Search results for "Terbium"

showing 10 items of 150 documents

CCDC 1934949: Experimental Crystal Structure Determination

2019

Related Article: Javier Castells-Gil, Samuel Mañas-Valero, Iñigo J. Vitórica-Yrezábal, Duarte Ananias, João Rocha, Raul Santiago, Stefan T. Bromley, José J. Baldoví, Eugenio Coronado, Manuel Souto, Guillermo Mínguez Espallargas|2019|Chem.-Eur.J.|25|12636|doi:10.1002/chem.201902855

Space GroupCrystallographycatena-[bis(mu-44'-{2-[45-bis(4-carboxylatophenyl)-2H-13-dithiol-2-ylidene]-2H-13-dithiole-45-diyl}dibenzoato)-(mu-acetato)-aqua-tri-terbium unknown solvate hydrate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2026744: Experimental Crystal Structure Determination

2021

Related Article: Paul Richardson, Riccardo Marin, Yixin Zhang, Bulat Gabidullin, Jeffrey Ovens, Jani O. Moilanen, Muralee Murugesu|2020|Chem.-Eur.J.|27|2361|doi:10.1002/chem.202003556

Space GroupCrystallographydecakis(mu-6677888-heptafluoro-22-dimethyloctane-35-dionato)-bis(mu-1-(pyrazine-2-carbonyl)-2-[(pyrazin-2-yl)methylidene]hydrazin-1-ido)-tetra-ytterbiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1419403: Experimental Crystal Structure Determination

2015

Related Article: Sudeshna Saha, Partha P. Jana, Carlos J. Gómez-García, Klaus Harms, Hari Pada Nayek|2016|Polyhedron|104|58|doi:10.1016/j.poly.2015.11.035

Space GroupCrystallographyoctakis(NN-dimethylformamide)-ytterbium (mu12-phosphato)-tetracosakis(mu2-oxido)-dodecaoxo-dodeca-tungstenCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1958347: Experimental Crystal Structure Determination

2020

Related Article: Raphael C. A. Vaz, Isabela O. Esteves, Willian X. C. Oliveira, João Honorato, Felipe T. Martins, Lippy F. Marques, Guilherme L. dos Santos, Ricardo O. Freire, Larissa T. Jesus, Emerson F. Pedroso, Wallace C. Nunes, Miguel Julve, Cynthia L. M. Pereira|2020|Dalton Trans.|49|16106|doi:10.1039/D0DT02497J

Space GroupCrystallographytetra-n-butylammonium tetrakis((4-chloroanilino)(oxo)acetato)-(dimethyl sulfoxide)-terbium(iii) trihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1582396: Experimental Crystal Structure Determination

2018

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Willian X. C. Oliveira, Francesc Lloret, Miguel Julve|2018|Dalton Trans.|47|6005|doi:10.1039/C8DT00895G

Space GroupCrystallographytetrakis(mu-cyano)-bis(cyano)-bis(hydrogen tris(pyrazolyl)borate)-bis(2-(1H-imidazol-2-yl)pyridine)-tetrakis(nitrato)-diaqua-di-iron(iii)-di-terbium(iii) hydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Self-assembly and intra-cluster reactions of erbium and ytterbium bis(2-ethylhexyl)sulfosuccinates in the gas phase.

2014

RATIONALE: The study of surfactant organization in vacuum allows surfactant–surfactant interaction to be unveiled in the absence of surrounding solvent molecules. Knowledge on their chemical-physical properties may also lead to the definition of more efficient gas-phase carriers, air-cleaning agents and nanoreactors. In addition, the presence of lanthanide-group ions adds unique photochemical properties to surfactants. METHODS: The structural features, stability and fragmentation patterns of charged aggregates formed by lanthanide- functionalized surfactants, ytterbium and erbium bis(2-ethylhexyl)sulfosuccinate ((AOT) 3 Yb and (AOT) 3 Er), have been investigated by electrospray ionization m…

Spectrometry Mass Electrospray IonizationSurface-Active AgentsSuccinatesself Assembly Mass spectrometry Lanthanides AOT Er YbGasesYtterbiumErbiumRapid communications in mass spectrometry : RCM
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Study of Confined 5-Aza[5]helicene in Ytterbium(III) Bis(2-ethylhexyl) Sulfosuccinate Reversed Micelles

