Search results for "UNESCO::"
showing 10 items of 31997 documents
Switching of Slow Magnetic Relaxation Dynamics in Mononuclear Dysprosium(III) Compounds with Charge Density
2016
The symmetry around a Dy ion is recognized to be a crucial parameter dictating magnetization relaxation dynamics. We prepared two similar square-antiprismatic complexes, [Dy(LOMe)2(H2O)2](PF6) (1) and Dy(LOMe)2(NO3) (2), where LOMe = [CpCo{P(O)(O(CH3))2}3], including either two neutral water molecules (1) or an anionic nitrate ligand (2). We demonstrated that in this case relaxation dynamics is dramatically affected by the introduction of a charged ligand, stabilizing the easy axis of magnetization along the nitrate direction. We also showed that the application of either a direct-current field or chemical dilution effectively stops quantum tunneling in the ground state of 2, thereby increa…
A thermally/chemically robust and easily regenerable anilato-based ultramicroporous 3D MOF for CO 2 uptake and separation
2021
The combination of the properly designed novel organic linker, 3,6-N-ditriazoyil-2,5-dihydroxy-1,4-benzoquinone (trz2An), with CoII ions results in a 3D ultramicroporous MOF with high CO2 uptake capacity and separation efficiency, with particular attention to CO2/N2 and CO2/CH4 gas mixtures. This material consists of 1D chains of octahedrally coordinated CoII ions linked through the anilato ligands in the equatorial positions and to the triazole substituents from two neighbouring chains in the two axial positions. This leads to a 3D microporous structure with voids with an affinity for CO2 molecules and channels that enable the selective entrance of CO2 but not of molecules with larger kine…
Effect of different concentrations of specific inhibitor of matrix metalloproteinases on the shear bond strength of self-adhesive resin cements to de…
2017
Background Considering the probability of chemical and enzymatic reactions between matrix metalloproteinases (MMPs) in the dentin structure and their specific inhibitors, the aim of the present study was to evaluate the effect of different concentrations of specific inhibitor of MMPs (galardin) on the shear bond strength of self-adhesive resin cements to dentin. Material and Methods Forty-eight sound human premolars were mounted in self-cured acrylic resin after removal of the enamel on the buccal and lingual surfaces. The dentin surfaces achieved were polished and prepared with 600-grit silicon carbide paper. The samples were divided into 3 groups (n=16) based on the concentration of galar…
Analysis of salivary detection of P16INK4A and RASSF1A promoter gene methylation and its association with oral squamous cell carcinoma in a Colombian…
2019
Background Epigenetic factors play a fundamental role in the etiopathogenesis of oral squamous cell carcinoma (OSCC). This study evaluated if salivary detection of P16INK4A/RASSF1A gene promoter methylation might be linked to the clinical/histological features of OSCC in a Colombian population. Material and Methods Methylation-specific polymerase chain reaction (MSP-PCR) was used to detect the methylation frequency of P16INK4A/RASSF1A genes in DNA obtained from whole saliva collected of 40 healthy controls (HC) and 43 OSCC patients. Determination of the clinical performance of MSP-PCR assay was based on standard algorithms derived from two-way contingency table analysis. The association of …
L’ évolution des assemblages lithiques des niveaux du Paléolithique moyen de l’Abrigo de la Quebrada (Valencia, Espagne)
2018
L’Abrigo de la Quebrada propose une séquence stratigraphique importante, avec neuf niveaux dont sept présentent des preuves d’occupation appartenant au Paléolithique moyen. De plus, l’existence d’un niveau stérile, le VI, séparant les niveaux supérieurs (II à V) des niveaux inférieurs (VII à IX), permet d’évaluer, dans une perspective diachronique, les changements constatés sur les différentes matiàres premières et sur les systémes de débitage employés pour chacune de ces deux grandes phases. Ces donne´ es sont compare´ es a` d’autres sites contemporains, dans le but d’e´valuer les normes technologiques et la gestion des ressources des ne´ andertaliens dans la zone ge´ographique de la re´gi…
Not only flint: Levallois on quartzite and limestone at Abrigo de la Quebrada (Valencia, Spain): Implications for neandertal Behavior
2016
This paper investigates the application of the Levallois technique to the knapping of nonflint raw materials (limestone and quartzite) in the upper levels of the Abrigo de la Quebrada rockshelter (Chelva, Valencia, Spain). Besides highlighting the significant flexibility that characterized Neandertal behavior, such an application is of singular interest because goodquality flint—lacking fissures and impurities and presenting a compact and homogeneous texture—is abundant in the site’s immediate vicinity. In other assemblages, the scarcity or poor quality of flint often suffices to explain the recourse to alternatives, but in these Quebrada levels raw material choice must be primarily determi…
Positive effect of platelet rich fibrin on osseointegration
2016
Background Leukocyte-platelet rich fibrin (L-PRF) is a second generation platelet concentrate clinically used to accelerate tissue healing and bone regeneration. Achieving reduced implant osseointegration time could provide immediate or early loading of implants. The aim of this study was to evaluate the L-PRF-induced osseointegration and bone-implant contact (BIC) in an experimental animal model. Material and Methods Twelve 4-month-old New Zealand white rabbits were used. Following general anesthesia, 3-5 mL of blood was obtained from the central artery in rabbit ear and L-PRF was prepared. Two implant cavities (5 mm long and 3 mm in diameter) were created in each tibia with a total of fou…
Binding Site Alteration Is Responsible for Field-Isolated Resistance to Bacillus thuringiensis Cry2A Insecticidal Proteins in Two Helicoverpa Species
2010
Background Evolution of resistance by target pests is the main threat to the long-term efficacy of crops expressing Bacillus thuringiensis (Bt) insecticidal proteins. Cry2 proteins play a pivotal role in current Bt spray formulations and transgenic crops and they complement Cry1A proteins because of their different mode of action. Their presence is critical in the control of those lepidopteran species, such as Helicoverpa spp., which are not highly susceptible to Cry1A proteins. In Australia, a transgenic variety of cotton expressing Cry1Ac and Cry2Ab (Bollgard II) comprises at least 80% of the total cotton area. Prior to the widespread adoption of Bollgard II, the frequency of alleles conf…
'Historia y cine. La construcción del pasado a través de la ficción', de Mónica Bolufer, Juan Gomis y Telesforo Hernández(eds.)
2016
Resena critica de: Bolufer, Monica; Gomis, Juan y Hernandez M. Telesforo (eds.) (2015), Historia y cine. La construccion del pasado a traves de la ficcion , Institucion Fernando el Catolico, Zaragoza. ISBN: 9788499113722, 216 pags.
Effectiveness of sodium bicarbonate combined with hydrogen peroxide and CPP-ACPF in whitening and microhardness of enamel
2017
Background: This study investigated the effects of sodium bicarbonate (NaHCO3) combined with 1.5 hydrogen peroxide (H2O2) and casein phosphopeptide amorphous calcium phosphate fluoride (CPP-ACPF) on color and microhardness of enamel. Material and Methods: Seventy-five bovine incisors were immersed in a tea solution for 7.5 days. The specimens were randomly divided into five groups according to the whitening agent applied: 1) 94 NaHCO3, 2) a blend of 94 NaHCO3 and CPP-ACPF, 3) a blend of 94 NaHCO3 and 1.5 H2O2, 4) a blend of 94 NaHCO3, 1.5 H2O2 and CPP-ACPF, 5) control. The whitening procedure was performed for 10 times over 10 days. At each day, the buccal surfaces were covered with whiteni…