Search results for "Toxic metal"

showing 5 items of 15 documents

Sequestering ability of landfill leachate towards toxic metal ions

2017

The great part of municipal solid wastes is worldwide stored in sanitary landfills. The interaction of organic and inorganic wastes with rainwater produces in the landfill a leachate of extremely variable composition. It depends on several variables such as the type of wastes, the age of landfill, the pH, the redox potential, etc [1-2]. Four are the recognized categories of pollutants in landfill leachate: inorganic macrocomponents, dissolved organic matter (DOM), heavy metals and xenobiotic organic compounds [3]. In particular, heavy metals (arsenic, cadmium, copper, lead, mercury, etc.) are usually present at concentration of few ppb and up to some ppm. A variable but consistent fraction …

Settore CHIM/01 - Chimica AnaliticaLandfill leachate sequestration toxic metal ions speciation Differential Pulse Anodic Stripping Voltammetry
researchProduct

Functionalized Halloysite for enhanced removal of toxic metal ions from aqueous solutions

2018

During the last years several nanomaterials have been extensively used in the heavy metal ions removal from aqueous solutions. Among them, clay minerals have gathered particular interest owing to their unique features (e.g., high specific surface area, low toxicity and natural availability at low price). Halloysite nanotubes (Hal) are particular clay minerals with a predominantly hollow tubular structure. In this work Hal and their derivatives, Hal-NH2 and Hal-SH, were used as adsorbent materials of lead(II) and mercury(II) ions from aqueous solutions. The adsorption ability of clay nanomaterials towards toxic metal ions has been studied takeing into account important variables of the metal…

Settore CHIM/01 - Chimica AnaliticaSettore CHIM/06 - Chimica OrganicaHalloysite toxic metal metal removal nanotube lead mercury voltammetry
researchProduct

Biochar from byproduct to high value added material – A new adsorbent for toxic metal ions removal from aqueous solutions

2018

Abstract An activated biochar coming from pyrolysis of dead Posidonia oceanica residues has been tested as adsorbent material for Cd2+, Pb2+ and Cu2+ ions. The biomass, the activated and the non activated biochars were previously characterized by using several instrumental techniques. The pH of metal ion solution in kinetic and thermodynamic adsorption experiments was fixed at 5 whilst, the dependence on ionic medium, ionic strength and temperature have been evaluated carrying out batch experiments at different experimental conditions. Differential Pulse Anodic Stripping Voltammetry and Inductively Coupled Plasma Optical Emission Spectroscopy have been used to measure the metal ion concentr…

Speciation020209 energyMetal ions in aqueous solutionInorganic chemistryIonic bondingToxic metal02 engineering and technology010501 environmental sciences01 natural sciencesAdsorptionBiochar0202 electrical engineering electronic engineering information engineeringMaterials ChemistryToxic metalsSettore CHIM/01 - Chimica AnaliticaPhysical and Theoretical ChemistryMaterialsSpectroscopy0105 earth and related environmental sciencesAqueous solutionChemistryPosidonia oceanicaCondensed Matter PhysicsAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsBiocharAnodic stripping voltammetryIonic strengthAdsorptionPyrolysisJournal of Molecular Liquids
researchProduct

Carbohydrate-supramolecular gels : adsorbents for chromium(VI) removal from wastewater.

2019

Abstract Hypothesis To overcome the contamination of water by heavy metals the adsorption of the pollutant on gel phases is an attractive solution since gels are inexpensive, potentially highly efficient and form a distinct phase while allowing diffusion of the contaminated water throughout the material. This work tests the chromium(VI) adsorbent capacity of new supramolecular gels for Chromium(VI) removal from wastewater. Experiments First hydrophobic imidazolium salts of carbohydrate anions were synthesised as new gelators. Subsequently, they were dissolved in a solvent by heating and, after cooling overnight, to give the formation of supramolecular gels. The properties of the resulting g…

Supramolecular chemistryInfrared spectroscopychemistry.chemical_element02 engineering and technologychemisorption010402 general chemistry01 natural sciencesBiomaterialsChromiumchemistry.chemical_compoundColloid and Surface ChemistryAdsorptionThermal stabilityHexavalent chromiumhexavalent chromiumChemistrySettore CHIM/06 - Chimica Organica021001 nanoscience & nanotechnology0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsSolventcarbohydrate gelatorwastewater treatmentChemical engineeringreduction of toxic metalSelf-healing hydrogelsSupramolecular gel0210 nano-technologyenvironmental remediation
researchProduct

Spontaneous urban weeds: a resource against environmental pollution

2022

Quality of the environment and social well-being, both at a collective and individual level, are closely interrelated issues. It is, in fact, a relationship that invests values of primary importance, such as those relating to human health and safety, heritage and resources to be passed on to future generations. Plant growth and survival can be challenged by harsh urban conditions. Many studies show the persistence of endemic species in built-up areas and document the ecosystem services provided. With this research we wanted to investigate the bioaccumulation of heavy metals such as cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), arsenic (As), molibden (Mo), cadmium (Cd), lead (Pb) and mer…

potentially toxic metals weeds biomonitoring urban areasHorticultureSettore AGR/02 - Agronomia E Coltivazioni Erbacee
researchProduct