Search results for "Thermodynamic limit"
showing 10 items of 76 documents
Quantum Criticality in a Bosonic Josephson Junction
2011
In this paper we consider a bosonic Josephson junction described by a two-mode Bose-Hubbard model, and we thoroughly analyze a quantum phase transition occurring in the system in the limit of infinite bosonic population. We discuss the relation between this quantum phase transition and the dynamical bifurcation occurring in the spectrum of the Discrete Self Trapping equations describing the system at the semiclassical level. In particular, we identify five regimes depending on the strength of the effective interaction among bosons, and study the finite-size effects arising from the finiteness of the bosonic population. We devote a special attention to the critical regime which reduces to th…
Scaling of Berry's phase close to the Dicke quantum phase transition
2006
We discuss the thermodynamic and finite size scaling properties of the geometric phase in the adiabatic Dicke model, describing the super-radiant phase transition for an $N$ qubit register coupled to a slow oscillator mode. We show that, in the thermodynamic limit, a non zero Berry phase is obtained only if a path in parameter space is followed that encircles the critical point. Furthermore, we investigate the precursors of this critical behavior for a system with finite size and obtain the leading order in the 1/N expansion of the Berry phase and its critical exponent.
Symmetry-protected intermediate trivial phases in quantum spin chains
2015
Symmetry-protected trivial (SPt) phases of matter are the product-state analogue of symmetry-protected topological (SPT) phases. This means, SPt phases can be adiabatically connected to a product state by some path that preserves the protecting symmetry. Moreover, SPt and SPT phases can be adiabatically connected to each other when interaction terms that break the symmetries protecting the SPT order are added in the Hamiltonian. It is also known that spin-1 SPT phases in quantum spin chains can emerge as effective intermediate phases of spin-2 Hamiltonians. In this paper we show that a similar scenario is also valid for SPt phases. More precisely, we show that for a given spin-2 quantum cha…
Dynamical bifurcation as a semiclassical counterpart of a quantum phase transition
2011
We illustrate how dynamical transitions in nonlinear semiclassical models can be recognized as phase transitions in the corresponding -- inherently linear -- quantum model, where, in a Statistical Mechanics framework, the thermodynamic limit is realized by letting the particle population go to infinity at fixed size. We focus on lattice bosons described by the Bose-Hubbard (BH) model and Discrete Self-Trapping (DST) equations at the quantum and semiclassical level, respectively. After showing that the gaussianity of the quantum ground states is broken at the phase transition, we evaluate finite populations effects introducing a suitable scaling hypothesis; we work out the exact value of the…
All spin-1 topological phases in a single spin-2 chain
2014
Here we study the emergence of different Symmetry-Protected Topological (SPT) phases in a spin-2 quantum chain. We consider a Heisenberg-like model with bilinear, biquadratic, bicubic, and biquartic nearest-neighbor interactions, as well as uniaxial anisotropy. We show that this model contains four different effective spin-1 SPT phases, corresponding to different representations of the $(\mathbb{Z}_2 \times \mathbb{Z}_2) + T$ symmetry group, where $\mathbb{Z}_2$ is some $\pi$-rotation in the spin internal space and $T$ is time-reversal. One of these phases is equivalent to the usual spin-1 Haldane phase, while the other three are different but also typical of spin-1 systems. The model also …
Spin-$\frac{1}{2}$ Heisenberg antiferromagnet on the star lattice: Competing valence-bond-solid phases studied by means of tensor networks
2018
Using the infinite Projected Entangled Pair States (iPEPS) algorithm, we study the ground-state properties of the spin-$1/2$ quantum Heisenberg antiferromagnet on the star lattice in the thermodynamic limit. By analyzing the ground-state energy of the two inequivalent bonds of the lattice in different unit-cell structures, we identify two competing Valence-Bond-Solid (VBS) phases for different antiferromagnetic Heisenberg exchange couplings. More precisely, we observe (i) a VBS state which respects the full symmetries of the Hamiltonian, and (ii) a resonating VBS state which, in contrast to previous predictions, has a six-site unit-cell order and breaks $C_3$ symmetry. We also studied the g…
Quantum Hopfield Model
2020
We find the free-energy in the thermodynamic limit of a one-dimensional XY model associated to a system of N qubits. The coupling among the &sigma
Static and dynamic glass transitions in the 10-state Potts glass: What can Monte Carlo simulations contribute?
2002
The p-state Potts glass with infinite range Gaussian interactions can be solved exactly in the thermodynamic limit and exhibits an unconventional phase behavior if p >4: A dynamical transition from ergodic to non-ergodic behavior at a temperature T D is followed by a first order transition at T 0 < T D, where a glass order parameter appears discontinuously, although the latent heat is zero. If one assumes that a similar scenario occurs for the structural glass transition as well (though with the singular behavior at T D rounded off), the p-state Potts glass should be a good test case to develop methods to deal with finite size effects for the static as well as the dynamic transition, and to…
The reaction enthalpy of hydrogen dissociation calculated with the Small System Method from simulation of molecular fluctuations.
2014
We show how we can find the enthalpy of a chemical reaction under non-ideal conditions using the Small System Method to sample molecular dynamics simulation data for fluctuating variables. This method, created with Hill's thermodynamic analysis, is used to find properties in the thermodynamic limit, such as thermodynamic correction factors, partial enthalpies, volumes, heat capacities and compressibility. The values in the thermodynamic limit at (T,V, μj) are then easily transformed into other ensembles, (T,V,Nj) and (T,P,Nj), where the last ensemble gives the partial molar properties which are of interest to chemists. The dissociation of hydrogen from molecules to atoms was used as a conve…
Classical Statistical Mechanics
2003
Some aspects of statistical mechanics that are particularly important for computer simulation approaches are recalled. Using Ising and classical Heisenberg models as examples, various statistical ensembles and appropriate thermodynamic potentials are introduced, and concepts such as Legendre transformations between ensembles and the thermodynamic integration method to obtain the entropy are mentioned. Probability distributions characterizing statistical fluctuations are discussed, fluctuation relations for response functions are derived, and the behavior of these quantities at first and second order phase transitions are described qualitatively. Also the general consequences of phase coexis…