Search results for "Toni"
showing 10 items of 8001 documents
Electrochemical reduction of graphene oxide films in aqueous and organic solutions
2013
Abstract Electrochemical reduction of graphene oxide (GO) films cast on tin oxide glass substrates were carried out in aqueous solutions and in propylene carbonate and acetonitrile. Cyclic voltammetric measurements indicate successful reduction of GO films. The reduction process begins in aqueous solutions at less negative potentials than in organic solutions. Additionally the pH value of the aqueous solutions influences the reduction potential. According to spectroscopic analysis the reduction process of the GO film can be controlled by the choice of reduction potential and electrolyte medium. The potential window in this work was made broader by increasing pH or by using organic electroly…
Transition metal binding properties of the redox-active 1,4,7,10,13,16-hexa(ferrocenylmethyl)-1,4,7,10,13,16-hexaazacyclooctadecane and its electroch…
1999
Abstract Solution studies to elucidate the coordination behaviour and the electrochemical response of the ferrocene-functionalized polyazamacrocycle 1,4,7,10,13,16-hexa(ferrocenylmethyl)-1,4,7,10,13,16-hexaazacyclooctadecane (L1) by potentiometric methods and electrochemical techniques have been carried out. Potentiometric methods in the presence of Cd2+, Hg2+, Pb2+ and Zn2+ were carried out in 1,4-dioxane/water (70:30 v/v, 25°C, 0.1 mol dm−3 KNO3). Electrochemical studies were carried out in acetonitrile/dichloromethane (50:50 v/v, 25°C, 0.1 mol dm−3 TBAClO4) in the presence of transition metal ions and anions.
Influence of chloride anions on the electrodeposition and electroactivity of the polymer matrix in polypyrrole, poly( N -methylpyrrole) and polypyrro…
2004
We report electrochemical studies on the influence of a small concentration of chloride ions on the electroactivity of the polymer matrix of polypyrrole (PPy), poly(N-methylpyrrole) [p(N-MePy)] and a poly(titanocene-propyl-pyrrole) derivative, p(Tc3Py) [Tc(CH2)3NC4H4; Tc=CpCp′TiCl2; Cp=C5H5; Cp′=C5H4] in acetonitrile (AN), tetrahydrofuran (THF) and N,N-dimethylformamide (DMF). The polymer films were obtained on Pt disc electrodes from AN solutions of the monomers containing 0.1 M tetrabutylammonium hexafluorophosphate (TBAPF6) as the supporting electrolyte and then transferred to the corresponding monomer-free solution. Studies in Cl−-containing solutions have shown that the p(Tc3Py) matrix…
Peri-Gondwanan Ordovician arc magmatism in southeastern Ireland and the Isle of Man: Constraints on the timing of Caledonian deformation in Ganderia
2018
The timing of and tectonic controls on Ordovician magmatism and deformation within accreted terranes are key elements in reconstructing the generation of the Caledonian-Appalachian orogen. This pap ...
Agrigento. Laboratorio di Laurea
2013
The essay outlines the peculiarities of the Course of Studies in Architecture held by the University of Palermo in Agrigento for about 20 years. The complex situation of the city and of its province have been sigled out and read by architectural design courses. Themes focused have been over the years: the overlapping of archaelogy and architecture; the ghost role of the old city; the overwhelming presence of infrastructures; the orographic condition of the multi centered city.
A partire dalla manutenzione: strategie per i siti archeologici
2010
A dieci anni dal Regolamento attuativo della Legge Merloni, il contributo punta ad aggiornare lo stato dell’arte sulla manutenzione dei siti archeologici. Nonostante i numerosi passi avanti, il quadro mostra ancora alcune ambiguità, mentre molti siti continuano a versare in condizioni precarie. La limitatezza delle risorse disponibili, tanto più grave pensando alla vastità del patrimonio culturale, per molto tempo ha costituito un alibi per trascurare la manutenzione. Invece essa costituisce un incentivo per una più efficiente gestione. Si tratta: dell’ambiguità del rapporto manutenzione/conservazione, dei paradossi normativi e dei limiti della programmazione, della specificità della manute…
L’incompletezza del patrimonio architettonico: testimonianze in terra cruda a Solunto
2015
L'incompletezza riassume la maggior parte delle caratteristiche fisiche e immateriali del patrimonio architettonico e produce due conseguenze principali: la sua elevata vulnerabilità e le difficoltà di comprensione. Questo tema offre anche una parola chiave per capire alcune situazioni critiche nei processi di conoscenza, conservazione e valorizzazione sul patrimonio architettonico. Le testimonianze di terra cruda superstiti a Solunto non sono tanto rilevanti per quantità e dimensione, ma forniscono un esempio lampante di questo tema. L’obiettivo di conservare questi pochi lacerti soluntini di architettura in crudo può assumere un maggior senso, se esso si collega, da un lato, alle potenzia…
La fornace di pietra a Marsa Siklah
2013
La fornace Penna, uno dei più interessanti esempi di Archeologia Industriale in Sicilia, è oggi ridotta a un rudere che si avvia ad una inesorabile fine. Le imponenti strutture di calcare perdono di giorno in giorno la loro stabilità statica e si sgretolano precipitando al suolo. Inutili gli appelli, le petizioni, gli allarmi e le richieste di intervento sollevate da più parti. Errori, ritardi burocratici, polemiche e interessi contrastanti hanno reso vani tutti i tentativi di salvare la ‘vecchia signora’. Questo libro è un omaggio all’opera del progettista, un geniale professionista siciliano del secolo scorso, ma anche a tutti coloro che nel corso di questi anni hanno testimoniato nei mod…
A Holocene relative sea-level database for the Baltic Sea
2021
Highlights: • A first standardized and publicly available Holocene relative sea-level database for the Baltic Sea is presented. • The database holds 1099 revised data points with an estimation of vertical and chronological uncertainties. • Negative RSL tendencies prevail over the positive and complex tendencies in the Baltic Sea Basin. • Mid-Holocene RSL highstand occurred around 7.5–6.5 ka BP being consistent with the end of the final melting of the LIS. • The contribution of ice loading in the eastern Baltic Sea Basin is likely overestimated in the ICE-5G and ICE-6G_C models. Abstract: We present a compilation and analysis of 1099 Holocene relative shore-level (RSL) indicators located aro…
The Mediterranean Sea and the Gulf of Cadiz as a natural laboratory for paleotsunami research: Recent advancements
2021
International audience; After the 2004 Indian Ocean (IOT) and the 2011 Tohoku-oki tsunamis, new research in tsunami-related fields was strongly stimulated worldwide and also in the Mediterranean. This research growth yields substantial advancements in tsunami knowledge.Among these advancements is the “Paleotsunami” research that has marked particular progress on the reconstruction of the tsunami history of a region. As an integration of the historical documentation available in the Mediterranean and the Gulf of Cadiz areas, geological and geoarchaeological records provide the insights to define the occurrence, characteristics, and impact of tsunamis of the past. Here, we present the recent …