Search results for "Thermal"

showing 10 items of 3576 documents

On the finite element simulation of thermal phenomena in machining processes

2007

Machining processes are frequently investigated by numerical simulations. Usually 2D analyses are carried out in order to reduce CPU times, considering orthogonal cutting conditions. In this way, the computational time sharply reduces and many process variables may be calculated (i.e. forces, chip morphology, shear angle, contact length). On the other hand, the analysis of thermal aspects involved in machining, for instance the temperature distribution reached in tool, still represents an open problem. Finite element codes are able to simulate a very short process time that is not sufficient to reach steady state conditions. Several approaches have been proposed to overcome this problem: in…

Distribution (mathematics)Materials scienceSteady stateMachiningOpen problemtemperature in machining machining FEMThermalProcess (computing)Mechanical engineeringSettore ING-IND/16 - Tecnologie E Sistemi Di LavorazioneFinite element methodFinite element simulation
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Modelling of a prosumer’s substation in a district heating network: validation and dynamic analysis

Thermal grids will play a key role in the development of local energy communities and the achievement of 100% renewable societies. However, challenges are related to the capability of dealing with the increasing number of producers which could supply heat to thermal grids. Indeed, as in the case of the electricity grid, heat could be available for some hours in a day from RES plants installed at user level and distributed in the network (also referred to as “prosumers”). To achieve more reliable results when performing energy analyses of these innovative applications, there is a need to rely on accurate models of each component. For instance, substations are of paramount importance in the i…

District heatingEnergy EfficiencyTransient simulationSolar EnergyDistributed generationSubstationThermal district
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From the Golgi-Cajal mapping to the transmitter-based characterization of the neuronal networks leading to two modes of brain communication: Wiring a…

2007

After Golgi-Cajal mapped neural circuits, the discovery and mapping of the central monoamine neurons opened up for a new understanding of interneuronal communication by indicating that another form of communication exists. For instance, it was found that dopamine may be released as a prolactin inhibitory factor from the median eminence, indicating an alternative mode of dopamine communication in the brain. Subsequently, the analysis of the locus coeruleus noradrenaline neurons demonstrated a novel type of lower brainstem neuron that monosynaptically and globally innervated the entire CNS. Furthermore, the ascending raphe serotonin neuron systems were found to globally innervate the forebrai…

DopamineTortuosityBrain functionWiring transmissionSynaptic TransmissionDiffusionDual probe microdialysisMicrofluorimetrychemistry.chemical_compoundCatecholaminesPressure gradientsVolume transmissionHistofluorescenceLocus coeruleusExtracellular spaceNeurological and mental disordersNeurotransmitterNeuronsNeurotransmitter AgentsGeneral NeuroscienceBrain5-HydroxytryptamineAmygdalamedicine.anatomical_structure5-Hydroxytryptamine; Amygdala; Brain function; Brain uncoupling protein-2; Catecholamines; CA turnover; Clearance; Diffusion; Dopamine; Dorsal raphe; Dual probe microdialysis; Extracellular space; Extrasynaptic receptors; Histofluorescence; Local circuits; Locus coeruleus; Mapping of monoamine neurons; Microdensitometry; Microfluorimetry; Neurological and mental disorders; Noradrenaline; Nucleus accumbens; Pressure gradients; Receptor mosaics; Receptor–receptor interactions; Substantia nigra; Thermal gradients; Tortuosity; Transmitter–receptor mismatches; Volume fraction; Volume transmission; Wiring transmissionClearanceNucleus accumbensCA turnoverLocal circuitsReceptor–receptor interactionsSilver StainingMapping of monoamine neuronsModels NeurologicalNeurotransmissionBiologySerotonergicSubstantia nigramedicineBiological neural networkAnimalsHumansThermal gradientsTransmitter–receptor mismatchesVolume fractionExtrasynaptic receptorsMonoamine neurotransmitterchemistryReceptor mosaicsForebrainNoradrenalineLocus coeruleusBrain uncoupling protein-2Neurology (clinical)NeuronNerve NetMicrodensitometry5-Hydroxytryptamine Amygdala Brain function Brain uncoupling protein-2 Catecholamines CA turnover Clearance DiffusionNeuroscienceDorsal raphe
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Benzoxetes and Benzothietes ¾ Heterocyclic Analogues of Benzocyclobutene

