Search results for "Troposphere"

Some aspects of the seasonal variation of carbon dioxide and ozone

1968

An attempt is made to estimate the seasonal source function, Q , of CO 2 on the basis of data for the biosphere, provided by Lieth, and for other sources. The variation of soil respiration appears to be the most uncertain factor. The resulting CO 2 variations in the atmosphere are calculated for horizontal exchange coefficients, K , which vary with latitude. Comparison with observations given by Bolin & Keeling shows that the results are not very sensitive with respect to the assumed variations of Q and of K with latitude. Previous results on the 0 3 budget are used to calculate seasonal variations of tropospheric 0 3 for stratospheric injection rates, and K values which vary with latitude.…

Sampling of an STT event over the Eastern Mediterranean region by lidar and electrochemical sonde

2005

A two-wavelength ultraviolet (289–316nm) ozone Differential Absorption Lidar (DIAL) system is used to perform ozone measurements in the free troposphere in the Eastern Mediterranean (Northern Greece). The ozone DIAL profiles obtained during a Stratosphere-to-Troposphere Transport (STT) event are compared to that acquired by an electrochemical ozonesonde, in the altitude range between 2 and 10 km. The measurement accuracy of these two instruments is also discussed. The mean difference between the ozone profiles obtained by the two techniques is of the order of 1.11 ppbv (1.86%), while the corresponding standard deviation is 4.69 ppbv (8.16%). A case study of an STT event which occurred on 29…

Airborne observation of mixing across the entrainment zone during PARADE 2011

2016

This study presents the analysis of the structure and air mass characteristics of the lower atmosphere during the field campaign PARADE (PArticles and RAdicals: Diel observations of the impact of urban and biogenic Emissions) on Mount Kleiner Feldberg in southwestern Germany during late summer 2011. We analysed measurements of meteorological variables (temperature, moisture, pressure, wind speed and direction) from radio soundings and of chemical tracers (carbon dioxide, ozone) from aircraft measurements. We focus on the thermodynamic and dynamic properties that control the chemical distribution of atmospheric constituents in the boundary layer. We show that the evolution of tracer profiles…

Global ozone budget and exchange between stratosphere and troposphere

1962

A survey of existing data reveals that tropospheric ozone is fairly uniformly distributed within the hemispheres, but that the hemispheres are well separated. Within the northern hemisphere representative data of tropospheric ozone exhibit a uniform seasonal variation the phase of which is delayed by about 2 months with respect to the injection into the troposphere. It is suggested that this delay is controlled by the rate of destruction of ozone within the troposphere. On the basis of this concept and additional reasonable assumptions it is possible to give a quantitative analysis of the ozone budget and of the seasonal variation of the exchange between stratosphere and troposphere. Calcul…

2019

Abstract. Activated chlorine compounds in the polar winter stratosphere drive catalytic cycles that deplete ozone and methane, whose abundances are highly relevant to the evolution of global climate. The present work introduces a novel dataset of in situ measurements of relevant chlorine species in the lowermost Arctic stratosphere from the aircraft mission POLSTRACC–GW-LCYCLE–SALSA during winter 2015/2016. The major stages of chemical evolution of the lower polar vortex are presented in a consistent series of high-resolution mass spectrometric observations of HCl and ClONO2. Simultaneous measurements of CFC-12 are used to derive total inorganic chlorine (Cly) and active chlorine (ClOx). Th…

The importance of stratospheric–tropospheric transport in affecting surface ozone concentrations in the western and northern tier of the United States

2011

Stratospheric–tropospheric exchange (STE) processes contribute at both high and low-elevation monitoring sites to background ozone (O3) concentrations. This study addresses the importance of stratospheric intrusions contributing to enhanced hourly average surface O3 concentrations (i.e., ≥50 ppb) at 12 O3 monitoring stations in the western and northern tier of the US for 2006, 2007, and 2008. The Lagrangian Analysis Tool (LAGRANTO) trajectory model identified specific days when stratosphere-to-troposphere transport was optimal to elevate surface O3 levels. The coincidences between the number of days with a daily maximum hourly average O3 concentration ≥ 50 ppb and stratosphere-to-tropospher…

Neural networks for analysing the relevance of input variables in the prediction of tropospheric ozone concentration

2006

Abstract This paper deals with tropospheric ozone modelling by using Artificial Neural Networks (ANNs). In this study, ambient ozone concentrations are estimated using surface meteorological variables and vehicle emission variables as predictors. The work is especially focused on analysing the importance of the input variables used by these models. This analysis is carried out in different time windows: all the time of study (April of 1997, 1999 and 2000), one month (April 1999), and finally, an hourly analysis. All the information extracted from these analyses can determine the most important factors in tropospheric ozone formation, thus achieving a qualitative model from the quantitative …

A complex case study of down to the surface intrusions of persistent stratospheric air over the Eastern Mediterranean

2006

Abstract In this study, we present a complex case study of concurrent stratosphere-to-troposphere transport (STT) events down to the surface of a low topography region in Northern Greece, which occurred in spring 2000. Two surface stations at Livadi (850 m asl) and Thessaloniki (20 m asl) were influenced by intrusions of stratospheric air masses that persisted for a time period from 7 to 10 days within the troposphere before reaching the stations. Before reaching the surface stations in Greece, the air masses crossed the tropopause in different synoptic systems over Eastern Europe, N. America and the N. Atlantic. This is the first study, to our knowledge, that presents a down to the surface…

Measurement report: Photochemical production and loss rates of formaldehyde and ozone across Europe

2021

Various atmospheric sources and sinks regulate the abundance of tropospheric formaldehyde (HCHO), which is an important trace gas impacting the HOx (≡ HO2 + OH) budget and the concentration of ozone (O3). In this study, we present the formation and destruction terms of ambient HCHO and O3 calculated from in situ observations of various atmospheric trace gases measured at three different sites across Europe during summertime. These include a coastal site in Cyprus, in the scope of the Cyprus Photochemistry Experiment (CYPHEX) in 2014, a mountain site in southern Germany, as part of the Hohenpeißenberg Photochemistry Experiment (HOPE) in 2012, and a forested site in Finland, where measurement…

Ozone mini-holes over Valencia (Spain) and their influence on the UV erythemal radiation

2010

Low ozone level episodes (also known as mini-holes) have been analysed over Valencia, Spain, during the period from 1 January 2000 to 31 December 2007. In this study, 24 episodes, lasting 1 or 2 days each, were detected. Most of them can be explained dynamically by the existence of an anticyclone over the Azores, which sends air masses coming from the Caribbean over the Iberian Peninsula. A positive anomaly in the vertical temperature profile in the high troposphere and one negative anomaly in the medium and low stratosphere are also observed in most of the analysed episodes. The total ozone column decrease is accompanied by a rise in the UV erythemal radiation levels. This increase is quan…