Search results for "Transition"
showing 10 items of 3988 documents
The [Fe(etz)6](BF4)2 Spin-Crossover System—Part One: High-Spin ⇌ Low-Spin Transition in Two Lattice Sites
1996
The [Fe(etz),](BF,), spin-cross-over system (etz = 1-ethyl-1 H-tetrazole) crystallizes in space group P1, with the following lattice constants at 298 K: a 10.419(3), b=15.709(1), c = 18.890(2) A = = 71.223(9), =77.986(10), and = 84.62(1)° V = 2862.0(9) A3 and Z = 3. Two nonequivalent lattice sites, one without (site A) and one with (site B) inversion symmetry, are observed. The population of the two sites nA:nB is 2:l. Iron(II) on site A undergoes a thermal low-spin (LS) high-spin (HS) transition with T1/2I, = 105 K. whereas that on site B remains in the high-spin state down to cryogenic temperatures. Application of external pressure of up to 1200 bar between 200 and 60 K does not cause for…
Origin of the large spectral shift in electroluminescence in a blue light emitting cationic iridium(III) complex
2007
A new, but archetypal compound [ Ir( ppy- F-2) (2)Me(4)phen] PF6, where ppy- F2 is 2-(2',4'- fluorophenyl) pyridine and Me(4)phen is 3,4,7,8- tetramethyl- 1,10- phenanthroline, was synthesized and used to prepare a solid-state light-emitting electrochemical cell (LEEC). This complex emits blue light with a maximum at 476 nm when photoexcited in a thin film, with a photoluminescence quantum yield of 52%. It yields an efficient single-component solid-state electroluminescence device with a current efficiency reaching 5.5 cd A(-1) and a maximum power efficiency of 5.8 Lm Watt(-1). However, the electroluminescence spectrum is shifted with respect to the photoluminescence spectrum by 80 nm resul…
A new 3-D polymeric spin transition compound: [tris(1,4-bis(tetrazol-1-yl)butane-N1,N 1′)iron(II)] bis(perchlorate)
2001
A series of novel polymeric compounds of formula [M(btzb)3][ClO4]2 (Mll = Fe, Ni or Cu) with btzb = 1,4-bis-(tetrazol-1-yl)butane have been prepared and their physical properties investigated. The btzb ligand has been prepared and its crystal structure determined, together with a tentative crystal structure of the 3-D compound [Fe(btzb)3][ClO4]2. The model of the latter shows two symmetry-related, interpenetrating Fe-btzb networks in which the iron(II) ions approach each other as close as 8.3 and 9.1 A. This supramolecular catenane undergoes a sharp thermal spin transition around 160 K with hysteresis (20 K) along with a pronounced thermochromic effect. The spin crossover behaviour has been…
Mössbauer Emission Spectroscopy of Mixed-Valency after Nuclear Decay in Iron Complexes
1991
The population of anomalous spin states and aliovalent charge states of iron induced by the 57 Co(EC)57 Fe nuclear decay in polycristalline transition metal compounds was studied by means of Coincidence Mossbauer Emission Spectroscopy (CMES), that is Time-Differential Mossbauer Emission Spectroscopy (TDMES) as well as γ/Xray-Coincidence Mossbauer Emission Spectroscopy (γ/X-CMES). By use of time-integral Mossbauer emission spectroscopy (TIMES) we have observed anomalous high spin (S = 2) states of 57 Fe(II) in the system [57Co/Co(phen)3(ClO 4)2 with increasing intensities on lowering the temperature. With TDMES we followed quantitatively the high spin-low spin relaxation kinetics in this com…
Understanding the stereo- and regioselectivities of the polar Diels-Alder reactions between 2-acetyl-1,4-benzoquinone and methyl substituted 1,3-buta…
2009
The polar Diels–Alder (DA) reactions of 2-acetyl-1,4-benzoquinone (acBQ) with methyl substituted 1,3-butadienes have been studied using DFT methods at the B3LYP/6-31G(d) level of theory. These reactions are characterized by a nucleophilic attack of the unsubstituted ends of the 1,3-dienes to the β conjugated position of the acBQ followed by ring-closure. The reactions present a total regioselectivity and large endo selectivity. The analysis based on the global electrophilicity of the reagents at the ground state, and the natural bond orbital (NBO) population analysis at the transition states correctly explain the polar nature of these cycloadditions. The large electrophilic character of acB…
