Search results for "Titanium"
showing 10 items of 878 documents
Electrochemical Fabrication and Physicochemical Characterization of Metal/High-k Insulating Oxide/Polymer/Electrolyte Junctions
2014
Photoelectrochemical polymerization of poly(3,4-ethylenedioxythiophene), PEDOT, was successfully realized on anodic film grown to 50 V on magnetron sputtered Ti-6 atom % Si alloys. Scanning electron microscopy allowed us to evidence formation of compact and uniform polymer layers on the oxide surface. Photoelectrochemical and impedance measurements showed that photopolymerization allows one to grow PEDOT in its conducting state, while a strong cathodic polarization is necessary to bring the polymer in its p-type semiconducting state. Information on the optical and electrical properties of metal/oxide/polymer/electrolyte junctions proves that PEDOT has promising performance as an electrolyte…
Phase evolution in hot forging of dual phase titanium alloys: Experiments and numerical analysis
2014
Abstract Modern aeronautical and aerospace industries must face the demanding challenge of reducing operational consumption and production costs coming from materials and labor. Current trend of engineering is oriented to meet both requirements increasing the use of materials characterized by high specific resistance as titanium alloys. Hot forging can be used to reduce the production costs of titanium components: forging in closed dies of billets or semi-finished forms, at different temperatures above or below the β-transus temperature, allows the production of complex shapes with limited amount of edge trim removal and machining rework after forging. Unfortunately, as far as Ti–6Al–4V tit…
Friction Stir Processing of NiTi Shape Memory Alloy: Microstructural Characterization
2010
Shape Memory Alloys (SMA) are metal materials that, after being strained, come back to their original shape at a designated temperature. Welding NiTi alloys is not simple because when the material is melted, due to the high reactivity of the alloy elements, the typical shape memory properties may disappear. The solid state welding process, such as friction stir welding, is thus attractive for SMA joining and it exhibits potentials for achieving welded joints affected by microstructural changes that preserve the shape memory properties. The present study investigates the feasibility of friction stir welding process to join NiTi shape memory alloys; in order to analyse the welding process, it…
Friction stir welding of dissimilar aluminium– magnesium joints: Sheet mutual position effects
2015
Friction stir welding (FSW) is a solid state welding process used to weld difficult to be welded or unweldable materials as aluminium alloys. In the last years, other materials have been successfully tested as magnesium, titanium and nickel based alloys. Dissimilar joints can be obtained by FSW, but issues arise concerning the correct choice of the process parameters. In the paper, the results of an experimental and numerical campaign aimed to produce dissimilar AZ31-AA6016-T6 butt joints are presented. The effect of sheet mutual position and main process parameters was investigated. It was found that intermetallics are the main cause of the poor quality of the joints. Sound joints can be p…
Joining Ti6Al4V and AISI 304 through friction stir welding of lap joints: experimental and numerical analysis
2014
The results of an experimental and numerical analysis on Friction Stir Welding of dissimilar lap joints made out of AISI304 and Ti-6Al-4 V thin sheets are presented. The mixed joints, welded with varying process parameters, have been characterized from a mechanical and metallurgical point of view. A numerical model able to take into account the behaviour of the two different materials has been used. The numerical results have been utilized to explain the joint properties and the occurring material flow. The effect of the heat input, tilt angle and sheets mutual position has been investigated. It is found that both hooking defects and tunnels may occur with incorrect choice of process parame…
Effect of Poly(Titanium Oxide) on the Viscoelastic and Thermophysical Properties of Interpenetrating Polymer Networks
2021
The authors thank V. Serga for many useful discussions. The research was (partly) performed in the Institute of Solid State Physics, University of Latvia ISSP UL. ISSP UL as the Center of Excellence is supported through the Framework Program for European universities Union Horizon 2020, H2020-WIDESPREAD-01–2016–2017-Teaming Phase 2 under Grant Agreement No. 739508, CAMART2 project.
The combined effect of refractory coatings containing reactive elements on high temperature oxidation behavior of chromia-forming alloys
2003
Abstract The high temperature oxidation behaviors of chromia-forming alloys (F17Ti and Fe–30Cr alloys) have been studied at 1273 K under isothermal conditions and at 1223 K under cyclic conditions, in air under the atmospheric pressure. To extend the oxidation lifetime, coatings have been applied onto the alloy surfaces. Al2O3 and Cr2O3 films doped with Sm2O3 or Nd2O3 were prepared via the metal-organic chemical vapor deposition technique. Single Cr2O3, Al2O3, Nd2O3 and codeposited Cr2O3–Nd2O3, Al2O3–Nd2O3, Al2O3–Sm2O3 coatings drastically improved the chromia-forming alloy high temperature oxidation behavior, since they decreased the oxidation rate and enhanced the oxide scale adhesion. Re…
Role of plastic deformation and microstructure in the micro-electrochemical behaviour of Ti–6Al–4V in sodium chloride solution
2013
Abstract The role of alloying elements and the influence of plastic deformation on the micro-electrochemical behaviour and the pitting corrosion susceptibility of TiAl6V4 have been investigated in 10 g/L NaCl using the electrochemical microcell technique. Local electrochemical measurements have revealed that both the increase of surface roughness and the increase of dislocation density have impact on the electrochemical behaviour of TiAl6V4 after plastic deformation. It has been shown the surface roughness induced by slip band emergence is the predominant parameter responsible for the increase of the cathodic current. It has also been shown that cathodic reactions occur preferentially at su…
Influence of plastic deformation on the microstructure and corrosion behaviour of Ti–10Mo–4Zr and Ti–6Al–4V alloys in the Ringer’s solution at 37°C
2015
Abstract The influence of plastic deformation on the microstructure and passivity of Ti–6Al–4V and Ti–10Mo–4Zr is studied. The content of titanium-based compounds in the passive film formed on the alloys increases under straining. In the region where necking occurs, the β-phase content drops in Ti–6Al–4V. The grain orientation spread increases with increasing strain. The quality index of EBSD maps is affected on Ti–10Mo–4Zr (dislocation structures along preferential orientations). The corrosion behaviour is investigated in the Ringer’s solution (37 °C). Results obtained in the anodic and cathodic domains are discussed considering changes described previously.
Paper Functionalized with Nanostructured TiO2/AgBr: Photocatalytic Degradation of 2–Propanol under Solar Light Irradiation and Antibacterial Activity
2020
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