Search results for "Tunneling"
showing 10 items of 182 documents
Strong Bonding of Single C60 Molecules to (1 × 2)-Pt(110): an STM/DFT Investigation.
2007
International audience; The interaction of single C60 molecules with the (1 × 2)-Pt(110) surface has been studied by scanning tunneling microscopy and density functional theory (DFT) calculations on slab models. Molecules are observed to be frozen at room temperature and are found to be almost exclusively in the same configuration. Extensive DFT calculations show that this configuration is the global energy minimum, suggesting that adsorbed molecules have enough rototranslational freedom to escape from the numerous local minima. The adsorption energy (3.81 eV) is the strongest ever found for C60, and it is roughly proportional to the number of the Pt and C atoms at contact distance. Analysi…
Mo(CO)6 dissociation on Cu(111) stimulated by a Scanning Tunneling Microscope
2013
Abstract The surface of Cu(111) was exposed to molybdenum hexacarbonyl Mo(CO)6 with monolayer coverage at temperature 160 K and studied by a Scanning Tunneling Microscope. The monolayer structure has a hexagonal arrangement and forms a (√7 × √7) R19 superlattice on the copper (111) plane. Upon repeated scanning the monolayer is transformed into a (1 × 2) superstructure with 3-fold oriented domains. The domains of (1 × 2) superstructure can change orientation under scanning according to 3-fold surface symmetry. From analysis of the domain mobility, it follows that CO groups of carbonyl fragments are organized in the (1 × 2) superstructure conditioning the domain reorientation. The observed s…
Universal transport dynamics in a quenched tunnel-coupled Luttinger liquid
2016
The transport dynamics of a quenched Luttinger liquid tunnel-coupled to a fermionic reservoir is investigated. In the transient dynamics, we show that for a sudden quench of the electron interaction universal power-law decay in time of the tunneling current occurs, ascribed to the presence of entangled compound excitations created by the quench. In sharp contrast to the usual non universal power-law behavior of a zero-temperature non-quenched Luttinger liquid, the steady state tunneling current is ohmic and can be explained in terms of an effective quench-activated heating of the system. Our study unveils an unconventional dynamics for a quenched Luttinger liquid that could be identified in…
Numerical simulations of photon scanning tunneling microscopy: role of a probe tip geometry in image formation
2005
Abstract Numerical simulations of two-dimensional probe–object system emulating a photon scanning tunnelling microscope are presented. R -matrix propagation algorithm incorporated into the differential method was used to achieve an extended capability to rigorously model a realistic system consisting of both a probe and a sample. Influence of the probe tip parameters on image formation in scanning near-field microscopy has been investigated. Coupling of the near-field to a single-mode probe and formation of a guided fundamental mode in a probe were investigated for various probe widths and lengths. The influence of the probe taper shape and apex size on near-field images was studied for sin…
Analysis of image formation with a photon scanning tunneling microscope
1996
International audience; The photon scanning tunneling microscope (PSTM) is based on the frustration of a total internal reflected beam by the end of an optical fiber. Until now it has been used to obtain topographic information, generally for smooth samples. We report theoretical as well as experimental results on the observation of a step on a quartz substrate with the PSTM. These results demonstrate the effects on image formation of the distance between the fiber tip and the sample surface, the orientation of the incident beam with respect to the step, the polarization, and the coherence of the light. Good agreement exists between numerical simulations and experiments. We show that a pert…
L-Tryptophan on Cu(111): engineering a molecular labyrinth driven by indole groups
2015
The present article investigates the adsorption and molecular orientation of L-Tryptophan, which is both an essential amino acid important for protein synthesis and of particular interest for the development of chiral molecular electronics and biocompatible processes and devices, on Cu(111) using scanning tunneling microscopy and spectroscopy at 55 K and at room temperature. The arrangement of chemisorbed L-Tryptophan on the copper surface varies with both temperature and surface coverage. At low coverage, small clusters form on the surface irrespective of temperature, while at high coverage an ordered chain structure emerges at room temperature, and a tightly packed structure forms a molec…
Role of Deprotonation and Cu Adatom Migration in Determining the Reaction Pathways of Oxalic Acid Adsorption on Cu(111)
2011
Scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS), and first principles theoretical calculations have been used to gain insight into the fundamental processes involved in the adsorption and self-assembly of oxalic acid on Cu(111). The experimental data demonstrate that several reaction pathways are involved in the chemisorption of oxalic acid on Cu(111), one of which leads to deprotonation of the acid into oxalate molecules that form ordered structures on the surface. Theoretical calculations indicate that the adsorption of oxalate molecules is not stable on the surface unless copper adatoms are taken into consideration. Coordination with copper adatoms prevents ox…
Network Virtualization Based on Effective Packet Transformations
2015
Promocijas darbā ir piedāvātas divas oriģinālas tehnoloģijas, kas paaugstina datortīklu virtualizēšanas efektivitāti: ZERO tunelēšanas protokols, un Pakešu Transformāciju Valoda (Packet Transformation Language, PTL), kas ļauj kompaktā pierakstā formāli aprakstīt ZERO un citus tunelēšanas protokolus. Darbā ir piedāvāts Ethernet-pāri-IP tunelēšanas protokols, kas nodala visus Ethernet kadrus tunelēšanai NICE un UGLY kadros. UGLY kadri tiek tunelēti ar tradicionālām metodēm, kā UDP vai GRE enkapsulācija, kas būtiski palielina kopējo paketes garumu dēļ papildus galvenēm un fragmentēšanas, kas parasti nepieciešama, lai transportētu garus Ethernet kadrus pāri IP datortīklam, kam parasti maksimāla…
Dephasing due to quasiparticle tunneling in fluxonium qubits: a phenomenological approach
2015
The fluxonium qubit has arisen as one of the most promising candidate devices for implementing quantum information in superconducting devices, since it is both insensitive to charge noise (like flux qubits) and insensitive to flux noise (like charge qubits). Here, we investigate the stability of the quantum information to quasiparticle tunneling through a Josephson junction. Microscopically, this dephasing is due to the dependence of the quasiparticle transmission probability on the qubit state. We argue that on a phenomenological level the dephasing mechanism can be understood as originating from heat currents, which are flowing in the device due to possible effective temperature gradients…
RELAXATION PHENOMENA IN CLASSICAL AND QUANTUM SYSTEMS
2012
Relaxation phenomena in three different classical and quantum systems are investigated. First, the role of multiplicative and additive noise in a classical metastable system is analyzed. The mean lifetime of the metastable state shows a nonmonotonicbehavior with a maximum as a function of both the additive and multiplicative noise intensities. In the second system, the simultaneous action of thermal and non-Gaussian noise on the dynamics of an overdamped point Josephson junction is studied. The effect of a Lévy noise generated by a Cauchy–Lorentz distribution on the mean lifetime of the superconductive metastable state, in the presence of a periodic driving, is investigated. We find resonan…