Search results for "Transform"

showing 10 items of 3975 documents

Film-forming process and biocide assessment of high-molecular-weight chitosan as determined by combined ATR-FTIR spectroscopy and antimicrobial assay…

2006

This pioneering study reported about the film-forming properties of high-molecular-weight chitosan as followed in situ by attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy, and has implications in fields such as biomedical, pharmaceutical, packaging, and coating applications. From the results, it was observed that immediately after dissolution in an acetic acid aqueous solution and subsequent casting over the ATR crystal, the formed carboxylate antimicrobial (-NH3+ -OOCH) species are not stable in the film formulation and become reduced over time; further assays confirmed previous research, which suggested that the presence and stability of these groups is stron…

BiocideChitosanAqueous solutionBacteriaOrganic ChemistryBiophysicsGeneral Medicineengineering.materialAntimicrobialBiochemistryAnti-Bacterial AgentsBiomaterialsChitosanchemistry.chemical_compoundchemistryAttenuated total reflectionPolymer chemistrySpectroscopy Fourier Transform InfraredengineeringBiopolymerCarboxylateFourier transform infrared spectroscopyNuclear chemistryBiopolymers
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Design, characterization and in vitro evaluation of 5-aminosalicylic acid loaded N-succinyl-chitosan microparticles for colon specific delivery

2011

The objective of this study was to prepare NS-chitosan microparticles for the delivery of 5-aminosalicylic acid (5-ASA) to the colon. Microparticles can spread out over a large area of colon allowing a more effective local efficacy of 5-ASA. N-Succinyl-chitosan was chosen as carrier system because of its excellent pharmaceutical properties in colon drug targeting such as poor solubility in acid environment, biocompatibility, mucoadhesive properties, and low toxicity. It was prepared by introducing succinic group into chitosan N-terminals of the glucosamine units. 5-ASA loaded NS-chitosan microparticles were prepared using spray-drying. As a control, a matrix obtained by freeze-drying techni…

BiocompatibilityCarrier systemColonStatic ElectricityBiocompatible MaterialsNanotechnologyChitosanchemistry.chemical_compoundDrug Delivery SystemsColloid and Surface ChemistryDifferential scanning calorimetryX-Ray DiffractionSpectroscopy Fourier Transform InfraredmedicineZeta potentialHumansDesiccationParticle SizePhysical and Theoretical ChemistrySolubilityMesalamineChitosanCalorimetry Differential ScanningSurfaces and InterfacesGeneral MedicineHydrogen-Ion ConcentrationMicrospheresKineticsFreeze DryingSolubilitychemistryTargeted drug deliveryMicroscopy Electron ScanningWettabilitySwellingmedicine.symptomRheologyBiotechnologyNuclear chemistryColloids and Surfaces B: Biointerfaces
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Biogenic Selenium Nanoparticles: A Fine Characterization to Unveil Their Thermodynamic Stability

2021

Among the plethora of available metal(loid) nanomaterials (NMs), those containing selenium are interesting from an applicative perspective, due to their high biocompatibility. Microorganisms capable of coping with toxic Se-oxyanions generate mostly Se nanoparticles (SeNPs), representing an ideal and green alternative over the chemogenic synthesis to obtain thermodynamically stable NMs. However, their structural characterization, in terms of biomolecules and interactions stabilizing the biogenic colloidal solution, is still a black hole that impairs the exploitation of biogenic SeNP full potential. Here, spherical and thermodynamically stable SeNPs were produced by a metal(loid) tolerant Mic…

BiocompatibilityGeneral Chemical EngineeringNanoparticle02 engineering and technologyDFT calculationsArticleMicrococcusNanomaterials03 medical and health sciencesAdsorptionbiogenic selenium nanoparticlesMoleculeGeneral Materials ScienceFourier transform infrared spectroscopyQD1-999030304 developmental biologymultivariate statistical analysischemistry.chemical_classification0303 health sciencesBiomolecule021001 nanoscience & nanotechnologyChemistryFTIR spectroscopychemistryChemical engineering<i>Micrococcus</i>thermodynamic stabilityChemical stabilityselenium nanorods0210 nano-technologyNanomaterials
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Charging a Capacitor from an External Fluctuating Potential using a Single Conical Nanopore

2015

We explore the electrical rectification of large amplitude fluctuating signals by an asymmetric nanostructure operating in aqueous solution. We show experimentally and theoretically that a load capacitor can be charged to voltages close to 1 V within a few minutes by converting zero time-average potentials of amplitudes in the range 0.5–3 V into average net currents using a single conical nanopore. This process suggests that significant energy conversion and storage from an electrically fluctuating environment is feasible with a nanoscale pore immersed in a liquid electrolyte solution, a system characteristic of bioelectronics interfaces, electrochemical cells, and nanoporous membranes.

