Search results for "Thermal"

Phase separation in the quaternary Heusler compound CoTi(1−x)MnxSb – A reduction in the thermal conductivity for thermoelectric applications

2010

We investigate the phase separation of the solid solution CoTi(1−x)MnxSb into the two Heusler compounds CoTiSb and CoMnSb. Energy-dispersive X-ray spectroscopy measurements on the two-phase material reveal the presence of size- and shape-tunable CoTiSb regions in a CoMnSb matrix. We demonstrate that the formed phase and grain boundaries have a considerable influence on the phonon scattering processes, which leads to a reduction in the thermal conductivity by a factor of three compared to single-phase CoTiSb.

Behavior of the phonon gas in restricted geometries at low temperatures

1999

Structural characterization and anomalous Hall effect of Rh2MnGe thin films

2015

Abstract We present the preparation, structural investigations, and transport properties of L21-ordered epitaxial Rh2MnGe Heusler thin films grown by pulsed laser deposition. The films grow (1 0 0) oriented on (1 0 0)MgO substrate with [ 0 1 1 ] Rh 2 MnGe ∥ [ 0 1 0 ] MgO . The rocking curve widths of (4 0 0) reflections are below 1° and decrease with increasing deposition temperature. The flat surface of the thin films allowed lithographic patterning enabling quantitative magnetotransport measurements. We measured resistivity and the Hall effect. We suggest skew scattering as the dominant effect in the temperature dependent anomalous Hall effect, consistent with the theoretically expected s…

Reduction of phonon thermal conductivity in nanowires and nanoribbons with dynamically rough surfaces and edges

2009

We present an analytical model and molecular-dynamics simulations of the phonon heat transport in nanowires and nanoribbons with anharmonic lattices and dynamically rough surfaces and edges. In agreement with recent experiments on heat transport in single-crystalline silicon nanowires with rough surfaces, our model and simulations predict finite and length-independent phonon thermal conductivity in such quasi–one-dimensional systems, in contrast to anomalous phonon thermal conductivity of corresponding momentum-conserving systems with atomically smooth surfaces, divergent with the system length. Within our model, the main cause of thermal conductivity reduction is the momentum-nonconserving…

Electronic cooling and hot electron effects in heavily doped silicon-on-insulator film

2004

The influence of carrier concentration in silicon-on-insulator film on the thermal characteristics of semiconductor and performance of the superconductor-semiconductor-superconductor micro-coolers have been investigated at sub kelvin temperatures. The overheating of the lattice in heavily doped silicon film must be taken into account in the analysis of electron-phonon coupling experiment and operation of the cooler device. The heat flow between electrons and phonons in heavily doped silicon films is found to be proportional to T6, which is in accordance with theoretical prediction for dirty limit. Increasing the doping level in the semiconductor considerably increases both the efficiency of…

Thermal fluctuations and longitudinal relaxation of single-domain magnetic particles at elevated temperatures

2004

We present numerical and analytical results for the swiching times of magnetic nanoparticles with uniaxial anisotropy at elevated temperatures, including the vicinity of T_c. The consideration is based in the Landau-Lifshitz-Bloch equation that includes the relaxation of the magnetization magnitude M. The resulting switching times are shorter than those following from the naive Landau-Lifshitz equation due to (i) additional barrier lowering because of the reduction of M at the barrier and (ii) critical divergence of the damping parameters.

Tailoring of the electrical and thermal properties using ultra-short period non-symmetric superlattices

2016

Thermoelectric modules based on half-Heusler compounds offer a cheap and clean way to create eco-friendly electrical energy from waste heat. Here we study the impact of the period composition on the electrical and thermal properties in non-symmetric superlattices, where the ratio of components varies according to (TiNiSn)���:(HfNiSn)���������, and 0 ��� n ��� 6 unit cells. The thermal conductivity (��) showed a strong dependence on the material content achieving a minimum value for n = 3, whereas the highest value of the figure of merit ZT was achieved for n = 4. The measured �� can be well modeled using non-symmetric strain relaxation applied to the model of the series of thermal resistanc…

EPR Study of Gd3+local structure in ScF3crystal with negative thermal expansion coefficient

2015

Zero field splitting (ZFS) of Gd3+ impurity in ScF3 is studied by electron paramagnetic resonance at 77 and 295 K. ZFS parameter b4 values obtained from angular dependence simulations show that regardless of negative thermal expansion in ScF3 temperature dependence of |b4| is similar to other cubic fluoroperovskites. Our analysis of ZFS parameters indicates that the local structure of Gd3+ centres expands positively with temperature.

An analog electronic interface to measure electrical conductivity in liquids

2005

Abstract Measuring conductivity in aqueous solutions is a problem which is not easy to solve due to the differences in mass and mobility that exist between ions conduction and electrons. Additionally, it is necessary to keep in mind the interaction processes electrode-solution. As a consequence, the electrolytic conductivity cell has to be polarized with alternating voltage of adequate amplitude and frequency in order to extract the correct information. In this paper an electronic conditioning circuit is presented which converts electric conductivity into a value of continuous voltage. A hardware solution is proposed to do the conductivity temperature compensation. Experimental results obta…

Thermal conductivity of thermoelectric Al-substituted ZnO thin films

2013

ZnO:Al thin films with a low electrical resistivity were grown by magnetron sputtering on sapphire substrates. The cross-plane thermal conductivity (κ = 4.5 ± 1.3 W/mK) at room temperature is almost one order of magnitude lower than for bulk materials. The thermoelectric figure of merit ZT at elevated temperatures was estimated from in-plane power factor and the cross-plane thermal conductivity at room temperature. It is expected that the thermal conductivity drops with increasing temperature and is lower in-plane than cross-plane. Consequently, the thin film ZT is at least three times higher than for bulk samples at intermediate temperatures. (© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinh…