Search results for "Trimethylbenzenes"

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Xylene isomerization and aromatic alkylation in zeolites NU-87, SSZ-33, β, and ZSM-5: molecular dynamics and catalytic studies

2004

The unique pore topology of zeolite NU-87, with 10-membered ring (MR) channels intersected by perpendicular 12-MR cavities, can offer new opportunities for alkylaromatics isomerization, as well as for aromatics alkylation. The catalytic performance has been studied for meta-xylene isomerization and disproportionation, as well as toluene alkylation with methanol, ethanol, propanol, and isopropanol. Product distribution was interpreted on the basis of pore topology and compared to zeolites with 12-MR (β), 10- and 12-MR (SSZ-33), and 10-MR (ZSM-5) zeolites. The presence of cavities allows more space for the location of bulky intermediates and/or products, and also traps the molecules, allowing…

Cumenechemistry.chemical_compoundChemistryXyleneTrimethylbenzenesPhysical and Theoretical ChemistryZSM-5AlkylationPhotochemistryMolecular sieveIsomerizationCatalysisCatalysisJournal of Catalysis
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CCDC 258947: Experimental Crystal Structure Determination

2005

Related Article: A.Ahman, M.Luostarinen, C.A.Schalley, M.Nissinen, K.Rissanen|2005|Eur.J.Org.Chem.|2005|2793|doi:10.1002/ejoc.200500039

bis(10122224-Tetrahydroxy-4561116171823-octakis(246-trimethylbenzenesulfonato)-281420-tetrapropylcalix[4]arene) tridecakis(tetrahydrofuran) clathrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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