Search results for "Tone"

CCDC 2081387: Experimental Crystal Structure Determination

2021

Related Article: Marco Meyer, Lorenzo Mardegan, Daniel Tordera, Alessandro Prescimone, Michele Sessolo, Henk J. Bolink, Edwin C. Constable, Catherine E. Housecroft|2021|Dalton Trans.|50|17920|doi:10.1039/D1DT03239A

CCDC 883708: Experimental Crystal Structure Determination

2013

Related Article: Julia R. Shakirova, Elena V. Grachova, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Matti Haukka, Tapani A. Pakkanen, and Igor O. Koshevoy|2013|Organometallics|32|4061|doi:10.1021/om301100v

CCDC 955946: Experimental Crystal Structure Determination

2013

Related Article: Julia R. Shakirova, Elena V. Grachova, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Matti Haukka, Tapani A. Pakkanen, and Igor O. Koshevoy|2013|Organometallics|32|4061|doi:10.1021/om301100v

Ab initio multi-reference perturbation theory calculations of the ground and low-lying electronic states of the KRb molecule

2016

The potential energy curves of the low-lying electronic states correlating up to the limit K(4p) + Rb(5s) of KRb molecule have been calculated using the multi-reference perturbation theory method at the CASSCF/ XMCQDPT2 level of theory without and with spin–orbit coupling. The calculated parameters of the ground X 1 R + state are in the best agreement among all previously performed ab initio calculations for the KRb molecule. The calculated vibrational intervals of the ground electronic term of the 39 K 85 Rb molecule describe the experiment with the accuracy within ±1 cm ?1 . The calculated intensities of the 2 1 R + (v 0 = 3, J 0 = 26) ? X 1 R + (v 00 = 0...24, J 00 = 25, 27) transitions …

Ring opening polymerization of d,l-lactide and ε-caprolactone catalysed by (pyrazol-1-yl)copper(ii) carboxylate complexes

2021

1,2-Bis{(3,5-dimethylpyrazol-1-yl)methyl}benzene (L) reacts with [Cu(OAc)2] and C6H5COOH, 4-OH-C6H4COOH, 2-Cl-C6H4COOH and (3,5-NO2)2-C6H3COOH to afford the copper complexes [Cu2(C6H5COO)4(L)2] (1), [Cu2(4-OH-C6H4COO)4(L)2] (2), [Cu2(2-Cl-C6H4COO)4(L)2]n (3) and [Cu{(3,5-NO2)2-C6H3COO}2L]n (4) which are characterised by IR, mass spectrometry, elemental analyses, and X-ray crystallography. The structural data revealed two geometries that are adopted by the complexes: (i) paddle wheel in 1, 2·7H2O, 3 and (ii) regular chains in 3 and 4. Magnetic studies show strong antiferromagnetic couplings in the paddle wheel complexes and a weak antiferromagnetic coupling in the monometallic chain one. Cat…

A family of layered chiral porous magnets exhibiting tunable ordering temperatures.

2013

A simple change of the substituents in the bridging ligand allows tuning of the ordering temperatures, Tc, in the new family of layered chiral magnets A[M(II)M(III)(X2An)3]·G (A = [(H3O)(phz)3](+) (phz = phenazine) or NBu4(+); X2An(2-) = C6O4X2(2-) = 2,5-dihydroxy-1,4-benzoquinone derivative dianion, with M(III) = Cr, Fe; M(II) = Mn, Fe, Co, etc.; X = Cl, Br, I, H; G = water or acetone). Depending on the nature of X, an increase in Tc from ca. 5.5 to 6.3, 8.2, and 11.0 K (for X = Cl, Br, I, and H, respectively) is observed in the MnCr derivative. Furthermore, the presence of the chiral cation [(H3O)(phz)3](+), formed by the association of a hydronium ion with three phenazine molecules, lead…

The oldest granite clast in the Moodies conglomerate, Barberton greenstone belt, South Africa, and its likely origin

2018

The high overtone and combination levels of SF6 revisited at Doppler-limited resolution: A global effective rovibrational model for highly excited vi…

2017

Abstract Sulfur hexafluoride is an important prototypal molecule for modeling highly excited vibrational energy flow and multi quanta absorption processes in hexafluoride molecules of technological importance. It is also a strong greenhouse gas of anthropogenic origin. This heavy species, however, features many hot bands at room temperature (at which only 30% of the molecules lie in the ground vibrational state), especially those originating from the lowest, v 6 =1 vibrational state. Using a cryogenic long path cell with variable optical path length and temperatures regulated between 120 and 163 K, coupled to Synchrotron Radiation and a high resolution interferometer, Doppler-limited spectr…

A new ichnofauna from the Permian of the Zat Valley in the Marrakech High Atlas of Morocco

2020

Abstract A new ichnofauna from the Permian of Morocco is described in details: it is the first Palaeozoic ichnofauna from the Zat Valley in Marrakech High Atlas. The new tracksite was found in the Tighdouine region, in the middle-upper Permian of the Cham-el-Houa Siltstone Formation. An abundant and diverse ichnoassemblage composed of both protostomian (probably arthropods and annelids) traces and vertebrate tracks is recorded. The presence of protostomian burrows and traceways, associated with tetrapod tracks corresponds to the Scoyenia ichnofacies. Protostomian traces are ascribed to Diplichnites gouldi, Diplopodichnus biformis, Scoyenia cf. gracilis and Spongeliomorpha carlsbergi. Tetrap…

Acoustic properties of ancient shallow-marine carbonates: effects of depositional environments and diagenetic processes (Middle Jurassic, Paris Basin…

2010

17 pages; International audience; Examination of petrophysical properties (acoustic velocity, porosity, permeability, and density) and petrographical characteristics (texture, facies composition, and diagenesis) of more than 250 core plugs from the Middle Jurassic carbonates of the eastern Paris Basin provides insights into the parameters controlling acoustic velocities in relatively low-porosity carbonate rocks ({Phi} < 20%). The pore-type observations reveal distinct acoustic velocities in samples with intergranular macropores and samples with micropores in subhedral micrite, such that velocities in microporous mudstone–wackestone (lagoonal) deposits are greater than in macroporous grains…