Search results for "Trace Element"
showing 10 items of 321 documents
Geochemical heterogeneities in magma beneath Mount Etna recorded by 2001-2006 melt inclusions
2015
We present a geochemical study on olivine and clinopyroxene-hosted melt inclusions (MIs) from 2001 to 2006 Etna basaltic lavas and pyroclastites. Three MI suites are distinguished on the basis of trace element fingerprinting. Type-1 MIs (from 2001 Upper South and 2002 Northeast vents) share their trace element signature with low-K lavas erupted before 1971. Critical trace element ratios (e.g., K/La, Ba/Nb), along with Pb isotope data of Type-1 MIs provide evidence for a heterogeneous mantle source resulting from mixing of three end-members with geochemical and isotopic characteristics of EM2, DMM, and HIMU components. Type-1 MIs composition does not support involvement of subduction-related…
Volcanism on the Eggvin Bank (Central Norwegian-Greenland Sea, latitude ∼71°N): age, source, and relationship to the Iceland and putative Jan Mayen p…
2004
Abstract The Eggvin Bank (Central Norwegian-Greenland Sea, latitude ∼71°N) is a topographically anomalous shallow area with scattered volcanic peaks extending between the island of Jan Mayen and East Greenland and straddling the northern segment of the mid-Atlantic Kolbeinsey Ridge axis. Basalts dredged from the Eggvin Bank range from variably depleted, tholeiitic, near-axis lavas to enriched, transitional-to-alkaline, off-axis seamount lavas. In terms of normalised incompatible element patterns, the most depleted, near-axis tholeiite is similar to neighbouring Kolbeinsey Ridge basalts, whereas the off-axis, transitional-to-alkaline lavas are similar to other alkaline basalts occurring clos…
Raw material variability as archaeological tools: Preliminary results from a geochemical study of the basalt vessel workshop at Iron Age Tel Hazor, I…
2016
The discovery of a basalt vessel workshop at Tel Hazor, one of the most important Iron Age sites in the Near East, marks a turning point in our understanding of stone artifact production and distribution during the1st millennium BCE. It offers a rare opportunity to characterize ancient raw material sources, production sites, and study production, trade and distribution systems. The basalt vessel workshop, the only one of its kind in the Levant, produced large quantities of bowl preforms and production waste. To better understand the production and distribution systems behind this specialized production center, in 2011 we initiated a focused geochemical project that concentrated on the produ…
Sr-Nd-Pb isotope ratios, geochemical compositions, and40Ar/39Ar data of lavas from San Felix Island (Southeast Pacific): Implications for magma genes…
2000
We present the first trace element and age data combined with new Sr, Nd, and Pb isotope ratios on lavas from San Felix Island in the Southeast Pacific. A 40Ar/39Ar plateau age of 421 ± 18 ka implies young intraplate volcanic activity in this region relative to the ∼22 Ma old volcanism on the neighbouring Easter seamount chain (ESC). The incompatible element compositions of the San Felix magmas are similar to those of EM1-type basalts from Gough, although the isotopic compositions differ. San Felix formed some 20 Ma after the ESC plume affected the plate in this region but no chemical signature of the ESC material is observed in the young volcanic rocks. The composition of the San Felix bas…
Hafnium-Neodymium isotope, trace element and U-Pb zircon age constraints on the petrogenesis of the 3.44–3.46 Ga Dwalile greenstone remnant, Ancient …
2020
Abstract The geodynamic setting of the 3.44–3.46 Ga Dwalile greenstone remnant (DGR) of the Ancient Gneiss Complex (Swaziland) and its relationship to other Greenstone belts of similar age is investigated in this contribution. We present Hf-Nd isotope, major and trace element data for komatiites, komatiitic basalts, basalts, basaltic andesites as well as felsic volcanic and sedimentary rocks, all metamorphosed at amphibolite-facies grade. Major and trace element compositions of metabasalts and metakomatiites indicate crustal contamination. The best-preserved samples yield 176Lu-176Hf and 147Sm-143Nd isochron ages of ca. 3500 and 3460 Ma, respectively, in line with U-Pb zircon ages of interl…
