Search results for "Total pressure"
showing 4 items of 14 documents
Simultaneous optimization of mobile phase composition, column nature and length to analyse complex samples using serially coupled columns
2013
Abstract The combination of the selectivity of different columns serially coupled improves the separation expectancies with regard to the separation offered by each single column. In the reported approaches, either a pre-selected isocratic mobile phase composition or gradient program, giving rise to acceptable retention, is used. In previous work (JCA 1281 (2013) 94), we showed that the approach succeeds with conventional columns, assembled through zero-dead volume couplers. In this work, the simultaneous interpretive optimization of mobile phase composition and column nature and length, based on a limited number of experimental data, is demonstrated. This approach allows an impressive redu…
Osmotic pressure, atomic pressure and the virial equation of state of polymer solutions: Monte Carlo simulations of a bead-spring model
1994
A recently introduced coarse-grained model of polymer chains is studied analyzing various contributions to the pressure as obtained from the virial theorem as a function of chain length N, temperature T and density ϕ. The off-lattice model of the polymer chains has anharmonic springs between the beads, but of finite extensibility, and the Morse-type interaction between beads is repulsive at very short distances and attractive at intermediate distances. Solvent molecules are not explicitly included. It is found that the covalent forces along the chain (modelled by the spring potentials) contribute a negative term to the pressure, irrespective of temperature, which vanishes linearly in ϕ as ϕ…
Semidilute and Concentrated Polymer Solutions near Attractive Walls: Dynamic Monte Carlo Simulation of Density and Pressure Profiles of a Coarse-Gra…
1997
Using a bead−spring model of flexible polymer chains, we study polymer adsorption from solutions onto attractive planar walls, varying both the strength of the adsorption potential e and the concentration of the solution over a wide range. Treating the case of good solvents, the profiles of density and pressure are computed and it is shown that thermal equilibrium between the adsorbed layer and the bulk solution is obtained. The case of a wall with purely repulsive potential under otherwise identical conditions is treated for comparison. It is shown that for the strongly adsorbing wall there is a pronounced layering, while a layered structure at the repulsive wall occurs only for high conce…
The XMM Cluster Outskirts Project (X-COP): Thermodynamic properties of the Intracluster Medium out to $R_{200}$ in Abell 2319
2018
We present the joint analysis of the X-ray and SZ signals in A2319, the galaxy cluster with the highest signal-to-noise ratio in Planck maps and that has been surveyed within our XMM Cluster Outskirts Project (X-COP). We recover the thermodynamical profiles by the geometrical deprojection of the X-ray surface brightness, of the SZ comptonization parameter, and an accurate and robust spectroscopic measurements of the temperature. We resolve the clumpiness of the density to be below 20 per cent demonstrating that most of this clumpiness originates from the ongoing merger and can be associated to large-scale inhomogeneities. This analysis is done in azimuthally averaged radial bins and in eigh…