2012

Benzo-condensed four-ring heterocycles, such as benzoxetes 1 and benzothietes 3 represent multi-purpose starting compounds for the preparation of various higher heterocyclic ring systems. The thermal or photochemical valence isomerizations between the benzenoid forms 1,3 and the higher reactive o-quinoid structures 2,4 provide the basis for the synthetic applications. On the other hand, this valence isomerization impedes in particular the generation and storage of 1 because the thermal equilibrium 1 ⇆ 2 is completely on the side of 2. Thus, the number of erroneous or questionable benzoxete structures published to date is surprisingly high. On the contrary, the thermal equilibrium 3 ⇆ 4 is o…

Double bondflash-vacuum-pyrolysisPharmaceutical ScienceReviewring closureAnalytical Chemistrylcsh:QD241-441chemistry.chemical_compoundlcsh:Organic chemistryBenzocyclobuteneComputational chemistryHeterocyclic CompoundsDrug DiscoveryOrganic chemistryPolycyclic CompoundsPhysical and Theoretical Chemistryring openingcycloadditionchemistry.chemical_classificationThermal equilibriumValence (chemistry)photochemistryFlash vacuum pyrolysisOrganic ChemistryCycloadditionchemistryChemistry (miscellaneous)Molecular MedicineIsomerizationMolecules
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Determination of trace elements by resonant ionization mass spectrometry (RIMS)

1988

A resonant ionization mass spectrometer has been developed as an analytical tool for the detection of trace elements, especially of plutonium and other radionuclides. The sample, deposited on a rhenium filament, is evaporated by electrical heating and the atoms of the element under investigation are selectively ionized by laser light delivered from three dye lasers pumped by a copper vapour laser. The resulting photoions are detected in a time-of-flight spectrometer with a channelplate detector. For plutonium a mass resolution of M/δM=1500 was obtained and an overall detection efficiency of 4×10−6 was determined for stepwise excitation and ionization via autoionizing states. With a laser li…

Dye laserSpectrometerPhysics::Instrumentation and DetectorsChemistryClinical BiochemistryAnalytical chemistryGeneral MedicineThermal ionization mass spectrometryMass spectrometryBiochemistryAnalytical ChemistryIonizationGeneral Materials SciencePhysics::Atomic PhysicsAtomic vapor laser isotope separationHyperfine structureHybrid mass spectrometerFresenius Zeitschrift f�r Analytische Chemie
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A novel approach to prevent graphene oxide re-aggregation during the melt compounding with polymers

2015

Abstract The technology for the preparation of polymer-GO nanocomposites was investigated by studying the structure-properties relationships of two different systems, based on PA6 and EVA, fabricated by using different preparation methods, i.e. melt mixing, wet phase inversion, and the combination of the two. The morphology of nanocomposites resulted dramatically influenced by the technique adopted and showed to be the critical variable affecting the physical properties of the materials. Finally, the mechanical and dynamic-mechanical of the nanocomposites were improved by using the hybrid technique combining the two procedures.

Dynamic mechanical thermal analysis (DMTA); Graphene; Interphase; Polymer-matrix composites (PMCs); Raman spectroscopy; Engineering (all); Ceramics and CompositesPolymer-matrix composites (PMCs)Materials scienceOxidelaw.inventionchemistry.chemical_compoundsymbols.namesakeEngineering (all)lawComposite materialInterphasechemistry.chemical_classificationDynamic mechanical thermal analysis (DMTA)NanocompositeMelt mixingGrapheneGeneral EngineeringPolymerSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialichemistryCompoundingRaman spectroscopyCeramics and CompositessymbolsGrapheneRaman spectroscopyPhase inversionComposites Science and Technology
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Comparative Study of the Mechanical Unfolding Pathways of α- and β-Peptides

