutting conditions on the mechanical behaviour (microhardness), the microstructure and the corrosion behaviour in NaCl solution (using the electrochemical microcell technique and pulse potentiodynamic testing) of a low carbon martensitic stainless steel (grade X4CrNiMo16.5.1 stainless steel) after tempering treatment was studied. Microhardness was increased on the machined surface. In addition, the electrochemical experiments have shown that the machined materials have a heterogeneous electrochemical behaviour. Significant effect of machining on pitting corrosion was noticed. The pitting potential was found to decrease as the microhardness increase…

Macroscopic and local electrochemical studies of austempered ductile iron in perchlorate solutions.

2006

The corrosion behavior of austempered ductile iron (ADI) in alkaline environment has been investigated at the microscale by means of the electrochemical microcell technique, surface analysis methods, and at the macroscale using classical electrochemical techniques. Local electrochemical investigations have revealed that the matrix (ausferrite), far from spheres, undergoes passivation in 1 M NaClO 4 , pH 10 solution within a wide potential range, from the corrosion potential (of about -280 mV/SCE) until 800 mV/SCE. Surface observations combined with local electrochemical analysis have shown that corrosion of ADI first occurs in the close vicinity of some graphite spheres and then around oxid…

Influence of the microstructure on the corrosion behaviour of low-carbon martensitic stainless steel after tempering treatment

2014

Abstract The microstructure of grade X4CrNiMo16.5.1 stainless steel was studied at different scales. The chemical composition of the native passive film formed on the different phases was then determined at the microscale. The degree of homogeneity of the native passive film is discussed. Subsequently, the susceptibility to pitting corrosion of X4CrNiMo16.5.1 was quantified using the electrochemical microcell technique. The nature of precursor sites and the morphology of pits were investigated by combining scanning electron microscopy with Electron BackScatter Diffraction and potentiostatic pulse tests. The role of the microstructure and the cold-worked layer generated by polishing in pitti…