Search results for "Thermodynamic equilibrium"
showing 10 items of 80 documents
Time-dependent Landauer-Büttiker formula for transient dynamics
2013
We solve analyti ally the Kadano Baym equations for a nonintera ting jun tion onne ted to an arbitrary number of nonintera ting wide-band terminals. The initial equilibrium state is properly des ribed by the addition of an imaginary tra k to the time ontour. From the solution we obtain the time-dependent ele tron densities and urrents within the jun tion. The nal results are analyti expressions as a fun tion of time, and therefore no time propagation is needed either in transient or in steady-state regimes. We further present and dis uss some appli ations of the obtained formulae. peerReviewed
Spinodal decomposition of polymer solutions: A parallelized molecular dynamics simulation
2008
In simulations of phase separation kinetics, large length and time scales are involved due to the mesoscopic size of the polymer coils, and the structure formation on still larger scales of length and time. We apply a coarse-grained model of hexadecane dissolved in supercritical carbon dioxide, for which in previous work the equilibrium phase behavior has been established by Monte Carlo methods. Using parallelized simulations on a multiprocessor supercomputer, large scale molecular dynamics simulations of phase separation following pressure jumps are presented for systems containing $N=435\phantom{\rule{0.2em}{0ex}}136$ coarse-grained particles, which correspond to several millions of atoms…
Incoherent Soliton Turbulence in Nonlocal Nonlinear Media
2011
The long-term behavior of a modulationally unstable nonintegrable system is known to be characterized by the soliton turbulence self-organization process: It is thermodynamically advantageous for the system to generate a large-scale coherent soliton in order to reach the (‘‘most disordered’’) equilibrium state. We show that this universal process of self-organization breaks down in the presence of a highly nonlocal nonlinear response. A wave turbulence approach based on a Vlasov-like kinetic equation reveals the existence of an incoherent soliton turbulence process: It is advantageous for the system to self-organize into a large-scale, spatially localized, incoherent soliton structure.
ERGODICITY IN RANDOMLY COLLIDING QUBITS
2009
The dynamics of a single qubit randomly colliding with an environment consisting of just two qubits is discussed. It is shown that the system reaches an equilibrium state which coincides with a pure random state of three qubits. Furthermore the time average and the ensemble averages of the quantities used to characterize the approach to equilibrium (purity and tangles) coincide, a signature of ergodic behavior.
Scale-free relaxation of a wave packet in a quantum well with power-law tails
2013
We propose a setup for which a power-law decay is predicted to be observable for generic and realistic conditions. The system we study is very simple: A quantum wave packet initially prepared in a potential well with (i) tails asymptotically decaying like ~ x^{-2} and (ii) an eigenvalues spectrum that shows a continuous part attached to the ground or equilibrium state. We analytically derive the asymptotic decay law from the spectral properties for generic, confined initial states. Our findings are supported by realistic numerical simulations for state-of-the-art expansion experiments with cold atoms.
Atomic transition probabilities of F I spectral lines from3s−3pand3p−3dtransition arrays
1999
We have measured the relative transition probabilities of about $100 3s\ensuremath{-}3p$ and $3p\ensuremath{-}3d$ lines of neutral fluorine in the visible and near-infrared spectrum with a wall-stabilized high-current arc, which is operated under conditions very close to partial local thermodynamic equilibrium. The set of measured lines includes about 40 intersystem transitions. Our data have been placed on an absolute scale by normalizing several strong transitions to the results of the OPACITY Project calculations, which are expected to be quite accurate for such transitions. We estimate that the uncertainties of our absolute transition probability values are in the \ifmmode\pm\else\textp…
One-dimensional Ising-like systems: an analytical investigation of the static and dynamic properties, applied to spin-crossover relaxation
2000
We investigate the dynamical properties of the 1-D Ising-like Hamiltonian taking into account short and long range interactions, in order to predict the static and dynamic behavior of spin crossover systems. The stochastic treatment is carried out within the frame of the local equilibrium method [1]. The calculations yield, at thermodynamic equilibrium, the exact analytic expression previously obtained by the transfer matrix technique [2]. We mainly discuss the shape of the relaxation curves: (i) for large (positive) values of the short range interaction parameter, a saturation of the relaxation curves is observed, reminiscent of the behavior of the width of the static hysteresis loop [3]; …
Truncated thermalization of incoherent optical waves through supercontinuum generation in photonic crystal fibers
2013
We revisit the process of optical wave thermalization through supercontinuum generation in photonic crystal fibers. We report theoretically and numerically a phenomenon of `truncated thermalization': The incoherent optical wave exhibits an irreversible evolution toward a Rayleigh-Jeans thermodynamic equilibrium state characterized by a compactly supported spectral shape. The theory then reveals the existence of a frequency cut-off which regularizes the ultraviolet catastrophe inherent to ensembles of classical nonlinear waves. This phenomenon sheds new light on the mechanisms underlying the formation of bounded supercontinuum spectra in photonic crystal fibers.
Stochastic Dynamics of Ferroelectric Polarization
2008
This study is addressed to the conceptual and technical problems emerging for ferroelectric systems out of thermodynamic equilibrium. The theoretical setup includes a lattice of interacting cells, each cell obeying regular dynamics determined by Ginzburg-Landau model Hamiltonians whereas relaxation toward minimum energy state is reproduced by thermal environment. Representative examples include polarization response of a single lattice cell, birth of a domain as triggered by the ergodicity breaking, and the effect of nonlocal electroelastic interaction all evidenced combining the Fokker-Planck, imaginary time Schrodinger and symplectic integration techniques.
Anomalous thermalization of nonlinear wave systems
2010
We report theoretically and experimentally in an optical system a process of anomalous thermalization of one-dimensional nonlinear Hamiltonian waves. It is characterized by an irreversible evolution of the waves towards a specific equilibrium state of a fundamental different nature than the expected thermodynamic equilibrium state. A kinetic approach of the problem reveals that this phenomenon is due to the existence of a local invariant in frequency space. A novel family of equilibrium distributions is discovered, which is found in quantitative agreement with the numerical simulations.