2007

Some relevant physicochemical properties of 5-aza[5]helicene (H5) in solutions of ytterbium bis(2-ethylhexyl) sulfosuccinate (Yb(DEHSS)3) reversed micelles have been investigated by UV-vis-NIR, photoluminescence, and FT-IR techniques with the aim of emphasizing the role played by specific Yb(III)/H5 interactions and confinement effects as driving forces of its binding to reversed micelles, preferential solubilization site, and local photophysical properties. It has been found that the binding strength of 5-aza[5]helicene to reversed micelles, triggered by steric and orientational constrains as well as the water content, is mainly regulated by its interaction with the Yb(III) counterion. Mor…

Steric effectsYtterbiumPhotoluminescencechemistry.chemical_elementLIQUID-CRYSTALSPhotochemistryHeterocyclic Compounds 4 or More RingsMicellechemistry.chemical_compoundSpectroscopy Fourier Transform InfraredMaterials ChemistryWATEROrganic chemistryAOTYtterbiumPhysical and Theoretical ChemistryMicelleschemistry.chemical_classificationAza CompoundsSpectroscopy Near-InfraredCHIROPTICAL PROPERTIESSuccinatesSOLID-SOLID REACTIONSTATESurfaces Coatings and FilmsFT-IRSODIUM BIS(2-ETHYLHEXYL)SULFOSUCCINATEchemistryHeliceneSolubilizationSOLUBILIZATIONLUMINESCENCESpectrophotometry UltravioletCounterionThe Journal of Physical Chemistry B
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Influence of Peripheral Substitution on the Magnetic Behavior of Single-Ion Magnets Based on Homo- and Heteroleptic TbIIIBis(phthalocyaninate)

2013

A series of homoleptic ([Tb(III)(Pc)(2) ]) and heteroleptic ([Tb(III)(Pc)(Pc')]) Tb(III) bis(phthalocyaninate) complexes that contain different peripheral substitution patterns (i.e., tert-butyl or tert-butylphenoxy groups) have been synthesized in their neutral radical forms and then reduced into their corresponding anionic forms as stable tetramethylammonium/tetrabutylammonium salts. All of these compounds were spectroscopically characterized and their magnetic susceptibility properties were investigated. As a general trend, the radical forms exhibited larger energy barriers for spin reversal than their corresponding reduced compounds. Remarkably, heteroleptic complexes that contain elect…

TetramethylammoniumSingle ion010405 organic chemistryStereochemistryOrganic Chemistrychemistry.chemical_elementTerbiumGeneral Chemistry010402 general chemistryRing (chemistry)01 natural sciencesMagnetic susceptibilityCatalysis0104 chemical sciencesIonchemistry.chemical_compoundCrystallographychemistryMagnetHomolepticChemistry - A European Journal
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CCDC 696697: Experimental Crystal Structure Determination

2009

Related Article: D.Visinescu, L.M.Toma, O.Fabelo, C.Ruiz-Perez, F.Lloret, M.Julve|2009|Polyhedron|28|851|doi:10.1016/j.poly.2008.12.032

Triaqua-(22'-bipyrimidine-NN')-bis(nitrato-OO')-terbium(iii) (22'-bipyridine-NN')-tetracyano-iron(iii) acetonitrile solvate monohydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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An experimental analysis of self-Q-switching via stimulated Brillouin scattering in an ytterbium doped fiber laser

2013

An experimental study of self-Q-switching (SQS) in an ytterbium doped fiber laser (YDFL) arranged using a twin-core GTWave assembly is reported. The main mechanisms that initiate, amplify, and limit SQS pulses in amplitude are revealed to be stimulated Brillouin and Raman scattering (SBS/SRS) and Yb3+ amplified spontaneous emission. The parameters featuring SQS oscillation in terms of efficiency and stability of pulsing are found to be intra-cavity loss and feedback strength. An analysis of the YDFL SQS regime?s features?pulsing time series, optical and RF spectra, amplitude and timing jitter?is provided for the two experimental situations: (i) when SQS pulsing stochastically intermits with…

YtterbiumAmplified spontaneous emissionMaterials sciencePhysics and Astronomy (miscellaneous)business.industryOscillationchemistry.chemical_elementQ-switchingAmplitudeOpticschemistryBrillouin scatteringFiber laserAtomic physicsbusinessInstrumentationJitterLaser Physics Letters
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