Search results for "Titanite"
showing 8 items of 8 documents
ASSESSING TRACE ELEMENT (DIS)EQUILIBRIUM AND THE APPLICATION OF SINGLE ELEMENT THERMOMETERS IN METAMORPHIC ROCKS
2018
Abstract Empirical and experimental calibration of single element solubility thermometers, such as Zr-in-rutile, Zr-in-titanite, Ti-in-zircon, and Ti-in-quartz, within the past 13 years has greatly expanded our ability to assess the pressure and temperature conditions of individual minerals associated with specific textures in metamorphic rocks. Combined with advances in in situ techniques for analyzing trace concentrations, this has led to an increase in the combined use of single element thermometers, geochronometers, and isotope ratios, often simultaneously, in metamorphic minerals. Here we review the calibration and application of single element thermometers at the pressure and temperat…
Young ages from old garnet in the polyphase metamorphic terrane of the Limpopo Belt, South Africa
2020
Abstract The P–T–t path of high-grade metamorphic rocks is significant for understanding vertical motions and heating of the crust. In general, garnet is used to constrain P–T paths and metamorphic zircon is used to obtain t for different metamorphic stages. However, this approach may be complicated by polyphase tectonothermal events. The Central Zone of the Limpopo Belt in South Africa is a complex Precambrian metamorphic terrane that has experienced three distinct high-grade metamorphic events at 3.22 Ga (M1), 2.62 Ga (M2), and 2.02 Ga (M3), based on zircon dating. A previous investigation of a metapelite enclave in the Bulai pluton in the Central Zone showed that metamorphic zircon in th…
Structural anisotropy and annealing-induced nanoscale atomic rearrangements in metamict titanite
2012
The structural state of metamict titanite was studied by Raman spectroscopy, complementary high-resolution transmission electron microscopy, and single-crystal X-ray diffraction. The results show that Raman scattering collected from metamict titanite is highly anisotropic, which is typical of single crystals. But surprisingly, the observed Raman-scattering dependence on the sample orientation is much more pronounced for heavily metamict than for weakly metamict titanite samples. These radiation-induced anisotropic effects are related to the specific atomic arrangements in metamict titanite. The Raman spectra collected in backscattering geometry from a plane nearly perpendicular to the chain…
Metamorphic reaction rates at ∼650–800°C from diffusion of niobium in rutile
2014
Abstract The ability to quantify the rates at which metamorphic reactions occur is critical to assessing the extent to which equilibrium is achieved and maintained in a variety of dynamic settings. Here we investigate the kinetics of rutile replacement by titanite during amphibolite-facies overprinting of eclogite, garnet amphibolite and anorthosite from Catalina Island, CA, the Tromso Nappe, Norway, the North Qaidam terrane, China, and the Guichicovi Complex, Mexico. Trace element concentration profiles across rutile rimmed by titanite, as determined by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), reveal Nb zoning in rutile that we interpret as the result of Nb …
The effect of titanite and other HFSE-rich mineral (Ti-bearing andradite, zircon, eudialyte) fractionation on the geochemical evolution of silicate m…
2008
Abstract We present trace element data for HFSE-rich minerals (titanite, eudialyte, Ti-bearing andradite, zircon) from plutonic rocks of the Eocene Tamazeght complex, High Atlas Mountains, Morocco. In most lithologies significant amounts of titanite are present and as such, titanite fractionation played a major role in the evolution of the HFSE budget of the whole complex. By combining our data with published titanite–melt partition coefficients we explore the effects of titanite fractionation on the evolution of geochemical parameters (Zr/Hf, Nb/Ta, La/Lu and Th/U ratios) during differentiation of silicate melts in detail. Based upon this, we further discuss the genetic relationships betwe…
Hydrothermal origin and age of jadeitites from Sierra del Convento Mélange (Eastern Cuba)
2012
Jadeitite (jadeite jade) from Sierra del Convento (eastern Cuba) occurs in a subduction-related serpentinite-matrix melange associated with a variety of high-pressure tectonic blocks including garnet-amphibolites and related anatectic trondhjemites. The eastern Cuban jadeitite is massive and characterized by rare quartz inclusions and omphacite exsolution in jadeite crystals, as well as replacement or infilling by omphacite. Minor minerals include epidote, biotite, albite, phengite, titanite, rutile, zircon, and apatite. Oscillatory zoning in jadeite crystals and zircon ages suggest hydrothermal crystallization in veins formed in serpentinized peridotite, probably of the mantle wedge. Al-Na…
Growth of zircon and titanite during metamorphism in the granitoid-gneiss terrane south of the Barberton greenstone belt, South Africa
2005
AbstractSHRIMP U-Pb zircon and titanite dating have been used to constrain the timing of mid- to lower- crustal metamorphism (∼650—700°C and 8—11 kbar) and syn-kinematic melting in the granitoid gneiss- dominated terrane south of the Barberton greenstone belt, South Africa. This study is concentrated on a clastic metasedimentary unit exposed in one of several greenstone remnants and a late-kinematic trondhjemite intrusive into spatially associated mixed gneisses. Locally, the clastic metasediments show extensive replacement of garnet and plagioclase by epidote and titanite. The titanites yield an upper intercept date of 3229±9 Ma, and provide a minimum age for the peak of metamorphism. Zirc…
Unraveling the exhumation history of high-pressure ophiolites using magnetite (U-Th-Sm)/He thermochronometry
2020
International audience; Magnetite is a ubiquitous oxide in ultramafic and mafic rocks, which is present in a large range of geological and tectonic settings. In the case of high-pressure ultramafic rocks, exhumation timing is commonly constrained by geochronometers in nearby lithologies. The development of the magnetite (U-Th-Sm)/He method (MgHe) has opened new perspectives to refine the exhumation history of such rocks. However no thermal history has been deduced using MgHe data so far. Here we applied MgHe dating to magnetite from an HP-LT alpine ophiolite body (Rocher Blanc) from the Schistes lustres units (Western Alps, France) where part the P-T-t history is constrained to further refi…