Search results for "Thixotropy"
showing 10 items of 12 documents
Design Of Experiments for the optimization the process parameters of thixotropic aluminum alloy
2006
The success of the thixoforming process depends on the possibility to confer to material, when it is found in the semisolid state, a microstructure characterized by globular particles of solid phase surrounded by a continuous film of liquid phase; such microstructure is obtainable through particular thermo-mechanical treatments. In the present research, in order to optimize the influence of process parameters in the step in which the thixotropic properties are conferred to the AA7075 aluminum alloy, the statistic technique of the Design Of Experiments (DOE) has been used. The advantages in the application of such technique are expressible in terms of reduction the times of development of pr…
A Multi-Component Reaction towards the Development of Highly Modular Hydrogelators
2018
Herein we report a multi‐component reaction approach for the development of a new class of hydrogelators based on the OxoTriphenylHexanOate (OTHO) backbone. A focused library of OTHOs has been synthesized and their hydrogelation features evaluated. The two most potent hydrogelators were studied by rheology revealing different stiffness, appearances and thixotropic behavior of the gels. The new gelators showcase the versatility of the OTHO backbone as a platform for the design of functionalized hydrogels with tunable gel properties. peerReviewed
Thixotropic Behavior of Salad Dressings Stabilized with Modified Starch, Pectin, and Gellan Gum. Influence of Temperature
2008
The thixotropy of low‐oil salad dressing has been analyzed at different temperatures (8–26°C). The usual formulation containing modified starch (4%) was compared with others in which part of the starch had been substituted by pectin (0.5%) or different concentrations of gellan (0.1 and 0.5%). Up and down flow curves were measured, showing in all cases shear thinning behavior and fitting the Herschel‐Bulkley model. Thixotropic areas enclosed by the up curve and the corresponding different down curves, STh, were obtained. With the aim of establishing comparative results, and since the viscosities were quite different, the parameter considered was relative thixotropic area, SR (%)=100 (STh/Sup…
Rheological Characterization of Low-calorie Milk-based Salad Dressings
1992
Oil-in-water emulsions of different quantitative composition, containing milk powder and locust bean gum. as stabilizing agents, showed similar rheological behavior: time-dependent thixotropic character and yield stress. Thixograms obtained for each sample could be modelled through the Hahn equation for the different shear rates. The analysis of the Hahn parameter variation for each sample as a function of shear rate led to a function σ= f(γ, t). Predicted shear stress values had relative errors lower than 10% in 99.9% of the samples studied. Analysis of composition influence on the rheological parameters showed an interactive role of gum, milk and acetic acid concentrations on emulsion con…
RHEOLOGICAL BEHAVIOUR OF MICROCRYSTALLINE CELLULOSE HYDROGELS
1992
ABSTRACT An extensive study was made of the rheological behaviour of microcrystal1ine cellulose-sodium carboxymethyl cellulose (MCC-NaCMC) gels at six different concentrations. The effect of agitation time, storage time, shear rate and temperature on the viscosity of these thixotropic gels was analysed, over 7200 resulting values of being available to this effect The pseudoplastic and thixotropic characteristics of the gels was established and a progressive decrease in gel viscosity with increasing storage time was observed, although retaining stability. On the other hand, constant agitation for five minutes was found to reduce gel viscosity by 40 to 50%, regardless of concentration.
Rapid Self-Healing and Thixotropic Organogelation of Amphiphilic Oleanolic Acid–Spermine Conjugates
2021
Natural and abundant plant triterpenoids are attractive starting materials for the synthesis of conformationally rigid and chiral building blocks for functional soft materials. Here, we report the rational design of three oleanolic acid-triazole-spermine conjugates, containing either one or two spermine units in the target molecules, using the Cu(I)-catalyzed Huisgen 1,3-dipolar cycloaddition reaction. The resulting amphiphile-like molecules 2 and 3, bearing just one spermine unit in the respective molecules, self-assemble into highly entangled fibrous networks leading to gelation at a concentration as low as 0.5% in alcoholic solvents. Using step-strain rheological measurements, we show ra…
Flow and thixotropy of non-contaminating oil drilling fluids formulated with bentonite and sodium carboxymethyl cellulose
2007
Abstract A study has been made of low-contaminating oil drilling mud in water base, composed of bentonite, at concentrations in the range of 6–12% (w/w), and sodium carboxymethyl cellulose at two different concentrations. Flow analysis yielded an empirical formula indicating shear stress as a function of the formulation concentrations of bentonite and sodium carboxymethyl cellulose, stirring time and shear rate. To study the thixotropy of the different formulations the cycles' method has been used. Calculations were made of the thixotropic areas, obtaining a semi-empirical equation for these areas. The results are analyzed on the base of relative thixotropic area and total relative thixotro…
Influence of process parameters for thixotropic alloys
2007
With reference to a metallic alloy, the attribute thixotropic is utilized to indicate the behaviour of it in the semi-solid state when its microstructure consists of spheroids in a liquid matrix. Such alloys are characterized by very low values of viscosity under shearing stress in the semi-solid state, while after solidification they show relevant mechanical properties. Actually a structural change from a dendritic structure to a globular one, with the globular grains finely dispersed in a liquid matrix, is observed after particular thermo-mechanical treatments. In the present paper the authors present the results of a wide experimental campaign on the AA 7075 aluminium alloy that shows a …
Cluster classification of dysphagia-oriented products considering flow, thixotropy and oscillatory testing
2011
Abstract The present paper proposes an objective classification of commercial thickened food widely used in patients with dysphagia. A total of 34 commercial enteral nutrition products were analyzed (beverages, main courses and desserts) corresponding to 6 different commercial brands. All these products contain different hydrocolloids (i.e., starch, xanthan gum, carrageenans, etc.) as thickeners, in order to get the desired texture. Joint consideration has been made of viscous behavior (flow and thixotropy) and viscoelastic behavior (oscillatory testing). Rheological measurements were fitted to different rheological and empirical mathematical models, and a total of 11 parameters were genera…
Thixotropy of Highly Viscous Sodium (Carboxymethyl)cellulose Hydrogels
1997
A general method to quantify the thixotropic behavior of systems with very low thixotropy is proposed. The areas enclosed by the rheograms τ=fγ. must be fitted to functions with well-determined boundary conditions. From these equations the corresponding thixotropic areas are obtained, together with the theoretical area enclosed by the rheogram corresponding to the maximum rheodestruction. The proposed method is applied to high viscosity sodium (carboxymethyl)cellulose gels.