Search results for "Trihydrido"

showing 10 items of 25 documents

Electrochemical and DFT studies of the oxidative decomposition of the trihydride complexes Cp*M(dppe)H3 (M = Mo, W) in acetonitrile

2006

International audience; A detailed electrochemical study of the oxidative decomposition of the trihydride complexes Cp*M(dppe)H3 (M = Mo, W) in acetonitrile is presented. For the Mo complex, the decomposition occurs by four different pathways involving classical and non-classical tautomers, whereas only the classical form is accessible for the W derivative. Each of the decomposition pathways has been quantitatively assessed by analyses of the linear sweep voltammograms. In addition to the previously established (B. Pleune, D. Morales, R. Meunier-Prest, P. Richard, E. Collange, J. C. Fettinger and R. Poli, J. Am. Chem. Soc., 1999, 121, 2209–2225) deprotonation, disproportionation, and H2 red…

StereochemistryDisproportionation010402 general chemistryElectrochemistry01 natural sciencesMedicinal chemistryDFTCatalysisReductive eliminationTungstenchemistry.chemical_compoundDeprotonationComplexMaterials Chemistrypentamethylcyclopentadienyl[CHIM.COOR]Chemical Sciences/Coordination chemistryAcetonitrileComputingMilieux_MISCELLANEOUSMolybdenumPhenylphosphinoethane010405 organic chemistryChemistry[ CHIM.COOR ] Chemical Sciences/Coordination chemistryGeneral ChemistryAssociative substitutionRate-determining stepTautomer0104 chemical sciences[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryTrihydridoPentamethylcyclopentadienyl ligand
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CCDC 1982653: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-(diphenyl(trihydridoborato)phosphonio)-O-(t-butyl(trihydridoborato)phenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateExperimental 3D Coordinates
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CCDC 1982657: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-(diphenyl(trihydridoborato)phosphonio)-O-(p-tolyl(trihydridoborato)phenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateExperimental 3D Coordinates
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CCDC 1982662: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-(diphenyl(trihydridoborato)phosphonio)-O-((naphthalenyl)(trihydridoborato)phenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateExperimental 3D Coordinates
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CCDC 225463: Experimental Crystal Structure Determination

2004

Related Article: M.G.Basallote, F.Estevan, M.Feliz, M.J.Fernandez-Trujillo, D.A.Hoyos, R.Llusar, S.Uriel, C.Vicent|2004|Dalton Trans.||530|doi:10.1039/b315841a

Space GroupCrystallography(mu~3~-Selenido)-tris(mu~2~-selenido)-trihydrido-tris(12-bis(dimethylphosphino)ethane-PP')-tri-tungsten tetraphenylborateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1982660: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-(diphenyl(trihydridoborato)phosphonio)-O-(o-tolyl(trihydridoborato)phenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateExperimental 3D Coordinates
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CCDC 937024: Experimental Crystal Structure Determination

2013

Related Article: Emmanuelle Rémond, Jérôme Bayardon, Shinobu Takizawa, Yoann Rousselin, Hiroaki Sasai, and Sylvain Jugé|2013|Org.Lett.|15|1870|doi:10.1021/ol400515e

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(R~p~S)-trihydrido[(2-[ferrocenyl(phenyl)phosphanyl]phenyl)(phenyl)methanol]boronExperimental 3D Coordinates
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CCDC 736942: Experimental Crystal Structure Determination

2010

Related Article: T.D.Forster, H.M.Tuononen, M.Parvez, R.Roesler|2009|J.Am.Chem.Soc.|131|6689|doi:10.1021/ja901460y

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesbis(eta^5^-Cyclopentadienyl)-(amino(trihydrido)borate-HN)-hydrido-zirconium
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CCDC 1982665: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-((biphenyl-2-yl)phenyl(trihydridoborato)phosphonio)-O-((trihydridoborato)diphenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateExperimental 3D Coordinates
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CCDC 1583212: Experimental Crystal Structure Determination

2018

Related Article: Nicolas Sok, Claire Bernhard, Pauline Désogère, Christine Goze, Yoann Rousselin, Frédéric Boschetti, Isabelle Baglin, Franck Denat|2018|Eur.J.Org.Chem.|2018|4762|doi:10.1002/ejoc.201800801

Space GroupCrystallographyCrystal SystemCrystal Structure{1-(9b9c-dimethyldecahydro-5H-2a4a7a9a-tetraazacyclopenta[cd]phenalen-1-yl)-N-[(pyren-1-yl)methyl]methanamine}(trihydrido)boronCell ParametersExperimental 3D Coordinates
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