Coupled evolution of back-arc and island arc-like mafic crust in the late-Neoproterozoic Agardagh Tes-Chem ophiolite, Central Asia: evidence from tra…
2002
We report major-element, trace-element and isotopic data of volcanic rocks from the late-Neoproterozoic (570 Ma) Agardagh Tes-Chem ophiolite in Central Asia, south-west of Lake Baikal (50.5°N, 95°E). The majority of samples are high-alumina basalts and basaltic andesites having island-arc affinities. They were derived from an evolved parental magma (Mg#≥0.60, Cr~180 ppm, Ni~95 ppm) by predominantly clinopyroxene fractionation. The parental magma developed from a primary mantle melt by fractionation of about 12% of an olivine+spinel assemblage. The island-arc rocks have high abundances of incompatible trace elements (light rare-earth element abundances up to 100 times chondritic, chondrite-n…
Atmospheric sources and sinks of volcanogenic elements in a basaltic volcano (Etna, Italy)
2011
Abstract This study reports on the first quantitative assessment of the geochemical cycling of volcanogenic elements, from their atmospheric release to their deposition back to the ground. Etna’s emissions and atmospheric depositions were characterised for more than 2 years, providing data on major and trace element abundance in both volcanic aerosols and bulk depositions. Volcanic aerosols were collected from 2004 to 2007, at the summit vents by conventional filtration techniques. Precipitation was collected, from 2006 to 2007, in five rain gauges, at various altitudes around the summit craters. Analytical results for volcanic aerosols showed that the dominant anions were S, Cl, and F, and…
Changes in soil chemical properties as affected by pyrogenic organic matter amendment with different intensity and frequency
2017
Pyrogenic organic matter (PyOM) has long been used as a soil amendment to improve soil physicochemical properties. However, few studies simultaneously investigated both intensities and frequencies of PyOM addition on soil chemical properties of soil base cations, soil pH buffering capacity (pHBC), and plant available micronutrients. In the main food production area of lower Liaohe River Plain in Northeast China, a field manipulation of PyOM addition was initiated in 2013 to examine how the intensities (0, 1%, 3%, and 5% of 0–20 cm soil mass) and frequencies (3% of soil mass applied once versus yearly for 3 years) of PyOM amendment affected soil chemical properties. Higher intensity of PyOM …
Towards the development of a fossil bone geochemical standard: An inter-laboratory study
2007
Ten international laboratories participated in an inter-laboratory comparison of a fossil bone composite with the objective of producing a matrix and structure-matched reference material for studies of the bio-mineralization of ancient fossil bone. We report the major and trace element compositions of the fossil bone composite, using in-situ method as well as various wet chemical digestion techniques. For major element concentrations, the intra-laboratory analytical precision (%RSDr) ranges from 7 to 18%, with higher percentages for Ti and K. The %RSDr are smaller than the inter-laboratory analytical precision (%RSDR; 100% was found for the high field strength elements (Hf, Th, Zr, Nb). The…
Iron isotope signature of magnetofossils and oceanic biogeochemical changes through the Middle Eocene Climatic Optimum.
2021
21 pages; International audience; Magnetotactic bacteria (MTB) intracellularly precipitate magnetite (Fe3O4) crystals that can be preserved in the geological record. When MTB die, the so-called magnetofossils constitute valuable proxies for paleoenvironmental reconstructions and are suspected to represent some of the oldest traces of biomineralization on Earth. Yet, the biogenicity of putative magnetofossils found in ancient terrestrial and extra-terrestrial samples is still largely debated and their significance for past climate still holds uncertainties. Here we studied a sedimentary sequence from the Indian Ocean (ODP Hole 711A) recording the Middle Eocene Climatic Optimum (MECO) through…