Search results for "Titanium"

A multi-step mechanism and integrity of titanate nanoribbons.

2014

A one-step hydrothermal treatment of TiO2 powders under strongly basic conditions has been used to synthesize titanate nanoribbons. The nanoparticles were thoroughly characterized using several methods including transmission electron microscopy (TEM), X-ray diffraction (XRD), Raman spectroscopy and X-ray photoelectron spectrometry (XPS) to determine their morphological, structural and chemical characteristics. The influence of the nature and size of the TiO2 precursor and of the reaction duration on the formation of the nanoribbons was investigated. The conditions required to obtain only titanate nanoribbons with a width ranging from 100 to 200 nm and several tens of micrometers in length w…

Intrinsic Nature of the Excess Electron Distribution at theTiO2(110)Surface

2012

The gap state that appears upon reduction of TiO2 plays a key role in many of titania's interesting properties but its origin and spatial localization have remained unclear. In the present work, the TiO2(110) surface is reduced in a chemically controlled way by sodium adsorption. By means of resonant photoelectron diffraction, excess electrons are shown to be distributed mainly on subsurface Ti sites strikingly similar to the defective TiO2(110) surface, while any significant contribution from interstitial Ti ions is discarded. In agreement with first principles calculations, these findings demonstrate that the distribution of the band gap charge is an intrinsic property of TiO2(110), indep…

Inorganic gels as precursors of TiO2 photocatalysts prepared by low temperature microwave or thermal treatment

2008

Abstract A simple procedure for preparing active TiO2 photocatalysts is presented. The starting materials were unusual TiO2 gels formed from TiCl4. The use of microwaves for a very short time enhanced the TiO2 crystallinity preventing an increase of particle size and minimizing the decrease of specific surface area. This result makes this preparation very attractive. The formation of the gels was monitored through measurements of viscosity. All the samples were characterized by means of X-ray diffraction, diffuse reflectance spectroscopy and BET specific surface area measurements. The photoactivity of the samples was evaluated using the photodegradation of 4-nitrophenol in liquid–solid regi…

Study of the high temperature behaviour of titanium alloy Ti6242S under complex atmospheres : aeronautical applications

2018

The use of titanium alloys in many applications (transport, energy, chemistry,...) allows significant weight savings in relation to the good mechanical properties/density ratio of these materials. Since titanium alloys are employed at high temperatures (T>500°C), their behavior in such conditions has to be studied in severe conditions in order to understand degradation mechanisms. Moreover, some specific conditions can be met during application, like thermal cycling, water vapour or presence of salts. These parameters are known to influence oxidation behavior of titanium alloys.In this thesis work, oxidation behavior of an aeronautics titanium alloy (Ti6242S) has been studied in air and moi…

Photocatalytic ozonation under visible light for the remediation of water effluents and its integration with an electro-membrane bioreactor

2018

Abstract Photocatalysis and photocatalytic ozonation under visible light have been applied for the purification of a complex aqueous matrix such as the grey water of Masdar City (UAE), by using N-doped brookite-rutile catalysts. Preliminary runs on 4-nitrophenol (4-NP) solutions allowed to test the reaction system in the presence of a model pollutant and to afford the relevant kinetic parameters of the process. Subsequently, the remediation of grey water effluent has been evaluated in terms of the reduction of total organic carbon (TOC) and bacterial counts. The concentration of the most abundant inorganic ionic species in the effluent has been also monitored during reaction. Photocatalytic…

ELECTROCHEMICAL FABRICATION OF METAL/OXIDE/CONDUCTING POLYMER JUNCTIONS FOR ELECTRONIC DEVICES

2014

Supermolecular control of charge transfer in dye-sensitized nanocrystalline TiO2 films: towards a quantitative structure-function relationship.

2005

Representative major element compositions of clinopyroxenes and phlogopites from ultrapotassic rocks from Nangqian basin (Eastern Tibet)

2020

Representative major element compositions (in wt%) of clinopyroxenes and phlogopites from Nangqian ultrapotassic rocks. In-situ major-element compositions of mineral phases were obtained using the JEOL JXA-8230 Electron Microprobe at ISTerre, University Grenoble Alpes. Analytical conditions were 15 kV accelerating voltage and 12 nA beam current. The ZAF procedure was applied to reduce the raw data. The microprobe was calibrated using natural and synthetic standards. An X-ray element map of a calcite-bearing aggregate was acquired using 15 kV accelerating voltage and 10 nA beam current.

Method for Manufacturing Custom-Shaped Prosthetic Parts from Titanium Alloys by Incremental Forming Using Industrial Robots

2014

The last decade has shown an increasing interest in a new class of forming processes known as Incremental Sheet forming (ISF). A possible application for this new procedure, targeted by the authors of this paper, is the manufacturing of custom-shaped prosthetic parts for use in various areas of human medicine. Such prostheses can have a functional role, when they target the replacing of a functional component of the human body, or an esthetic role, when they target the solving of problems related to the appearance of the human body. In this paper the authors aim to determine the strain hardening curves for the titanium alloy Ti6Al4V at room temperature and at 800°C. The incremental forming …

Evaluation of the effects of titanium dioxide and aluminum oxide nanoparticles through tarsal contact exposure in the model insect Oncopeltus fasciat…

2019

Abstract Despite the increasing presence of metal nanoparticles in the biosphere as a consequence of their widespread use, knowledge about the impact of these nanoparticles on fauna, ecosystems and human health is far from completion. This is especially true for terrestrial invertebrates. Insects are environmentally exposed to nanoparticles by several ways, the ectopic contact being one of the most probable. The model insect Oncopeltus fasciatus, has been used in the present work for testing toxicity of nanoparticles present in a surface. Adverse effects of TiO2 nanoparticles and Al2O3 in nanoparticulated or bulk form on mortality, reproductive and embryonic developmental parameters have be…