Search results for "Thermal analysis"
showing 8 items of 208 documents
Synthesis and characterization of a novel high luminescent gold-2-mercapto-1-methyl-imidazole complex
2010
Synthesis and characterization of a new gold-2-mercapto-1-methyl imidazole are reported. This new organic material shows an extraordinary fluorescence activity (superfluorescence) up to 220°C with an unusual quantum yield of 0.2. Both fluorescence and NMR spectroscopy were applied to understand the behavior of the gold-2-mercapto-1-methylimidazole complex. Results suggest that the superfluorescence activity can be attributed to the shrinking of the HOMO-LUMO band gap energy following complexation of the organic imidazole system with gold. Copyright © 2010 John Wiley & Sons, Ltd.
Clay Nanotube/PNIPAAM Hybrid material
2014
Reduction and catalytic behaviour of heterobimetallic copper–lanthanide oxides
2008
Abstract The reduction of the heterobimetallic copper–lanthanide oxides 2CuO·CeO2 and 3CuO·Ln2CuO4 (Ln = La, Pr, Nd) was studied by H2-TG/DTA and H2-TPR. All systems exhibit two main reduction steps accompanied by mass losses in the temperature range 20–1000 °C. The first step was attributed to CuO reduction, whereas the second step is due either to copper reduction in the Ln2CuO4 phase with the concomitant formation of Ln2O3 or to the surface reduction of CeO2. The products were characterized by XRD, SEM, EDX, and BET techniques and are better described as supported copper type materials. They were active for the mesityl oxide (4-methyl-2-penten-2-one) gas phase hydrogenation.
Enrichment and activation of smectite-poor clay
2011
A new method of smectite clay enrichment has been developed. The method is based on dispersing clay in a phosphate solution and sequential coagulation. The product of enrichment is characterized with X-ray powder diffraction, wavelength dispersive X-ray fluorescence spectrometry, differential thermal analysis and thermogravimetry. Sorption of methylene blue and hexadecylpyridinium bromide on raw and purified clays was studied.
Effect of Stacking Sequence and Sodium Bicarbonate Treatment on Quasi-Static and Dynamic Mechanical Properties of Flax/Jute Epoxy-Based Composites
2019
The present paper deals with the investigation of quasi-static and dynamic mechanical response of epoxy-based composites reinforced with flax and/or jute plain weave fabrics. In order to evaluate the influence of the stacking sequence, two monolithic laminates reinforced with flax or jute fibers and two hybrid flax/jute laminates were manufactured through the vacuum infusion technique. Furthermore, an eco-friendly and cost-effective surface treatment based on fiber soaking in a sodium bicarbonate solution was employed to improve the fiber-matrix adhesion. The mechanical characterization (by means of quasi-static flexural, dynamic mechanical thermal analysis and Charpy impact tests) allowed …
Synthesis, Optical, and Morphological Studies of ZnO Powders and Thin Films Fabricated by Wet Chemical Methods
2020
Zinc oxide nanoparticles were prepared from Zn5(CO3)2(OH)6 precursor, capped with poly(vinylpyrrolidone) (PVP), and annealed at 600 °