Search results for "UNESCO"
showing 10 items of 33168 documents
Cádiz en Charcas: conjeturas e indicios
2012
Este es un artículo de historia constitucional. Se centra en la relación entre la Constitución española de 1812 y la Constitución boliviana de 1826. Su conclusión principal niega la idea de que, por el solo hecho de que ambas fueron cartas liberales contemporáneas entre sí escritas en la misma lengua, la primera Constitución haya influenciado en la segunda. Al contrario, toma a las semejanzas de redacción como un mero mecanismo de auxilio técnico, pero no por una fuente de influencia. Y, no las califica así, porque la influencia supone una relación de autoridad moralmente justificada, lo que, precisamente, estaba ausente entre el poder metropolitano y sus colonias. Una serie de documentos h…
Marginal and internal fit evaluation of conventional metal-ceramic versus zirconia CAD/CAM crowns
2019
Background The purpose of this in vivo study was to compare the marginal and internal gap widths of monolithic zirconia crowns fabricated by CAD/CAM technique and metal-ceramic crowns fabricated by conventional technique. Material and methods 10 participants needing a single restoration were selected. Zirconia crowns using CAD/CAM technology (Group A) (n=10) and metal-ceramic crowns (Group B) (n=10) using lost wax casting technique were fabricated for each selected tooth. The marginal and internal gaps of crowns were recorded using a replica technique with light body silicone material stabilized with a regular set putty. Each replica was sectioned buccolingually and mesiodistally and then e…
Finite element analysis of stress concentration between surface coated implants and non surface coated implants - An in vitro study.
2019
Background To determine qualitative comparison in stress distribution between surface coated implants and non surface coated implants using 2 different lengths and vertical, oblique, and lateral forces. Material and Methods 3 dimensional finite element study was carried out at first molar site with 4 surface coated and 4 non surface coated implants using mimic 8.11, solid edge 2004, hypermesh 9.0, and ansys12.1 software. Results The pattern of stress distribution was almost similar between vertical and oblique loading but varied with lateral loads between surface coated and non surface coated implants. As the length of the implants increased stress concentration had no significant variation…
Switching of Slow Magnetic Relaxation Dynamics in Mononuclear Dysprosium(III) Compounds with Charge Density
2016
The symmetry around a Dy ion is recognized to be a crucial parameter dictating magnetization relaxation dynamics. We prepared two similar square-antiprismatic complexes, [Dy(LOMe)2(H2O)2](PF6) (1) and Dy(LOMe)2(NO3) (2), where LOMe = [CpCo{P(O)(O(CH3))2}3], including either two neutral water molecules (1) or an anionic nitrate ligand (2). We demonstrated that in this case relaxation dynamics is dramatically affected by the introduction of a charged ligand, stabilizing the easy axis of magnetization along the nitrate direction. We also showed that the application of either a direct-current field or chemical dilution effectively stops quantum tunneling in the ground state of 2, thereby increa…
A thermally/chemically robust and easily regenerable anilato-based ultramicroporous 3D MOF for CO 2 uptake and separation
2021
The combination of the properly designed novel organic linker, 3,6-N-ditriazoyil-2,5-dihydroxy-1,4-benzoquinone (trz2An), with CoII ions results in a 3D ultramicroporous MOF with high CO2 uptake capacity and separation efficiency, with particular attention to CO2/N2 and CO2/CH4 gas mixtures. This material consists of 1D chains of octahedrally coordinated CoII ions linked through the anilato ligands in the equatorial positions and to the triazole substituents from two neighbouring chains in the two axial positions. This leads to a 3D microporous structure with voids with an affinity for CO2 molecules and channels that enable the selective entrance of CO2 but not of molecules with larger kine…
Effect of different concentrations of specific inhibitor of matrix metalloproteinases on the shear bond strength of self-adhesive resin cements to de…
2017
Background Considering the probability of chemical and enzymatic reactions between matrix metalloproteinases (MMPs) in the dentin structure and their specific inhibitors, the aim of the present study was to evaluate the effect of different concentrations of specific inhibitor of MMPs (galardin) on the shear bond strength of self-adhesive resin cements to dentin. Material and Methods Forty-eight sound human premolars were mounted in self-cured acrylic resin after removal of the enamel on the buccal and lingual surfaces. The dentin surfaces achieved were polished and prepared with 600-grit silicon carbide paper. The samples were divided into 3 groups (n=16) based on the concentration of galar…
The effect of bone marrow-derived stem cells associated with platelet-rich plasma on the osseointegration of immediately placed implants
2020
Background Stem cells associated with growth factors have been shown to improve bone healing and the osseointegration of dental implants. A Brazilian miniature pig model was used to evaluate the effect of autologous bone marrow-derived mesenchymal stem cells (BM-MSCs) associated with platelet-rich plasma (PRP) on the osseointegration of immediately placed dental implants. Material and methods A total of four male adult miniature pigs were used in this study. BM-MSCs from each pig were isolated from the iliac crest and expanded in vitro. The undifferentiated BM-MSCs were mixed with autologous PRP and implanted in the post-extraction sockets at the experimental sites before implant placement …
Analysis of salivary detection of P16INK4A and RASSF1A promoter gene methylation and its association with oral squamous cell carcinoma in a Colombian…
2019
Background Epigenetic factors play a fundamental role in the etiopathogenesis of oral squamous cell carcinoma (OSCC). This study evaluated if salivary detection of P16INK4A/RASSF1A gene promoter methylation might be linked to the clinical/histological features of OSCC in a Colombian population. Material and Methods Methylation-specific polymerase chain reaction (MSP-PCR) was used to detect the methylation frequency of P16INK4A/RASSF1A genes in DNA obtained from whole saliva collected of 40 healthy controls (HC) and 43 OSCC patients. Determination of the clinical performance of MSP-PCR assay was based on standard algorithms derived from two-way contingency table analysis. The association of …
L’ évolution des assemblages lithiques des niveaux du Paléolithique moyen de l’Abrigo de la Quebrada (Valencia, Espagne)
2018
L’Abrigo de la Quebrada propose une séquence stratigraphique importante, avec neuf niveaux dont sept présentent des preuves d’occupation appartenant au Paléolithique moyen. De plus, l’existence d’un niveau stérile, le VI, séparant les niveaux supérieurs (II à V) des niveaux inférieurs (VII à IX), permet d’évaluer, dans une perspective diachronique, les changements constatés sur les différentes matiàres premières et sur les systémes de débitage employés pour chacune de ces deux grandes phases. Ces donne´ es sont compare´ es a` d’autres sites contemporains, dans le but d’e´valuer les normes technologiques et la gestion des ressources des ne´ andertaliens dans la zone ge´ographique de la re´gi…
Not only flint: Levallois on quartzite and limestone at Abrigo de la Quebrada (Valencia, Spain): Implications for neandertal Behavior
2016
This paper investigates the application of the Levallois technique to the knapping of nonflint raw materials (limestone and quartzite) in the upper levels of the Abrigo de la Quebrada rockshelter (Chelva, Valencia, Spain). Besides highlighting the significant flexibility that characterized Neandertal behavior, such an application is of singular interest because goodquality flint—lacking fissures and impurities and presenting a compact and homogeneous texture—is abundant in the site’s immediate vicinity. In other assemblages, the scarcity or poor quality of flint often suffices to explain the recourse to alternatives, but in these Quebrada levels raw material choice must be primarily determi…