Search results for "Thermal"

A non-local model of thermal energy transport: The fractional temperature equation

2013

Abstract Non-local models of thermal energy transport have been used in recent physics and engineering applications to describe several “small-scale” and/or high frequency thermodynamic processes as shown in several engineering and physics applications. The aim of this study is to extend a recently proposed fractional-order thermodynamics ( [5] ), where the thermal energy transfer is due to two phenomena: A short-range heat flux ruled by a local transport equation; a long-range thermal energy transfer that represents a ballistic effects among thermal energy propagators. Long-range thermal energy transfer accounts for small-scale effects that are assumed proportional to the product of the in…

Heat solitons and thermal transfer of information along thin wires

2020

Abstract The aim of this paper is to consider soliton propagation of heat signals along a cylinder whose heat exchange with the environment is a non-linear function of the difference of temperatures of the cylinder and the environment and whose heat transfer along the system is described by the Maxwell–Cattaneo equation. To find the soliton solutions we use the auxiliary equation method. Our motivation is to obtain and compare the speed of propagation, the maximum rate of information transfer, and the energy necessary for the transfer of one bit of information for different solitons, by assuming that a localized soliton may carry a bit of information. It is shown that a given total power (e…

Heat and work fluxes in thermoelectric coolers

2021

Abstract Thermodynamics considers heat and work as the observables of energy. Then, in a non-equilibrium process, the fluxes of heat, work and energy are related. The expressions for the heat and energy flux densities are well known; although several conventions have been adopted. The work flux density defined from the heat and energy flux densities can be very useful in describing the energy balance when chosen to emphasize observable quantities. This paper discusses the advantages of the use of the conduction heat flux density given by Fourier’s law and a work flux density defined from it. As a case study, heat and work fluxes are evaluated in the elements of a thermoelectric cooler using…

Local thermal non-equilibrium effects in the Darcy–Bénard instability of a porous layer heated from below by a uniform flux

2013

Abstract The influence of the lack of thermal equilibrium between the solid phase and the fluid phase on the convective instability in a porous medium is studied. A horizontal layer with parallel and impermeable bounding walls is considered. The lower wall is assumed to be isoflux, and the upper wall isothermal. The basic motionless state is perturbed with small-amplitude disturbances, so that a linear analysis of the instability is carried out with a streamfunction-temperature formulation of the local balance equations. Then, the governing equations are solved for the normal modes, leading to an eigenvalue problem for the neutral stability. This eigenvalue problem is solved analytically, t…

Assessment of a mattress with phase change materials using a thermal and perception test

2017

Abstract Mattresses composed by phase change materials (PCMs) may improve the thermoregulation of the human body. The aim of the study was to analyse the thermoregulatory efficiency of a PCMs and a conventional mattresses via the evaluation of the skin temperature, thermal comfort and thermal perception. Twenty participants lay on a PCMs and a conventional mattress for 20 min in each mattress on the same day. Skin temperature of the back of the participants and temperature of the sheet of the mattresses were measured before and immediately after lying on each mattress. Thermal comfort and thermal perception were also reported during the last minute of the lying test. The PCMs mattress resul…

Catalytic oxidation and reduction of polycyclic aromatic hydrocarbons (PAHs) present as mixtures in hydrothermal media

2012

Author's version of an article in the journal: Polycyclic Aromatic Compounds. Also available from the publisher at: http://dx.doi.org/10.1080/10406638.2012.663451 The reactivity of fluorene, anthracene, and fluoranthene under oxidation and reduction conditions were investigated in this study. This project looks at catalytic and green approaches of converting PAHs to less toxic and/or less stable derivatives that are amenable to further degradation. Hydrothermal reactions have been performed at 300°C with pure H2O and Nafion-SiO2 catalyst for oxidation, and pure H2O, HCOOH, Pd-C, and Nafion-SiO2 catalysts for reductive hydrogenation. Time series has been performed for both the oxidation and …

Carbon Nanodots as Functional Excipient to Develop Highly Stable and Smart PLGA Nanoparticles Useful in Cancer Theranostics

2020

Theranostic systems have attracted considerable attention for their multifunctional approach to cancer. Among these, carbon nanodots (CDs) emerged as luminescent nanomaterials due to their exceptional chemical properties, synthetic ease, biocompatibility, and for their photothermal and fluorescent properties useful in cancer photothermal therapy. However, premature renal excretion due to the small size of these particles limits their biomedical application. To overcome these limitations, here, hybrid poly(lactic-co-glycolic acid) (PLGA-CDs) nanoparticles with suitable size distribution and stability have been developed. CDs were decisive in the preparation of polymeric nanoparticles, not on…

Highly Homogeneous Biotinylated Carbon Nanodots: Red-Emitting Nanoheaters as Theranostic Agents toward Precision Cancer Medicine

2019

Very recent red-emissive carbon nanodots (CDs) have shown potential as near-infrared converting tools to produce local heat useful in cancer theranostics. Besides, CDs seem very appealing for clinical applications combining hyperthermia, imaging, and drug delivery in a single platform capable of selectively targeting cancer cells. However, CDs still suffer from dramatic dot-to-dot variability issues such that a rational design of their structural, optical, and chemical characteristics for medical applications has been impossible so far. Herein, we report for the first time a simple and highly controllable layer-by-layer synthesis of biotin-decorated CDs with monodisperse size distribution, …

SYNTHESIS AND CHARACTERISATION OF NEW AZOLE BUILDING BLOCKS FOR FUNCTIONAL IONIC SYSTEMS

The synthesis of a series of 27 salts based on 5-(4-(alkyloxy)phenyl)-1,4-dimethyl-3-(perfluoroalkyl)-1,2,4-triazol-4-ium structures, differing in the length of the alkyl and perfluoroalkyl chains, as well as in the counter ions is reported. Some properties of this new family of salts as perspective liquid-crystalline ionic liquids (LC-ILs) are described and the influence of the varying moieties in the modulation of the properties is discussed.

High Pressure Treatment Effect on Physicochemical and Nutritional Properties of Fluid Foods During Storage: A Review

2012

Abstract:  Consumers demand foods that are easy to consume and that are of high nutritional and sensory quality. Therefore, they appreciate the similarity of minimally processed products to fresh products. In recent years, the food industry has shown increased interest in nonthermal preservation technologies, because they provide products of proven quality and can be an alternative to traditional thermal methods, thus increasing added value. This review examines the effects of high pressure processing (HPP) on the nutritional and physicochemical parameters of fluid foods. While some general trends can be observed, the effects of HPP differ not only according to treatment intensity, but also…