BioelectronicsMultidisciplinaryMaterials scienceNanostructurebusiness.industryElectrolyteConical surfaceBioinformaticsArticleElectrochemical celllaw.inventionTransductionNanoporeCapacitorlawIon channelsFISICA APLICADADevicesOptoelectronicsEnergy transformationbusinessScientific Reports
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Mathematical Modelling of In-sewer Processes as a Tool for Sewer System Design

2018

The objective of this paper is to evaluate the potential impact of in-sewer processes (COD components transformation and hydrogen sulphide production) on the design of sewer systems. The tool used for such analysis is a mathematical model derived from the WATS model (Wastewater Aerobic/anaerobic Transformation in Sewers) able to describe the processes occurring in the sewer system both under aerobic and anaerobic conditions. The model is applied to three synthetic catchments with, respectively, 10,000, 50,000 and 250,000 inhabitants connected to gravity sewer systems different in terms of type (separate or combined), slope, length, travel time, wastewater temperature. The simulation results…

Biological nutrients removaPotential impactSettore ICAR/03 - Ingegneria Sanitaria-AmbientaleSewerEnvironmental engineeringAerobic/anaerobic conditionHydrogen sulphideWastewater transformationTravel timeAerobic/anaerobic conditions Sewer Wastewater transformations Biological nutrients removalWastewaterEnvironmental scienceSystems designSanitary sewer
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Novel Iris Biometric Watermarking Based on Singular Value Decomposition and Discrete Cosine Transform

2014

Published version of an article in the journal: Mathematical Problems in Engineering. Also available from the publisher at: http://dx.doi.org/10.1155/2014/926170 A novel iris biometric watermarking scheme is proposed focusing on iris recognition instead of the traditional watermark for increasing the security of the digital products. The preprocess of iris image is to be done firstly, which generates the iris biometric template from person's eye images. And then the templates are to be on discrete cosine transform; the value of the discrete cosine is encoded to BCH error control coding. The host image is divided into four areas equally correspondingly. The BCH codes are embedded in the sing…

BiometricsArticle SubjectGeneral MathematicsIris recognitionComputingMethodologies_IMAGEPROCESSINGANDCOMPUTERVISIONEngineering (all)Robustness (computer science)Computer Science::MultimediaDiscrete cosine transformMathematics (all)Computer visionDigital watermarkingTransform codingMathematicsComputer Science::Cryptography and Securitybusiness.industrylcsh:MathematicsVDP::Technology: 500::Mechanical engineering: 570General EngineeringWatermarkVDP::Technology: 500::Information and communication technology: 550lcsh:QA1-939ComputingMethodologies_PATTERNRECOGNITIONlcsh:TA1-2040Computer Science::Computer Vision and Pattern RecognitionArtificial intelligencebusinesslcsh:Engineering (General). Civil engineering (General)BCH codeMathematics (all); Engineering (all)Mathematical Problems in Engineering
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Genesis of amorphous calcium carbonate containing alveolar plates in the ciliate Coleps hirtus (Ciliophora, Prostomatea).

2013

7 pages; International audience; In the protist world, the ciliate Coleps hirtus (phylum Ciliophora, class Prostomatea) synthesizes a peculiar biomineralized test made of alveolar plates, structures located within alveolar vesicles at the cell cortex. Alveolar plates are arranged by overlapping like an armor and they are thought to protect and/or stiffen the cell. Although their morphology is species-specific and of complex architecture, so far almost nothing is known about their genesis, their structure and their elemental and mineral composition. We investigated the genesis of new alveolar plates after cell division and examined cells and isolated alveolar plates by electron microscopy, e…

Biomineralization570Morphology (linguistics)MineralogyColeps hirtus02 engineering and technologyCalcium Carbonatelaw.invention03 medical and health scienceschemistry.chemical_compoundX-Ray DiffractionStructural BiologylawSpectroscopy Fourier Transform InfraredCell cortexCiliophora[SDV.IB.BIO]Life Sciences [q-bio]/Bioengineering/BiomaterialsAlveolar plates030304 developmental biologyCiliate0303 health sciencesProstomateabiologyVesicleCiliateSpectrometry X-Ray Emission500respiratory system021001 nanoscience & nanotechnologybiology.organism_classification[ SDV.IB.BIO ] Life Sciences [q-bio]/Bioengineering/BiomaterialsAmorphous calcium carbonateMicroscopy ElectronchemistryProtozoanBiophysicsAmorphous calcium carbonateElectron microscope0210 nano-technologyBiomineralization
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Climate variation during the Holocene influenced the skeletal properties of Chamelea gallina shells in the North Adriatic Sea (Italy)