Potential Resistance of Employees to Change in the Transition to Industry 5.0
2021
The unprecedented evolution of the technological environment inevitably generates resistance to change in the population. The paper aims to detect these resistances in the conditions of a future transition to Industry 5.0. Firstly, we present the results of a bibliographic study of the specialized literature, in order to answer the dilemma of the existence or absence of the differences between the two concepts, that of Industry 4.0 and that of Industry 5.0. Secondly, the paper contains the results of an online survey based on a questionnaire conducted among employees in the central area of Romania. The research is related to the employees’ perception on the possible evolution of the economi…
Search for Magnetic Monopoles and Stable High-Electric-Charge Objects in 13 Tev Proton-Proton Collisions with the ATLAS Detector
2020
We thank CERN for the very successful operation of the LHC, aswell as the support staff fromour institutionswithout whom ATLAS could not be operated efficiently. We acknowledge the support of ANPCyT, Argentina; YerPhI, Armenia; ARC, Australia; FWF, BMWFW, Austria; ANAS, Azerbaijan; SSTC, Belarus; CNPq, FAPESP, Brazil; NSERC, CFI, NRC, Canada; CERN; CONICYT, Chile; CAS, NSFC, MOST, China; COLCIENCIAS, Colombia; VSC CR, MSMT CR, MPO CR, Czech Republic; DNSRC, DNRF, Denmark; IN2P3-CNRS, CEA-DRF/IRFU, France; SRNSFG, Georgia; MPG, HGF, BMBF, Germany; GSRT, Greece; RGC, Hong Kong SAR, Hong Kong China; Benoziyo Center, ISF, Israel; INFN, Italy; JSPS, MEXT, Japan; JINR; CNRST, Morocco; NWO, Nether…
Low-lying electromagnetic transition strengths in 180 Pt
2018
Lifetime measurements have been performed using the 98 Mo ( 86 Kr , 4 n ) 180 Pt reaction at a beam energy of 380 MeV, and the recoil distance Doppler-shift method. In a second experiment the 168 Yb ( 16 O , 4 n ) 180 Pt reaction at a beam energy of 88 MeV using the Ge-gated γ − γ fast timing technique was used to determine lifetimes. Lifetimes of the four lowest yrast states of 180 Pt have been determined. The experimental data are compared to calculations within the framework of the interacting boson model and the general collective model. Both models predict a deformed ground state and are consistent with all the remaining experimental results. peerReviewed
β-decay rates of 115,117Rh into 115,117Pd isotopes in the microscopic interacting boson-fermion model
2020
The structure of odd-A 115,117Rh and 115,117Pd isotopes is studied by means of the neutron-proton interacting boson-fermion model (IBFM-2). JP=12+ quantum number assignment for the 115,117Pd ground states is critically discussed and the predicted energy levels are compared to the existing experimental data. The resulting nuclear wave functions are used to compute the β-decay ft values of the transitions from 115,117Rh to 115,117Pd in the microscopic IBFM-2 and the results compared with the data. peerReviewed
Chirality of 135 Nd reexamined : Evidence for multiple chiral doublet bands
2019
One new pair of positive-parity chiral doublet bands have been identified in the odd-A nucleus 135Nd which together with the previously reported negative-parity chiral doublet bands constitute a third case of multiple chiral doublet (MχD) bands in the A ≈ 130 mass region. The properties of the MχD bands are well reproduced by constrained covariant density functional theory and particle rotor model calculations. The newly observed MχD bands in 135Nd represents an important milestone in supporting the existence of MχD in nuclei. peerReviewed