Search results for "Thermal equilibrium"
showing 10 items of 65 documents
Active colloidal suspensions: Clustering and phase behavior
2014
We review recent experimental, numerical, and analytical results on active suspensions of self-propelled colloidal beads moving in (quasi) two dimensions. Active colloids form part of the larger theme of active matter, which is noted for the emergence of collective dynamic phenomena away from thermal equilibrium. Both in experiments and computer simulations, a separation into dense aggregates, i.e., clusters, and a dilute gas phase has been reported even when attractive interactions and an alignment mechanism are absent. Here, we describe three experimental setups, discuss the different propelling mechanisms, and summarize the evidence for phase separation. We then compare experimental obse…
ChemInform Abstract: Relaxation Phenomena of a Triplet Spin Probe in Glassy and Crystalline o-Terphenyl.
2010
The authors used quinoxaline in its photoexcited triplet state as a spin probe in order to measure the spin-lattice relaxation rate in o-terphenyl glass as a function of temperature. They found a power law with an exponent close to 2. Since o-terphenyl can easily be crystallized, they investigated the crystal, too. Below 3.5 K the spin is highly polarized, contrary to the behavior in the glass, where it reaches thermal equilibrium down to the lowest temperatures of their experiment (1.4 K). Around 3.5 K the polarization in the crystal vanishes. Above it appears with opposite sign due to thermal equilibration.
Thermoconvective instability and local thermal non-equilibrium in a porous layer with isoflux-isothermal boundary conditions
2014
The effects of lack of local thermal equilibrium between the solid phase and the fluid phase are taken into account for the convective stability analysis of a horizontal porous layer. The layer is bounded by a pair of plane parallel walls which are impermeable and such that the lower wall is subject to a uniform flux heating, while the upper wall is isothermal. The local thermal non-equilibrium is modelled through a two-temperature formulation of the energy exchange between the phases, resulting in a pair of local energy balance equations: one for each phase. Small-amplitude disturbances of the basic rest state are envisaged to test the stability. Then, the standard normal mode procedure is…
Measurement of the Convective Heat-Transfer Coefficient
2014
We propose an experiment for investigating how objects cool down toward the thermal equilibrium with its surrounding through convection. We describe the time dependence of the temperature difference of the cooling object and the environment with an exponential decay function. By measuring the thermal constant tau, we determine the convective heat-transfer coefficient, which is a characteristic constant of the convection system.
The KeV Majoron as a dark matter particle
1993
We consider a very weakly interacting KeV majoron as dark matter particle (DMP), which provides both the critical density $\rho_{cr} = 1.88 \times 10^{-29} h^{2}$ $g/cm^{3}$ and the galactic scale $M_{gal}$ $\sim m^{3}_{Pl}/m^{2}_{J} \sim 10^{12} M_{\odot} (m_{J}/1 KeV)^{-2}$ for galaxy formation. The majoron couples to leptons only through some new "directly interacting particles", called DIPS, and this provides the required smallness of the coupling constants. If the masses of these DIPS are greater than the scale $V_s$ characterizing the spontaneous violation of the global lepton symmetry they are absent at the corresponding phase transition ($T \sim V_s$) and the majorons are produced d…
An Explicit Model for the Thermal-Mechanical Analysis of Hot Metal Forming Processes
1995
Abstract In the paper the authors propose a new finite element code for the coupled thermal-mechanical analysis of hot metal forming processes. As regards the mechanical problem, an explicit algorithm based on the solution of the dynamic equilibrium equation and an explicit time integration scheme is used, while the heat transfer analysis is based on the solution of the thermal equilibrium equations; in order to put the thermal problem in an explicit linear form a three level scheme has been employed for the discretization of the time variable. The model is based on a staggered procedure, in which the mechanical and the thermal analysis are carried out with respect to different time horizon…
Aging effects in simple models for glassy relaxation
2006
Aging effects in the two-time correlation function and the response function after a quench from a high temperature to some low temperature are considered for a simple kinetic random energy model exhibiting stretched exponential relaxation. Because the system reaches thermal equilibrium for long times after the quench, all aging effect are of a transient nature. In particular, the violations of the fluctuation-dissipation theorem are considered and it is found that the relation between the response and the two-time correlation function depends on another function, the so-called asymmetry. This asymmetry vanishes in equilibrium but cannot be neglected in the aging regime. It is found that pl…
Finite Size Scaling Tools for the Study of Interfacial Phenomena and Wetting
2019
In this chapter, we use the word “interface” in the sense of a boundary between coexisting bulk phases (in thermal equilibrium). An example is the interface between liquid (e.g. water) and gas phases (water vapor) but also interfaces between fluid and solid phases (e.g. water and ice) can be considered, as well as interfaces between coexisting solid phases. The generic example are “domain walls” in magnets, separating domains with opposite orientation of the magnetization, a case that can already be studied in the framework of the simple Ising model (Chaps. 2 and 3) where one has spins on the sites of a rigid perfect lattice pointing up or down.
Application of modulated calorimetry to the Liquid metals using electromagnetic levitation and static magnetic field
2018
Measurement of the thermophysical properties of liquid metals is challenging because of their high chemical activity and high temperatures. The electromagnetic levitation allows one to hold the electrically conductive liquid sample containerless in an inert atmosphere in thermal equilibrium while measurements on the sample can be taken in a non-contact way followed by extraction of some thermophysical properties. Yet, the electromagnetic forces within the skin layer inside the sample cause convective flow of the liquid thus disabling the data extraction. A static magnetic field imposed over a sample is known to damp the convective flow. With these ideas, an experimental set-up with a DC mag…
Formation of metastable structures by phase separation triggered by initial composition gradients in thin films.
2012
Phase separation kinetics of a binary (A,B) mixture contained in a thin film of thickness D induced by a quench from the one-phase region into the miscibility gap is studied by simulations using a Cahn-Hilliard-Cook model. The initial randomly mixed state (50% A, 50% B) contains a concentration gradient perpendicular to the film, while the surfaces of the film are "neutral" (no preference for either A or B). In thermal equilibrium, a pattern of large A-rich and B-rich domains must result, separated by domain walls oriented perpendicularly to the external surfaces of the thin film. However, it is shown that for many choices of D and the strength of the initial gradient Ψ(g), instead a very l…