2021

Understanding how marine taxa will respond to near-future climate changes is one of the main challenges for management of coastal ecosystem services. Ecological studies that investigate relationships between the environment and shell properties of commercially important marine species are commonly restricted to latitudinal gradients or small-scale laboratory experiments. This paper aimed to explore the variations in shell features and growth of the edible bivalve Chamelea gallina from the Holocene sedimentary succession to present-day thanatocoenosis of the Po Plain-Adriatic Sea system (Italy). Comparing the Holocene sub-fossil record to modern thanatocoenoses allowed obtaining an insight o…

BiomineralizationAtmospheric ScienceRecrystallization (geology)010504 meteorology & atmospheric sciencesPhysiologyOceans and Sea01 natural sciencesAnimal ShellX-Ray DiffractionSpectroscopy Fourier Transform InfraredHoloceneClimatologySedimentary GeologyMineralsMultidisciplinaryQuaternary PeriodbiologyGeographyFossilsQREukaryotaFossilGeologyMineralogyDiagenesisOceanographyItalyTaphonomyPhysical SciencesMedicineChamelea gallina[SDU.STU.PG]Sciences of the Universe [physics]/Earth Sciences/PaleontologyPorosityGeologyResearch Article010506 paleontologyBivalvesScienceClimate ChangeOceans and SeasMaterials ScienceMaterial PropertiesClimate changeengineering.materialCalcium CarbonateCalcification PhysiologicAnimal ShellsAnimals14. Life underwaterPaleoclimatologyEcosystem0105 earth and related environmental sciencesPetrologyHolocene EpochAnimalAragoniteRadiometric DatingOrganismsBiology and Life SciencesPaleontologyGeologic TimeMolluscsbiology.organism_classificationInvertebratesBivalviaSea surface temperatureAragonite13. Climate actionengineeringEarth SciencesCenozoic EraSedimentary rockSedimentPaleobiologyPhysiological ProcessesZoologyPloS One
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Quantification of hydrolysis of toxic organophosphates and organophosphonates by diisopropyl fluorophosphatase from Loligo vulgaris by in situ Fourie…

2008

Abstract The enzyme diisopropyl fluorophosphatase (DFPase) from the squid Loligo vulgaris effectively catalyzes the hydrolysis of diisopropyl fluorophosphate (DFP) and a number of organophosphorus nerve agents, including sarin, soman, cyclosarin, and tabun. Up to now, the determination of kinetic data has been achieved by techniques such as pH-stat titration, ion-selective electrodes, and fluorogenic substrate analogs. We report a new assaying method using in situ Fourier transform infrared (FTIR) spectroscopy with attenuated total reflection (ATR) for the real-time determination of reaction rates. The method employs changes in the P–O–R stretching vibration of DFP and nerve agent substrate…

BiophysicsLoligoOrganophosphonatesInfrared spectroscopyCyclosarinBiochemistrychemistry.chemical_compoundSpectroscopy Fourier Transform InfraredmedicineOrganic chemistryAnimalsFourier transform infrared spectroscopyOrganophosphorus acid anhydrolaseMolecular BiologyDiisopropyl-fluorophosphataseTabunChromatographyHydrolysisOsmolar ConcentrationCell BiologyOrganophosphatesKineticsPhosphoric Triester HydrolaseschemistryAttenuated total reflectionDiisopropyl fluorophosphatemedicine.drugAnalytical biochemistry
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Biowaiver Monograph for Immediate-Release Solid Oral Dosage Forms: Bisoprolol Fumarate

2014

Abstract Literature data relevant to the decision to allow a waiver of in vivo bioequivalence (BE) testing for the approval of immediate-release (IR) solid oral dosage forms containing bisoprolol as the sole active pharmaceutical ingredient (API) are reviewed. Bisoprolol is classified as a Class I API according to the current Biopharmaceutics Classification System (BCS). In addition to the BCS class, its therapeutic index, pharmacokinetic properties, data related to the possibility of excipient interactions, and reported BE/bioavailability problems are taken into consideration. Qualitative compositions of IR tablet dosage forms of bisoprolol with a marketing authorization (MA) in ICH (Inter…

Bisoprolol FumarateCell Membrane PermeabilityAdrenergic beta-AntagonistsBiological AvailabilityPharmaceutical ScienceExcipientPharmacologyBioequivalenceDosage formBiopharmaceuticsExcipientsmedicineBisoprololHumansTissue DistributionBiotransformationChromatography High Pressure LiquidHeart FailureActive ingredientChemistryStereoisomerismHydrogen-Ion ConcentrationBiopharmaceutics Classification SystemBioavailabilityIntestinal AbsorptionSolubilityTherapeutic EquivalencyBisoprololmedicine.drugJournal of Pharmaceutical Sciences
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