Search results for "Thermal"
showing 10 items of 3576 documents
Organobase-Catalyzed Synthesis of Multiarm Star Polylactide With Hyperbranched Poly(ethylene glycol) as the Core
2011
Multiarm star copolymers consisting of the polyether-polyol hyperbranched poly(ethylene glycol) (hbPEG) as core and poly(L-lactide) (PLLA) arms are synthesized via the organobase- catalyzed ring-opening polymerization of lactide using hbPEG as a multifunctional macroinitiator. Star copolymers with high molecular weights up to 792 000 g mol−1 are prepared. Detailed 2D NMR analysis provides evidence for the attachment of the PLLA arms to the core and reveals that the adjustment of the monomer/initiator ratio enables control of the arm length. Size exclusion chromatography measurements show narrow molecular weight distributions. Thermal analysis reveals a lower glass transition temperature, me…
Comparison of two melting range analysis methods with lactitol monohydrate
2001
Abstract In pharmacopoeia, the melting point is determined by a standard method with a melting point instrument. The melting point can also be determined with differential scanning calorimetry (DSC). In this study, the standard method and DSC method are compared for determining the melting range of lactitol monohydrate. The effect of initial temperature, grinding, and drying on the melting range of different lactitol monohydrate samples was studied by a melting point instrument. The melting point and melting enthalpy of the stable form of lactitol monohydrate was identified by DSC. The statistical analysis of the results is based on a t-test. All studied variables had a small effect on the …
Urban morphology detection and it's linking with land surface temperature: A case study for Tehran Metropolis, Iran
2021
Abstract Expansion of urban areas and alteration of natural land cover exacerbate the local climate change. To find out the effect of land cover changes on the local climate, in this study, the Local Climate Zone (LCZ) concept was utilized to detect urban morphology in Tehran Metropolis. LCZ and Land Surface Temperature (LST) can be identified and classified based on available remote sensing products. Firstly, LCZ maps of Tehran metropolis were extracted using Landsat imagery, and secondly, relationships between LCZ and LST were explored for three years (1990, 2004, and 2018). We found that Tehran urban structure has 13 LCZs based on imagery from Landsat 5 and 14 LCZs based on images for La…
The effect of montmorillonite clay in alginate gel beads for polychlorinated biphenyl adsorption: Isothermal and kinetic studies
2014
Beads of alginate montmorillonite have been used as sorbent for polychlorinated biphenyls from aqueous solutions.The structure and the differences between the different beads were established by IR spectroscopy (FT-IR). The adsorption at 25 °C has been studied in a batch system, following its kinetics and assessing adsorbent dose, initial PCB concentrations, and pH effects. The results show that increasing the initial concentration of the PCBs and the adsorption time favored the adsorption. Adsorption isotherm data were modeled using Chapman, Freundlich and Langmuir adsorption isotherms and the appropriate parameters were calculated.Adsorption of trichlorobiphenyls on alginate–montmorilloni…
Zeolite-gas systems and solar refrigeration : a study of the adsorptive properties at high pressures in the R22 freon-13X zeolite and ammonia-13X zeo…
1990
The adsorption of ammonia and R22 freon on 13X zeolite was studied in the conditions of possible use of these fluids in heat machines for solar refrigeration. The ranges of temperature and pressure, investigated in this study, extended from 0 to 80 °C and from 10-1 to 6 105 Pa respectively. The adsorption isotherms were collected by microgravimetry using a thermobalance specially built to be used in aggressive gases at pressures up to 106 Pa. Weak hysteresis was detected when ammonia was desorbed below 80 °C. A critical study concerning both applicability of classical adsorption equations (Dubinin-Radushkevitch and Langmuir) and comparison with other zeolite-gas systems is presented. Compar…
FRACTAL STRUCTURES IN SINGLE CRYSTALS OF FERROELECTRIC LITHIUM NIOBATE GROWN UNDER STRONGLY UNSTABLE CONDITIONS
2009
Atomic force microscopy studies of lithium niobate single crystals containing heterogeneously distributed lanthanide (Gd) admixture and a regular domain structure of 100 nm to 1 μm steps obtained under conditions of severe thermal instability have revealed fractal structures of the size of 10 to 100 nm within regions of the regular domain structures. A super-structure of clustered defects with 1–2 nm steps explaining results of Raman spectra analysis is supposed to exist in the cation sub-lattice and formation of periodic fractal structures of the size of ∼1 nm–100 μm is suggested to take place in lithium niobate single crystals containing lanthanide admixture.
Generation of lanthanide coordination polymers with dicarboxylate ligands: synthesis, structure, thermal decomposition and magnetic properties of the…
2000
The malonate complex of formula [Pr2(C3H2O4)3(H2O)3]·2H2O (1) was prepared and his crystal structure determined by X-ray diffraction methods. 1 crystallizes in the monoclinic space group P21, Z = 4, with unit cell parameters a = 7.631(2), b = 12.899(4), c = 8.923(2) A and β = 101.11(3)°. 1 is a polymer which grows in the (110) plane. The hydrogen bond stabilizes the crystal structure forming a three-dimensional network. The two non-equivalent praseodymium(III) ions have different environments. Finally, the thermal behaviour and magnetic properties were investigated.
Core–Shell Engineering to Enhance the Spectral Stability of Heterogeneous Luminescent Nanofluids
2017
This work was supported by the Spanish Ministerio de Educación y Ciencia (MAT2016-75362-C3-1-R) and by COST Action CM1403. L.L.-P. thanks the Universidad Autónoma de Madrid for the ‘‘Formación de Personal Investigador (FPI-UAM)’’program. P.H.-G. thanks the Spanish Ministerio de Economia y Competitividad for the Juan de la Cierva program (IJCI-2015-24551). M.P. and A.S. thank University of Verona (Italy) for financial support in the framework of the ‘‘Cooperint 2016’’ and “Ricerca di Base 2015” projects. The work of K.S. was supported by Latvian National Research Program IMIS2 (Grant No. 302/2012).
Mechanochemical synthesis of an Eu(III) complex. Preparation and Luminescence Properties of PMMA:[C42H38N5O19Eu] Hybrid Films
2015
Abstract Photoluminescent films of poly(methyl methacrylate), PMMA, doped with the complex [EuL2(H2O)2(NO3)3] were prepared, where L is the neutral ligand 2,6-bis[2-formylphenoxymethyl]pyridine (C21H17NO4). The Eu(III) complex was synthesized by classic chemosynthesis, and also through a solvent-free mechanochemical synthesis, and characterized by spectroscopy, thermal analysis (TGA and DTA), and single crystal X-ray diffraction. The mechanochemical route improves the yield for the complex, which is synthesized over times considerably shorter compared to the traditional synthesis, and through a solvent-free procedure. The photoluminescent properties of the Eu(III) complex and hybrid films P…
Fast and green: Sustainable rapid-prototyping of microfluidic chips on polylactic acid substrates
2018
This paper reports novel ways to bond bio-based polylactic acid (PLA) substrates for the production of sustainable, single-use, microfluidic components. A laser-based, fast (minutes) fabrication process for multi-layer microfluidic devices in PLA was reported recently but in that report, demonstrator devices were bonded with adhesive tape, which significantly reduced the devices transparency. In this paper, we propose two novel ways to bond PLA substrates, which alleviate the need for adhesives, and enable optimal device transparency.