2015

Using molecular simulations, we analyze the unfolding pathways of various peptides. We compare the mechanical unfolding of a β-alanine's octamer (β-HAla8) and an α-alanine's decamer (α-Ala10). Using force-probe molecular-dynamics simulations, to induce unfolding, we show that the 3(14)-helix formed by β-HAla8 is mechanically more stable than the α-helix formed by α-Ala10, although both structures are stabilized by six hydrogen bonds. Additionally, computations of the potential of mean force validate this result and show that also the thermal stability of the 3(14)-helix is higher. It is demonstrated that β-HAla8 unfolds in a two-step fashion with a stable intermediate. This is contrasted wi…

Dynamic strengthHydrogen bondHydrogen BondingMolecular Dynamics SimulationProtein Structure SecondarySurfaces Coatings and Filmschemistry.chemical_compoundCrystallographyMonomerchemistrybeta-AlanineMaterials ChemistryBiophysicsThermal stabilityHistone octamerPhysical and Theoretical ChemistryPotential of mean forcePeptidesThe Journal of Physical Chemistry B
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Analysis of Protected Accidental Transients in the EFIT Reactor With the RELAP5 Thermal-Hydraulic Code

2008

The European Facility for Industrial Transmutation (EFIT) is aimed at demonstrating the feasibility of transmutation process through the Accelerator Driven System (ADS) route on an industrial scale. The conceptual design of this reactor of about 400 MW thermal power is under development in the frame of the European EUROTRANS Integrated Project of the EURATOM Sixth Framework Program (FP6). EFIT is a pool-type reactor cooled by forced circulation of lead in the primary system where the heat is removed by steam generators installed inside the reactor vessel. The reactor power is sustained by a spallation neutron source supplied by a proton beam impinging on a lead target at the core centre. A …

EFIT reactor RELAP5 thermal-hydraulic code protected accidental transientsEngineeringNuclear transmutationWaste managementbusiness.industryNuclear engineeringThermal power stationHeat sinkThermal hydraulicsNatural circulationDecay heatbusinessReactor pressure vesselSettore ING-IND/19 - Impianti NucleariThermal energyVolume 3: Thermal Hydraulics; Instrumentation and Controls
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First Ionization Potentials of Fm, Md, No, and Lr

2018

We report the first ionization potentials (IP1) of the heavy actinides, fermium (Fm, atomic number Z = 100), mendelevium (Md, Z = 101), nobelium (No, Z = 102), and lawrencium (Lr, Z = 103), determined using a method based on a surface ionization process coupled to an online mass separation technique in an atom-at-a-time regime. The measured IP1 values agree well with those predicted by state-of-the-art relativistic calculations performed alongside the present measurements. Similar to the well-established behavior for the lanthanides, the IP1 values of the heavy actinides up to No increase with filling up the 5f orbital, while that of Lr is the lowest among the actinides. These results clear…

ENERGIESThermal ionizationchemistry.chemical_element01 natural sciencesBiochemistryCatalysisColloid and Surface ChemistrySURFACE-IONIZATIONPhysics in GeneralCHEMISTRYIonization0103 physical sciencesELEMENTS010306 general physicsSPECTROSCOPY010304 chemical physicsChemistryFermiumGeneral ChemistryActinideATOMMendeleviumNobeliumAtomic numberAtomic physicsLawrenciumJournal of the American Chemical Society
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Dynamic thermal simulation of buildings: a case study to validate ESP-r software

2008

Energy aspects and environmental problems have a key role in the definition of building’s design, management and maintenance. The energy saving and the decrease of environmental impact throughout the life cycle assessment of buildings maintaining an high level of comfort are Key points for a modern and sustainable construction (total quality of the building). In fact, the building’s design has to be considered the result of a multi-objective problem. Furthermore the European Directive 2002/91/EC issues the sustainable themes on the energy performance of buildings [1], and include the energy certification of new buildings with effect from 2006

ESP-rSettore ING-IND/11 - Fisica Tecnica Ambientalethermal building simulation
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