Search results for "Transmission"
showing 10 items of 2080 documents
Genotoxic effects of zinc oxide nanoparticles
2015
The potential toxicity of nanoparticles has currently provoked public and scientific discussions, and attempts to develop generally accepted handling procedures for nanoparticles are under way. The investigation of the impact of nanoparticles on human health is overdue and reliable test systems accounting for the special properties of nanomaterials must be developed. Nanoparticular zinc oxide (ZnO) may be internalised through ambient air or the topical application of cosmetics, only to name a few, with unpredictable health effects. Therefore, we analysed the determinants of ZnO nanoparticle (NP) genotoxicity. ZnO NPs (15-18 nm in diameter) were investigated at concentrations of 0.1, 10 and …
Soluble IF-ReS2 nanoparticles by surface functionalization with terpyridine ligands.
2010
A major drawback in the application of layered chalcogenide nanoparticles/tubes is their inertness to chemical and biological modification and functionalization. Their potential use in composite materials might be greatly enhanced by improving the chalcogenide/matrix interface bonding. A novel modification strategy for layered chalcogenide nanoparticles based on the chalcophilic affinity of metals and the chelating terpyridine is reported. The terpyridine anchor group can be conjugated to fluorescent tags or hydrophilic/hydrophobic groups that confer solubility in various solvents to the otherwise insoluble chalcogenide nanoparticles. The functionalized particles are characterized using TEM…
Development and analysis of a model based on chirped fiber Bragg gratings employed for cracks characterization in materials
2018
In this work a model was developed that allows to understand the behavior of a chirped fiber Bragg grating for the detection and characterization of cracks in materials. In addition to the amplitude response, we show that the group delay of the grating provides useful information for the characterization of the crack. The position of the crack can be determined thanks to the linear chirp of the grating that fixes a correlation between the spatial position and both, the wavelength and the group delay. However, our analysis shows that this simple approach has a source of error, which can be overcome if a controllable external strain can be applied to the embedded grating, additional to the st…
Evidence for Graphene Edges Beyond Zigzag and Armchair
2009
The edges of nanoscopic objects determine most of their properties. For this reason the edges of honeycomb carbon--always considered either zigzag- or armchair-like--need special attention. In this report we provide experimental evidence confirming a previous unexpected prediction: zigzag is a metastable edge, as its planar reconstruction lowers energy and forms the most stable graphene edge. Our evidence is based on re-analyzing a recent experiment. Since the reconstructed edge, along with other unconventional edges we discuss, has distinct chemical properties, this discovery urges for care in experiments and theory--we must enter the realm beyond zigzag and armchair.
Maxwell and Sharvin conductance in gold point contacts investigated using TEM-STM
2000
We have investigated the conductance of gold point contacts using a scanning tunneling microscope ~STM! inside a transmission electron microscope ~TEM!. Measuring the conductance of these point contacts as a function of radius, we could directly compare it with theories both in the ballistic regime ~Sharvin! as well as in the diffusive regime ~Maxwell!. The width of the contacts were between a single atom and 20 nm. Using an interpolation formula ~Wexler! between the two limits, we obtain a mean free path of 4 nm, which is about ten times shorter than the room-temperature bulk value. The low value indicates an enhanced scattering, which is not due to high temperature in the point contact, i…
Transmission properties at microwave frequencies of two-dimensional metallic lattices
1999
The transmission properties of different metallic photonic lattices (square and rectangular) have been experimentally studied. A numerical algorithm based on time domain finite differences has been used for simulating these photonic structures. The introduction of defects in the two-dimensional metallic lattice modifies its transmission spectrum. If metal rods are eliminated from (or added to) the lattice, extremely narrow peaks are observed at some particular frequencies below (or above) the band pass edge. Vicente.Such@uv.es ; Enrique.Navarro@uv.es
Magnetic polyorganosiloxane core–shell nanoparticles: Synthesis, characterization and magnetic fractionation
2010
Abstact Here, we present the synthesis, characterization and magnetic separation of magnetic polyorganosiloxane nanoparticles. Magnetic iron oxide nanoparticles with average particle radii of 3.2 nm had been synthesized by a simple coprecipitation process of iron(II) and iron(III) salt in basic solution. Afterwards, the particles were successfully incorporated into a polyorganosiloxane network via a polycondensation reaction of trimethoxymethylsilane (T), diethoxydimethylsilane (D) and the functional monomer (chloromethylphenyl)trimethoxysilane (ClBz-T) in aqueous dispersion. A core–shell system was chosen to increase the flexibility of the system concerning size, composition and functional…
Development of curcumin loaded sodium hyaluronate immobilized vesicles (hyalurosomes) and their potential on skin inflammation and wound restoring.
2015
In the present work new highly biocompatible nanovesicles were developed using polyanion sodium hyaluronate to form polymer immobilized vesicles, so called hyalurosomes. Curcumin, at high concentration was loaded into hyalurosomes and physico-chemical properties and in vitro/in vivo performances of the formulations were compared to those of liposomes having the same lipid and drug content. Vesicles were prepared by direct addition of dispersion containing the polysaccharide sodium hyaluronate and the polyphenol curcumin to a commercial mixture of soy phospholipids, thus avoiding the use of organic solvents. An extensive study was carried out on the physico-chemical features and properties o…
Micro- and nano-diamond particles in carbon spherules found in soil samples
2008
Carbonaceous spherules of millimeter size diameter and found in the upper soils throughout Europe are investigated by TEM, including SAED, HRTEM and EELS, and Raman spectroscopy. The spherules consist primarily of carbon and have an open cell-like internal structure. Most of the carbon appears in an amorphous state, but different morphologies of nano- and microdiamond particles have also been discovered including flake shapes. The latter observation, together with the original findings of some of these spherules in crater-like structures in the landscape and including severely deformed rocks with some spherules being embedded in the fused crust of excavated rocks, points towards unique cond…
Electron transfer in ZnO–Fe2O3 aqueous slurry systems and its effects on visible light photocatalytic activity
2017
ZnFex (x = 0.025, 0.05, and 0.1) nanocomposites and pure ZnO and Fe2O3 photocatalysts were synthesized by a simple sol–gel route and characterized by means of specific surface area (SSA) analysis, X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), and transmission electron microscopy/energy dispersive X-ray spectroscopy (TEM/EDS). Their photocatalytic activity was investigated under visible light by using methylene blue (MB) and benzoic acid (BA) as model compounds. Coupling ZnO and Fe2O3 results in higher photocatalytic activity with respect to the pure materials. Photoelectrochemical characterization performed in slurry systems allowed the elucidation of the electronic struc…