Search results for "Twist"
showing 10 items of 82 documents
N-Acyl-glutarimides: Effect of Glutarimide Ring on the Structures of Fully Perpendicular Twisted Amides and N–C Bond Cross-Coupling
2020
N-Acyl-glutarimides have emerged as the most reactive precursors for N-C(O) bond cross-coupling reactions to date, wherein the reactivity is driven by ground-state destabilization of the amide bond. Herein, we report a full study on the effect of a glutarimide ring on the structures, electronic properties, and reactivity of fully perpendicular N-acyl-glutarimide amides. Most notably, this report demonstrates the generality of deploying N-acyl-glutarimides to achieve full twist of the acyclic amide bond, and results in the discovery of N-acyl-glutarimide amide with an almost perfect twist value, τ = 89.1°. X-ray structures of five new N-acyl-glutarimides are reported. Reactivity studies in t…
Biomechanics and functional morphology of a climbing monocot.
2015
Climbing monocots can develop into large bodied plants despite being confined by primary growth. In our study on Flagellaria indica we measured surprisingly high stem biomechanical properties (in bending and torsion) and we show that the lack of secondary growth is overcome by a combination of tissue maturation processes and attachment mode. This leads to higher densities of mechanically relevant tissues in the periphery of the stem and to the transition from self-supporting to climbing growth. The development of specialised attachment structures has probably underpinned the evolution of numerous other large bodied climbing monocot taxa.
Molecular Mechanism of the site-specific self-cleavage of the RNA phosphodiester backbone by a Twister Ribozyme
2017
Published as part of the special collection of articles derived from the 10th Congress on Electronic Structure: Principles and Applications (ESPA-2016). The catalytic activity of some classes of natural RNA, named as ribozymes, has been discovered just in the past decades. In this paper, the cleavage of the RNA phosphodiester backbone has been studied in aqueous solution and in a twister ribozyme from Oryza sativa. The free energy profiles associated with a baseline substrate-assisted mechanism for the reaction in the enzyme and in solution were computed by means of free energy perturbation methods within hybrid QM/MM potentials, describing the chemical system by the M06-2× functional and t…
Performance Study of Twisted Darrieus Hydrokinetic Turbine With Novel Blade Design
2021
Abstract Twisted Darrieus water turbine is receiving growing attention for small-scale hydropower generation. Accordingly, the need for raised water energy conversion incentivizes researchers to focus on the blade shape optimization of twisted Darrieus turbine. In view of this, experimental analysis has been performed to appraise the efficiency of a spiral Darrieus water rotor in the present work. To better the performance parameters of the studied water rotor with twisted blades, three novel blade shapes, namely U-shaped blade, V-shaped blade, and W-shaped blade, have been numerically tested using a computational fluid dynamics three-dimensional numerical model. The maximum power coefficie…
Projective models of K3 surfaces with an even set
2006
The aim of this paper is to describe algebraic K3 surfaces with an even set of rational curves or of nodes. Their minimal possible Picard number is nine. We completely classify these K3 surfaces and after a carefull analysis of the divisors contained in the Picard lattice we study their projective models, giving necessary and sufficient conditions to have an even set. Moreover we investigate their relation with K3 surfaces with a Nikulin involution.
Vector Bundles and Torsion Free Sheaves on Degenerations of Elliptic Curves
2006
In this paper we give a survey about the classification of vector bundles and torsion free sheaves on degenerations of elliptic curves. Coherent sheaves on singular curves of arithmetic genus one can be studied using the technique of matrix problems or via Fourier-Mukai transforms, both methods are discussed here. Moreover, we include new proofs of some classical results about vector bundles on elliptic curves.
Chaotic dynamics and partial hyperbolicity
2017
The dynamics of hyperbolic systems is considered well understood from topological point of view as well as from stochastic point of view. S. Smale and R. Abraham gave an example showing that, in general, the hyperbolic systems are not dense among all differentiable systems. In 1970s, M. Brin and Y. Pesin proposed a new notion: partial hyperbolicity to release the notion of hyperbolicity. One aim of this thesis is to understand the dynamics of certain partially hyperbolic systems from stochastic point of view as well as from topological point of view. From stochastic point of view, we prove the following results: — There exists an open and dense subset U of robustly transitive nonhyperbolic …
On a new proof of Moser's twist mapping theorem
1976
Based on a new idea of the author, a new proof of J. Moser's twist mapping theorem is presented.
Electron Energy Loss and DFT/SCI Study of the Singlet and Triplet Excited States of Aminobenzonitriles and Benzoquinuclidines: Role of the Amino Gro…
1999
Spectroscopic consequences of varying the twist angle of the amino group in aminobenzonitrile systems in the electronic ground state are investigated by applying electron energy loss (EEL) spectroscopy and density functional theory to 4-N,N-dimethylaminobenzonitrile (DMABN), 4-N,N-dimethylamino-3,5-dimethylbenzonitrile (MMD), benzoquinuclidine (BQ), and 6-cyanobenzoquinuclidine (CBQ). A number of singlet and triplet excited states was observed and assigned with the help of DFT/SCI theory. The results characterize the gas-phase spectroscopy of the molecules and verify to within 0.3 eV the predictive power of DFT/SCI theory for vertical states over a wide range of twist and pyramidalization a…
Partial spreads in finite projective spaces and partial designs
1975
A partial t-spread of a projective space P is a collection 5 p of t-dimensional subspaces of P of the same order with the property that any point of P is contained in at most one element of 50. A partial t-spread 5 p of P is said to be a t-spread if each point of P is contained in an element of 5P; a partial t-spread which is not a spread will be called strictly partial. Partial t-spreads are frequently used for constructions of affine planes, nets, and Sperner spaces (see for instance Bruck and Bose [5], Barlotti and Cofman [2]). The extension of nets to affine planes is related to the following problem: When can a partial t-spread 5 ~ of a projective space P be embedded into a larger part…