Search results for "Transition temperature"

Collapse of Cylindrical Brushes with 2-Isopropyloxazoline Side Chains Close to the Phase Boundary

2013

A high-molar-mass cylindrical brush polymer with a main chain degree of polymerization of Pw = 1047 is synthesized by free-radical polymerization of a poly-2-isopropyloxazoline macromonomer with Pn = 28. The polymerization is conducted above the lower phase transition temperature of the macromonomer, i.e., in the phase-separated regime, which provides a sufficiently concentrated macromonomer phase mandatory to obtain high-molar-mass cylindrical brushes. Upon heating to the phase transition temperature, the hydrodynamic radius is observed to shrink from 34 to 27 nm. Further increase in temperature resulted in aggregated chains which were observed to coexist with single chains until eventuall…

1984

Influence de la structure de chaine sur le type de phase et relation entre la masse moleculaire et les temperatures de transition

Effect of the crystallization on the phase transitions IV ⇐ III and IV ⇐ II of ammonium nitrate

1993

Abstract The solid state phase transition path of ammonium nitrate is influenced by the manner of crystallization. Slow crystallization from water gives ideal crystals, which behaved differently from crystals prepared by rapid crystallization from the melt.

Microstructure and characteristic properties of dogfish skin gelatin gels prepared by freeze/spray-drying methods

2020

International audience; The effects of two pretreatments (microwaves or oven-drying) on the dogfish (Squalus acanthias) skin as well as two drying processes (freeze-drying or spray-drying) on the extracted gelatins were studied. Thus six types of gelatins were obtained, three of which were freeze-dried (FG) and the others were spray-dried (SG), from the untreated skin (US), microwaves-pretreated skin (MS) and oven-pretreated skin (OS). The highest yield (8.67%) was obtained for the OSFG, while the lowest one (3.06%) was measured for the OSSG. Interestingly, all gelatins exhibited relatively high protein (84.02-89.53%), and low lipid (0.50-1.71%) and ash (3.05-7.17%) contents. In addition, g…

Grain boundary ridges slow dawn grain boundary motion: In-situ observation

2014

Abstract The impact of grain boundary (GB) ridge on motion of high-angle GB in Zn was studied. The steady-state motion of faceted GB half-loop with [ 10 1 ¯ 0 ] tilt GB and GB ridge was recorded in-situ. The temperatures of faceting–roughening transition were experimentally defined for three GB half-loops. Above the transition temperature GB half-loops had GB “rough-to-rough” ridge with continuously curved GB segments. Below the transition temperature a facet appeared and coexisted with two “facet-to-rough” ridges. For the first time we could extract mobility of “rough-to-rough” and “rough-to-facet” ridges and bring out clearly that GB ridge slows down GB motion. Present removes contradicti…

Pressure- and temperature-induced valence tautomeric interconversion in a o-dioxolene adduct of a cobalt-tetraazamacrocycle complex

2001

An electronic switch at the molecular level has been realized by using a class of ionic compounds of the formula [Co(L)(diox)]Y (L = tetraazamacrocyclic ligand, Y = mononegative anion). Such compounds undergo temperature- and pressure-induced intramolecular one-electron transfer equilibria. The transition temperature of interconversion varies with the nature of the counterions Y (Y = PF6, BPh4, I). Surprisingly the effect of the anion on the transition temperature is not only governed by its volume but also by its coulombic interaction.

Effect of Core–Shell Rubber Nanoparticles on the Mechanical Properties of Epoxy and Epoxy-Based CFRP

2022

This research was funded by M-Era.Net project MERF “Matrix for carbon reinforced epoxy laminates with reduced flammability” grant No. 1.1.1.5/ERANET/20/04 from the Latvian State Education Development Agency and M-Era.Net project “EPIC—European Partnership for Improved Composites“ funded by grant No. TH06020001. A.S., K.S. and A.Z. are grateful to funding received from the European Union Horizon 2020 Framework program H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART2.